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US4451601A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass-filled polyarylene sulfide compositions containing organosilanes

Assignee: Phillips Petroleum Co
•
Filing: 1983-02-09
•
Granted: 1984-05-29
•
Expires: 2003-02-09
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Abstract

Abstract Properties such as flow rate and hydrolytic stability of glass-filled polyarylene sulfide compositions can be modified by the addition of certain organosilanes.

Inventors

  • 👤 Jennings P. Blackwell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:02
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 59 words
A composition comprising: glass-filled polyarylene sulfide and at least one organosilane in an amount sufficient to decrease the flow rate of said polyarylene sulfide upon heating of the composition to a temperature at least about the melting point of said polyarylene sulfide; wherein said at least one organosilane is selected from the group consisting of 1-Benzylchloro-2-trimethoxysilylethane, 2-p-Sulfoxylazylethyltrimethoxysilane, and (p-Aminophenyl)trimethoxysilane.
Claim 2
Dependent Claim 59 words
A composition comprising: glass-filled polyarylene sulfide and at least one organosilane in an amount sufficient to decrease the flow rate of said polyarylene sulfide upon heating of the composition to a temperature at least about the melting point of said polyarylene sulfide; wherein said at least one organosilane is selected from the group consisting of 1-Benzylchloro-2-trimethoxysilylethane, 2-p-Sulfoxylazylethyltrimethoxysilane, and (p-Aminophenyl)trimethoxysilane.
Claim 3
Dependent Claim 19 words
A composition in accordance with claim 1 wherein said organosilane is 1-Benzylchloro-2-trimethoxysilylethane and said polyarylene sulfide is polyphenylene sulfide.
Claim 4
Dependent Claim 19 words
A composition in accordance with claim 1 wherein said organosilane is 2-p-Sulfoxylazylethyltrimethoxysilane and said polyarylene sulfide is polyphenylene sulfide.
Claim 5
Dependent Claim 19 words
A composition in accordance with claim 1 wherein said organosilane is (p-Aminophenyl)trimethoxysilane and said polyarylene sulfide is polyphenylene sulfide.
Claim 6
Dependent Claim 24 words
A composition according to claim 1 wherein the amount of said organosilane is about 0.2 to about 2 weight percent based upon total composition.
Claim 7
Independent Claim 72 words
A method for decreasing the flow rate of a glass-filled polyarylene sulfide, said method comprising: (a) combining glass, polyarylene sulfide and at least one organosilane selected from the group consisting of 1-Benzylchloro-2-trimethoxysilylethane, 2-p-Sulfoxylazylethyltrimethoxysilane, and (p-Aminophenyl)trimethoxysilane to produce a mixture; and (b) subjecting said mixture to a temperature of at least about the melting point of said polyarylene sulfide for a time sufficient to effect at least a partial cure of said mixture.
Claim 8
Independent Claim 72 words
A method for decreasing the flow rate of a glass-filled polyarylene sulfide, said method comprising: (a) combining glass, polyarylene sulfide and at least one organosilane selected from the group consisting of 1-Benzylchloro-2-trimethoxysilylethane, 2-p-Sulfoxylazylethyltrimethoxysilane, and (p-Aminophenyl)trimethoxysilane to produce a mixture; and (b) subjecting said mixture to a temperature of at least about the melting point of said polyarylene sulfide for a time sufficient to effect at least a partial cure of said mixture.
Claim 9
Dependent Claim 14 words
A method in accordance with claim 6 wherein said polyarylene sulfide is polyphenylene sulfide.
Claim 10
Dependent Claim 21 words
A method in accordance with claim 7 wherein said mixture is extruded at a temperature of at least about 550° F.
Claim 11
Dependent Claim 27 words
A method in accordance with claim 7 wherein the weight percentage, based upon total composition, of said at least one organosilane is about 0.2 to about 2.
Claim 12
Dependent Claim 12 words
A method in accordance with claim 7 wherein said organosilane is 1-Benzylchloro-2-trimethoxysilylethane.
Claim 13
Dependent Claim 12 words
A method in accordance with claim 7 wherein said organosilane is 2-p-Sulfoxylazylethyltrimethoxysilane.
Claim 14
Dependent Claim 12 words
A method in accordance with claim 7 wherein said organosilane is (p-Aminophenyl)trimethoxysilane.
Claim 15
Dependent Claim 9 words
A composition produced by the method of claim 6.
Claim 16
Dependent Claim 9 words
A composition produced by the method of claim 7.
Claim 17
Dependent Claim 9 words
A composition produced by the method of claim 8.
Claim 18
Dependent Claim 9 words
A composition produced by the method of claim 9.
Claim 19
Dependent Claim 9 words
A composition produced by the method of claim 10.
Claim 20
Dependent Claim 9 words
A composition produced by the method of claim 11.
Claim 21
Dependent Claim 9 words
A composition produced by the method of claim 12.

References Cited (Backward Citations)

US3484333A Cited
US3864203A Cited
JPS5252958A Cited
US4244860A Cited
US4284549A Cited
US4350786A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-29 1987-11-28 1988-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-29 1991-11-28 1992-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-29 1995-11-28 1996-05-29 $7700.00 Window Closed / Lapsed

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