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US4450246A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel polyurethane catalysts in polyurethane foam process

Assignee: WR Grace and Co Conn
•
Filing: 1982-10-26
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Granted: 1984-05-22
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Expires: 2002-10-26
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Abstract

Abstract A process for producing a polyurethane foam by reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of a catalytic amount of specific amine compounds of the formula: <IMAGE> or <IMAGE> wherein R1 is a methyl or ethyl and R2 is hydrogen or methyl such that when R1 is methyl, R2 is methyl and when R1 is ethyl, R2 is hydrogen, X is an organic mono or dicarboxylic acid and n is an integer from 0 to 1.

Inventors

  • 👤 Felek Jachimowicz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:32
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/18; C08G18/1875; C08G18/20; C08G18/2009; C08G18/2018

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 100 words
A process for forming a polyurethane comprising reacting an organic polyisocyanate with a polyol selected from an organic polyether polyol or polyester polyol in the presence of a catalytic amount of an amine selected from the group having the structural formula: ##STR3## wherein R 1 is a methyl or ethyl group and R 2 is a hydrogen or methyl group such that when R 1 is methyl, R 2 is methyl and when R 1 is ethyl, R 2 is hydrogen, X is an organic mono or dicarboxylic acid and n is a number from 0 to up to 1.
Claim 2
Dependent Claim 100 words
A process for forming a polyurethane comprising reacting an organic polyisocyanate with a polyol selected from an organic polyether polyol or polyester polyol in the presence of a catalytic amount of an amine selected from the group having the structural formula: ##STR3## wherein R 1 is a methyl or ethyl group and R 2 is a hydrogen or methyl group such that when R 1 is methyl, R 2 is methyl and when R 1 is ethyl, R 2 is hydrogen, X is an organic mono or dicarboxylic acid and n is a number from 0 to up to 1.
Claim 3
Dependent Claim 18 words
The process of claim 1 wherein R 1 and R 2 are each methyl and n is 0.
Claim 4
Dependent Claim 22 words
The process of claim 1 wherein R 1 and R 2 are each methyl and n is a number up to 1.
Claim 5
Dependent Claim 22 words
The process of claim 3 wherein X is selected from formic acid, adipic acid, fumaric acid, 2-ethyl hexanoic acid and mixtures thereof.
Claim 6
Dependent Claim 18 words
The process of claim 1 wherein R 1 is ethyl, R 2 is hydrogen and n is 0.
Claim 7
Dependent Claim 22 words
The process of claim 1 wherein R 1 is ethyl, R 2 is hydrogen and n is a number up to 1.
Claim 8
Dependent Claim 22 words
The process of claim 6 wherein X is selected from formic acid, adipic acid, fumaric acid, 2-ethyl hexanoic acid and mixtures thereof.
Claim 9
Dependent Claim 26 words
The process of claim 1 wherein the catalyst is present in from about 0.05 to 5 percent by weight based on the weight of polyol present.
Claim 10
Dependent Claim 26 words
The process of claim 2 wherein the catalyst is present in from about 0.05 to 5 percent by weight based on the weight of polyol present.
Claim 11
Dependent Claim 26 words
The process of claim 4 wherein the catalyst is present in from about 0.05 to 5 percent by weight based on the weight of polyol present.
Claim 12
Dependent Claim 26 words
The process of claim 5 wherein the catalyst is present in from about 0.05 to 5 percent by weight based on the weight of polyol present.
Claim 13
Dependent Claim 26 words
The process of claim 7 wherein the catalyst is present in from about 0.05 to 5 percent by weight based on the weight of polyol present.
Claim 14
Dependent Claim 28 words
The process of claim 1 wherein the reaction is carried out in the presence of from 0.5 to 50 weight percent blowing agent based on weight of polyol.
Claim 15
Dependent Claim 28 words
The process of claim 2 wherein the reaction is carried out in the presence of from 0.5 to 50 weight percent blowing agent based on weight of polyol.
Claim 16
Dependent Claim 28 words
The process of claim 3 wherein the reaction is carried out in the presence of from 0.5 to 50 weight percent blowing agent based on weight of polyol.
Claim 17
Dependent Claim 28 words
The process of claim 5 wherein the reaction is carried out in the presence of from 0.5 to 50 weight percent blowing agent based on weight of polyol.
Claim 18
Dependent Claim 28 words
The process of claim 6 wherein the reaction is carried out in the presence of from 0.5 to 50 weight percent blowing agent based on weight of polyol.
Claim 19
Dependent Claim 26 words
The process of claim 3 wherein said reaction of polyol and polyisocyanate is carried out in a reaction zone suitable for forming a flat-top bun product.
Claim 20
Dependent Claim 26 words
The process of claim 6 wherein said reaction of polyol and polyisocyanate is carried out in a reaction zone suitable for forming a flat-top bun product.

References Cited (Backward Citations)

US3136731A Cited
US3320190A Cited
US3476933A Cited
US3769244A Cited
DE2363324A1 Cited
US4165412A Cited
DE2947648A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-22 1987-11-21 1988-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-22 1991-11-21 1992-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-22 1995-11-21 1996-05-22 $7700.00 Window Closed / Lapsed

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