US4452933A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Stabilized polyester-polycarbonate blends and stabilization process therefor
Assignee: General Electric Co
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Filing: 1983-06-09
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Granted: 1984-06-05
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Expires: 2003-06-09
Abstract
Abstract Ester-carbonate interchange in blends of aromatic polycarbonates and poly(alkylene dicarboxylates) is inhibited by adding thereto a hydroxy- or amino-substituted carboxylic acid derivative such as methyl salicylate, malic acid, glycine or dibutyl tartrate.
Inventors
- 👤 Russell J. McCready
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 15:34
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13; C08K5/134; C08K5/1345; C08K5/16; C08K5/20; C08L; C08L67/00; C08L67/02; C08L69/00
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
159 words
A process for stabilizing a composition comprising at least one poly(alkylene dicarboxylate) prepared by the reaction of at least one alkenediol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a titanium compound as catalyst and at least one aromatic polycarbonate, which comprises adding thereto an amount effective to inhibit ester-carbonate interchange of at least one α-hydroxy or α-amino aliphatic acid derivative, or o-hydroxy or σ-amino aromatic acid derivative, of the formula ##STR6## wherein: X 1 is 0 or NH; X 2 or OR 5 when X 1 is NH and is OR 5 or NHR 5 when X 1 is 0; Z is CH or a single-ring aromatic carbocyclic radical in which the X 1 H and ##STR7## moieties occupy ortho positions; R 4 is hydrogen, a lower alkyl radical or a lower aryl radical which optionally contains hydroxy or COOR 5 substituents; and R 5 is hydrogen, lower alkyl or lower aryl.
Claim 2
Dependent Claim
159 words
A process for stabilizing a composition comprising at least one poly(alkylene dicarboxylate) prepared by the reaction of at least one alkenediol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a titanium compound as catalyst and at least one aromatic polycarbonate, which comprises adding thereto an amount effective to inhibit ester-carbonate interchange of at least one α-hydroxy or α-amino aliphatic acid derivative, or o-hydroxy or σ-amino aromatic acid derivative, of the formula ##STR6## wherein: X 1 is 0 or NH; X 2 or OR 5 when X 1 is NH and is OR 5 or NHR 5 when X 1 is 0; Z is CH or a single-ring aromatic carbocyclic radical in which the X 1 H and ##STR7## moieties occupy ortho positions; R 4 is hydrogen, a lower alkyl radical or a lower aryl radical which optionally contains hydroxy or COOR 5 substituents; and R 5 is hydrogen, lower alkyl or lower aryl.
Claim 3
Dependent Claim
35 words
A process according to claim 1 wherein the polycarbonate comprises repeating units of the formula ##STR8## wherein R 3 is a divalent aromatic radical derived from a dihydroxyaromatic compound of the formula HO--R 3 --OH.
Claim 4
Dependent Claim
54 words
A process according to claim 2 wherein the poly(alkylene dicarboxylate) comprises units of the formula ##STR9## wherein R 1 is a saturated divalent aliphatic hydrocarbon radical containing about 2-10 carbon atoms and R 2 is a divalent aliphatic radical containing about 2-20 carbon atoms or a divalent aromatic radical containing about 6-20 carbon atoms.
Claim 5
Dependent Claim
22 words
A process according to claim 3 wherein the weight ratio of poly(alkylene dicarboxylate) to polycarbonate is from about 99:1 to about 1:99.
Claim 6
Dependent Claim
16 words
A process according to claim 4 wherein R 1 is the ethylene, trimethylene or tetramethylene radical.
Claim 7
Dependent Claim
13 words
A process according to claim 5 wherein R 2 is an aromatic radical.
Claim 8
Dependent Claim
19 words
A process according to claim 6 wherein the dihydroxyaromatic compound from which R 3 is derived is bisphenol A.
Claim 9
Dependent Claim
13 words
A process according to claim 7 wherein the poly(alkylene dicarboxylate) is a terephthalate.
Claim 10
Dependent Claim
11 words
A process according to claim 4 wherein X 1 is 0.
Claim 11
Dependent Claim
18 words
A process according to claim 9 wherein X 2 is OR 5 and R 5 is lower alkyl.
Claim 12
Dependent Claim
19 words
A process according to claim 10 wherein Z is a single-ring aromatic carboxylic radical and R 4 is hydrogen.
Claim 13
Dependent Claim
11 words
A process according to claim 11 wherein X 2 is methoxy.
Claim 14
Dependent Claim
16 words
A process according to claim 12 wherein R 1 is the ethylene, trimethylene or tetramethylene radical.
Claim 15
Dependent Claim
13 words
A process according to claim 13 wherein R 2 is an aromatic radical.
Claim 16
Dependent Claim
19 words
A process according to claim 14 wherein the dihydroxyaromatic compound from which R 3 is derived is bisphenol A.
Claim 17
Dependent Claim
13 words
A process according to claim 15 wherein the poly(alkylene dicarboxylate) is a terephthalate.
Claim 18
Dependent Claim
26 words
A process according to claim 4 wherein the acid derivative is methyl salicylate, ethyl salicylate, phenyl salicylate, salicylamide, glycine, malic acid, mandelic acid or dibutyl tartrate.
Claim 19
Dependent Claim
16 words
A process according to claim 17 wherein R 1 is the ethylene, trimethylene or tetramethylene radical.
Claim 20
Dependent Claim
13 words
A process according to claim 18 wherein R 2 is an aromatic radical.
Claim 21
Dependent Claim
19 words
A process according to claim 19 wherein the dihydroxyaromatic compound from which R 3 is derived is bisphenol A.
Claim 22
Dependent Claim
13 words
A process according to claim 20 wherein the poly(alkylene dicarboxylate) is a terephthalate.
Claim 23
Dependent Claim
18 words
A stabilized composition prepared by the process of any one of claims 1, 9-11, 15, 16 and 18-21.
References Cited (Backward Citations)
US2214405A
Cited
US3218372A
Cited
US3386935A
Cited
GB1022958A
Cited
US3491057A
Cited
US3594448A
Cited
US3998796A
Cited
US3943100A
Cited
US4044073A
Cited
US4147738A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-06-05 | 1987-12-05 | 1988-06-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-06-05 | 1991-12-05 | 1992-06-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-06-05 | 1995-12-05 | 1996-06-05 | $7700.00 | Window Closed / Lapsed |