US4011304A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for controlling removal of hydrogen sulfide from gases
Assignee: Air Resources Inc
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Filing: 1975-03-05
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Granted: 1977-03-08
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Expires: 1995-03-05
Abstract
Abstract Hydrogen sulfide is removed from a gas stream in an oxidation-reduction system by contacting the gas stream with an aqueous chelated iron solution in which the iron is in the ferric state to absorb hydrogen sulfide and convert it to elemental sulfur. The solution is regenerated by aeration. A redox electrode is used to monitor the oxidation potential of the solution, and corrective action is taken, as required, to maintain the concentration of ferric iron in the solution so as to achieve efficient removal of hydrogen sulfide.
Inventors
- 👤 Robert A. Mancini
- 👤 David M. Cyr
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 20:01
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; Y; Y10; Y10S; Y10S423/00; Y10S423/05
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
227 words
In a process for the removal of hydrogen sulfide from a gas in an oxidation-reduction system by contacting the gas with a chelated iron solution comprising an aqueous solution of iron complexed with at least one chelating agent, whereby iron in the ferric state oxidizes the hydrogen sulfide to elemental sulfur and is reduced to the ferrous state, separating sulfur from said solution, and regenerating said solution by aeration to oxidize the iron to the ferric state; the improved method of regulating the redox potential of the solution in the system to obtain a hydrogen sulfide removal efficiency of at least about 85%, which comprises: a. effecting addition for fresh chelated iron solution to the system and withdrawal of used solution from the system so as to increase the ratio of ferric ions to ferrous ions and thereby increase the redox potential of the solution in the system; b. maintaining a substantially constant volume of solution in the system; c. maintaining substantially the maximum rate of aeration of the solution; d. measuring the redox potential of the solution in the system by means of a redox electrode; and e. controlling said addition of fresh solution and said withdrawal of used solution to maintain said redox potential of the solution in the system at not less than a predetermined minimum required to maintain the activity of the solution.
Claim 2
Dependent Claim
227 words
In a process for the removal of hydrogen sulfide from a gas in an oxidation-reduction system by contacting the gas with a chelated iron solution comprising an aqueous solution of iron complexed with at least one chelating agent, whereby iron in the ferric state oxidizes the hydrogen sulfide to elemental sulfur and is reduced to the ferrous state, separating sulfur from said solution, and regenerating said solution by aeration to oxidize the iron to the ferric state; the improved method of regulating the redox potential of the solution in the system to obtain a hydrogen sulfide removal efficiency of at least about 85%, which comprises: a. effecting addition for fresh chelated iron solution to the system and withdrawal of used solution from the system so as to increase the ratio of ferric ions to ferrous ions and thereby increase the redox potential of the solution in the system; b. maintaining a substantially constant volume of solution in the system; c. maintaining substantially the maximum rate of aeration of the solution; d. measuring the redox potential of the solution in the system by means of a redox electrode; and e. controlling said addition of fresh solution and said withdrawal of used solution to maintain said redox potential of the solution in the system at not less than a predetermined minimum required to maintain the activity of the solution.
Claim 3
Dependent Claim
53 words
The process of claim 1 further characterized in that said solution contains (A) at least one chelating agent capable of binding iron in the ferrous state to prevent precipitation of ferrous sulfide and (B) at least one chelating agent capable of binding iron in the ferric state to prevent precipitation of ferric hydroxide.
Claim 4
Dependent Claim
77 words
The process of claim 2 further characterized in that said first-named chelating agent (A) is selected from the group consisting of the polyamino polycarboxylic acids and their alkali metal salts, the polyamino hydroxyethyl polycarboxylic acids and their alkali metal salts, the polyphosphonomethyl amines and their alkali metal salts, and mixtures of the foregoing, and said second-named chelating agent (B) is selected from the group consisting of sugars, reduced sugars, and sugar acids and their alkali metal salts.
Claim 5
Dependent Claim
64 words
The process of claim 2 further characterized in that said first-named chelating agent (A) is selected from the group consisting of the polyamino polyacetic acids and their alkali metal salts, the polyamino hydroxyethyl polyacetic acids and their alkali metal salts and mixtures of the foregoing, and said second-named chelating agent (B) is a reduced sugar selected from the group consisting of sorbitol and mannitol.
Claim 6
Dependent Claim
38 words
The process of claim 2 further characterized in that said first-named chelating agent comprises a mixture of the sodium salts of ethylene diamine tetra-acetic acid and N-hydroxyethyl ethylene diamine triacetic acid, and said second-named chelating agent comprises sorbitol.
Claim 7
Dependent Claim
40 words
The process of claim 5 further characterized in that said solution contains sufficient alkaline material selected from the group consisting of sodium hydroxide, sodium carbonate, and mixtures thereof to provide a solution pH of from about 8 to about 10.5.
Claim 8
Dependent Claim
30 words
The process of claim 5 further characterized in that said solution has a molar ratio of said first-named chelating agent to iron in said solution of not greater than 2:1.
Claim 9
Dependent Claim
55 words
The process of claim 5 further characterized in that said solution has an iron content of from about 200 to about 5000 ppm by weight, and said redox potential relative to the normal hydrogen electrode, as measured by a platinum redox electrode, is maintained at not less than from about -215 to about -250 millivolts.
Claim 10
Dependent Claim
82 words
The process of claim 5 further characterized in that: said solution has an iron content of from about 200 to about 5000 ppm by weight, a pH of from about 8 to about 10.5, and a molar ratio of said first-named chelating agent to iron of from about 1:1 to about 1.5:1, and said redox potential relative to the normal hydrogen electrode, as measured by a platinum redox electrode, is maintained at not less than from about -215 to about -250 millivolts.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-07 | 1980-09-06 | 1981-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-07 | 1984-09-06 | 1985-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-07 | 1988-09-06 | 1989-03-08 | $7700.00 | Window Closed / Lapsed |