US4451442A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Removal of hydrogen sulfide from fluid streams with minimum production of solids
Assignee: Dow Chemical Co
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Filing: 1982-06-21
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Granted: 1984-05-29
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Expires: 2002-06-21
Abstract
Abstract Fluid streams containing hydrogen sulfide from a steam turbine or from a sour gas stream are contacted with an aqueous solution of a polyvalent metal chelate and an oxidizing agent whereby the hydrogen sulfide is converted to free sulfur and then to soluble sulfur compounds. The metal chelate is reduced to a lower oxidation state metal chelate and reduced metal chelate is subsequently oxidized with air back to the higher oxidation state and reused.
Inventors
- 👤 Gaines C. Jeffrey
- 👤 Lance A. Cooper
- 👤 Sharon S. Whipple
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 07:48
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493; B01D53/1425; B01D53/1456; B01D53/1462; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; Y; Y02; Y02P; Y02P20/00; Y02P20/151; Y10; Y10S; Y10S423/00; Y10S423/19
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
136 words
A continuous process for removing hydrogen sulfide from a fluid stream containing hydrogen sulfide which comprises (A) contacting said stream in a first reaction zone with an aqueous solution at a pH range suitable for removing hydrogen sulfide whereby said solution contains an effective amount of a polyvalent metal chelate and an effective amount of an oxidizing agent capable of oxidizing elemental sulfur to soluble sulfur compounds whereby said hydrogen sulfide is converted to free sulfur and then to soluble sulfur compounds and said polyvalent metal chelate is reduced to a lower oxidation state metal chelate, (B) contacting said solution containing reduced polyvalent metal chelate in a second reaction zone with a oxygen containing gas stream whereby said metal chelate is continuously reoxidized, and (C) continuously recirculating said reoxidized solution back to said first reaction zone.
Claim 2
Dependent Claim
136 words
A continuous process for removing hydrogen sulfide from a fluid stream containing hydrogen sulfide which comprises (A) contacting said stream in a first reaction zone with an aqueous solution at a pH range suitable for removing hydrogen sulfide whereby said solution contains an effective amount of a polyvalent metal chelate and an effective amount of an oxidizing agent capable of oxidizing elemental sulfur to soluble sulfur compounds whereby said hydrogen sulfide is converted to free sulfur and then to soluble sulfur compounds and said polyvalent metal chelate is reduced to a lower oxidation state metal chelate, (B) contacting said solution containing reduced polyvalent metal chelate in a second reaction zone with a oxygen containing gas stream whereby said metal chelate is continuously reoxidized, and (C) continuously recirculating said reoxidized solution back to said first reaction zone.
Claim 3
Dependent Claim
35 words
The process as set forth in claim 1 wherein the amount of metal chelate is from about stoichiometric based on the hydrogen sulfide absorbed to the solubility limit of said metal chelate in said solution.
Claim 4
Dependent Claim
31 words
The process as set forth in claim 1 wherein the amount of oxidizing agent is from about stoichiometric based on the free sulfur formed to about five times the stoichiometric amount.
Claim 5
Dependent Claim
16 words
The process as set forth in claim 1 wherein the pH ranges from 5 to 11.
Claim 6
Dependent Claim
26 words
The process as set forth in claim 1 wherein the reaction zones are maintained at a temperature in the range from about 0° to 95° C.
Claim 7
Dependent Claim
30 words
The process as set forth in claim 1 wherein the oxidizing agent is selected from the group consisting of sulfur dioxide and the alkali metal salts of inorganic oxidizing acids.
Claim 8
Dependent Claim
26 words
The process as set forth in claim 6 wherein the oxidizing acids are selected from the group consisting of sulfurous, perchloric, cloric, hypochlorous and permanganic acids.
Claim 9
Dependent Claim
16 words
The process as set forth in claim 1 wherein said fluid stream is a geothermal stream.
Claim 10
Dependent Claim
17 words
The process as set forth in claim 1 wherein said fluid stream is a sour gas stream.
Claim 11
Dependent Claim
17 words
The process as set forth in claim 1 wherein said polyvalent metal chelate is an iron chelate.
Claim 12
Dependent Claim
18 words
The process of claim 10 wherein the iron chelate is a chelate of iron with a aminopolycarboxylic acid.
Claim 13
Dependent Claim
40 words
The process of claim 11 wherein the aminopolycarboxylic acid is selected from the group consisting of ethylenediaminetetraacetic acid, diethylenetriamine pentaacetic acid, N-hydroxyethylethylene diamine triacetic acid, diethylenetriamine pentaacetic acid, cyclohexene diamene tetraacetic acid, triethylenetetraamine hexaacetic acid, nitrilotriacetic acid, and N-hydroxyethyliminodiacetic acid.
Claim 14
Dependent Claim
19 words
The process of claim 10 wherein the iron chelate is a chelate of iron with an amine phosphonic acid.
Claim 15
Dependent Claim
29 words
The process of claim 13 wherein the amine phosphonic acid is selected from the group consisting of ethylenediamine tetra(methylene phosphonic acid), aminotri(methylene phosphonic acid), and diethylenetriamine penta(methylene phosphonic acid).
Claim 16
Dependent Claim
18 words
The process of claim 10 wherein the iron chelate is a chelate of iron with an phosphonate acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-29 | 1987-11-28 | 1988-05-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-29 | 1991-11-28 | 1992-05-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-29 | 1995-11-28 | 1996-05-29 | $7700.00 | Window Closed / Lapsed |