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US4452933A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized polyester-polycarbonate blends and stabilization process therefor

Assignee: General Electric Co
•
Filing: 1983-06-09
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Granted: 1984-06-05
•
Expires: 2003-06-09
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Abstract

Abstract Ester-carbonate interchange in blends of aromatic polycarbonates and poly(alkylene dicarboxylates) is inhibited by adding thereto a hydroxy- or amino-substituted carboxylic acid derivative such as methyl salicylate, malic acid, glycine or dibutyl tartrate.

Inventors

  • 👤 Russell J. McCready

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:34
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13; C08K5/134; C08K5/1345; C08K5/16; C08K5/20; C08L; C08L67/00; C08L67/02; C08L69/00

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 159 words
A process for stabilizing a composition comprising at least one poly(alkylene dicarboxylate) prepared by the reaction of at least one alkenediol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a titanium compound as catalyst and at least one aromatic polycarbonate, which comprises adding thereto an amount effective to inhibit ester-carbonate interchange of at least one α-hydroxy or α-amino aliphatic acid derivative, or o-hydroxy or σ-amino aromatic acid derivative, of the formula ##STR6## wherein: X 1 is 0 or NH; X 2 or OR 5 when X 1 is NH and is OR 5 or NHR 5 when X 1 is 0; Z is CH or a single-ring aromatic carbocyclic radical in which the X 1 H and ##STR7## moieties occupy ortho positions; R 4 is hydrogen, a lower alkyl radical or a lower aryl radical which optionally contains hydroxy or COOR 5 substituents; and R 5 is hydrogen, lower alkyl or lower aryl.
Claim 2
Dependent Claim 159 words
A process for stabilizing a composition comprising at least one poly(alkylene dicarboxylate) prepared by the reaction of at least one alkenediol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a titanium compound as catalyst and at least one aromatic polycarbonate, which comprises adding thereto an amount effective to inhibit ester-carbonate interchange of at least one α-hydroxy or α-amino aliphatic acid derivative, or o-hydroxy or σ-amino aromatic acid derivative, of the formula ##STR6## wherein: X 1 is 0 or NH; X 2 or OR 5 when X 1 is NH and is OR 5 or NHR 5 when X 1 is 0; Z is CH or a single-ring aromatic carbocyclic radical in which the X 1 H and ##STR7## moieties occupy ortho positions; R 4 is hydrogen, a lower alkyl radical or a lower aryl radical which optionally contains hydroxy or COOR 5 substituents; and R 5 is hydrogen, lower alkyl or lower aryl.
Claim 3
Dependent Claim 35 words
A process according to claim 1 wherein the polycarbonate comprises repeating units of the formula ##STR8## wherein R 3 is a divalent aromatic radical derived from a dihydroxyaromatic compound of the formula HO--R 3 --OH.
Claim 4
Dependent Claim 54 words
A process according to claim 2 wherein the poly(alkylene dicarboxylate) comprises units of the formula ##STR9## wherein R 1 is a saturated divalent aliphatic hydrocarbon radical containing about 2-10 carbon atoms and R 2 is a divalent aliphatic radical containing about 2-20 carbon atoms or a divalent aromatic radical containing about 6-20 carbon atoms.
Claim 5
Dependent Claim 22 words
A process according to claim 3 wherein the weight ratio of poly(alkylene dicarboxylate) to polycarbonate is from about 99:1 to about 1:99.
Claim 6
Dependent Claim 16 words
A process according to claim 4 wherein R 1 is the ethylene, trimethylene or tetramethylene radical.
Claim 7
Dependent Claim 13 words
A process according to claim 5 wherein R 2 is an aromatic radical.
Claim 8
Dependent Claim 19 words
A process according to claim 6 wherein the dihydroxyaromatic compound from which R 3 is derived is bisphenol A.
Claim 9
Dependent Claim 13 words
A process according to claim 7 wherein the poly(alkylene dicarboxylate) is a terephthalate.
Claim 10
Dependent Claim 11 words
A process according to claim 4 wherein X 1 is 0.
Claim 11
Dependent Claim 18 words
A process according to claim 9 wherein X 2 is OR 5 and R 5 is lower alkyl.
Claim 12
Dependent Claim 19 words
A process according to claim 10 wherein Z is a single-ring aromatic carboxylic radical and R 4 is hydrogen.
Claim 13
Dependent Claim 11 words
A process according to claim 11 wherein X 2 is methoxy.
Claim 14
Dependent Claim 16 words
A process according to claim 12 wherein R 1 is the ethylene, trimethylene or tetramethylene radical.
Claim 15
Dependent Claim 13 words
A process according to claim 13 wherein R 2 is an aromatic radical.
Claim 16
Dependent Claim 19 words
A process according to claim 14 wherein the dihydroxyaromatic compound from which R 3 is derived is bisphenol A.
Claim 17
Dependent Claim 13 words
A process according to claim 15 wherein the poly(alkylene dicarboxylate) is a terephthalate.
Claim 18
Dependent Claim 26 words
A process according to claim 4 wherein the acid derivative is methyl salicylate, ethyl salicylate, phenyl salicylate, salicylamide, glycine, malic acid, mandelic acid or dibutyl tartrate.
Claim 19
Dependent Claim 16 words
A process according to claim 17 wherein R 1 is the ethylene, trimethylene or tetramethylene radical.
Claim 20
Dependent Claim 13 words
A process according to claim 18 wherein R 2 is an aromatic radical.
Claim 21
Dependent Claim 19 words
A process according to claim 19 wherein the dihydroxyaromatic compound from which R 3 is derived is bisphenol A.
Claim 22
Dependent Claim 13 words
A process according to claim 20 wherein the poly(alkylene dicarboxylate) is a terephthalate.
Claim 23
Dependent Claim 18 words
A stabilized composition prepared by the process of any one of claims 1, 9-11, 15, 16 and 18-21.

References Cited (Backward Citations)

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US3218372A Cited
US3386935A Cited
GB1022958A Cited
US3491057A Cited
US3594448A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-06-05 1987-12-05 1988-06-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-06-05 1991-12-05 1992-06-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-06-05 1995-12-05 1996-06-05 $7700.00 Window Closed / Lapsed

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