Electrophotographic photoreceptor with thiobarbituric acid derivative

Claim 2

An electrophotographic photoreceptor comprising an electrophotographic photoreceptive layer containing a charge generating material and a charge transporting material, said charge generating material being a compound which has a barbituric acid nucleus or a thiobarbituric acid nucleus represented by the following general formula (I): ##STR4## wherein n represents 0, 1 or 2; X represents an oxygen atom or a sulfur atom; R 1 and R 2 independently represent a hydrogen atom, an alkyl group, an aralkyl group or an aryl group; R 3 and R 4 independently represent a hydrogen atom, an alkyl group, an aralkyl group or a phenyl group, wherein the alkyl, aralkyl or phenyl groups may be substituted; and A represents a divalent group derived from a heterocyclic ring selected from a group consisting of imidazoles, 3H-indoles, thiazoles, benzothiazoles, naphthothiazoles, thianaphtheno-7',6',4,5-thiazoles, oxazoles, benzoxazoles, naphthoxazoles, selenazoles, benzoselenazoles, naphthoselenazoles, thiazolines, quinolines, isoquinolines, benzimidazoles and pyridines.

Claim 3

The electrophotographic photoreceptor as claimed in claim 1, wherein said electrophotographic photoreceptive layer consists of a single layer containing the charge generating material, the charge transporting material, and a binder.

Claim 4

The electrophotographic photoreceptor as claimed in claim 1, wherein said electrophotographic photoreceptive layer consists of the combination of a charge generating layer containing the charge generating material and a charge transporting layer containing the charge transporting material.

Claim 5

An electrophotographic photoreceptor as claimed in claim 2, wherein the thickness of the photoreceptive layer is from 3 to 50 μm.

Claim 6

An electrophotographic photoreceptor as claimed in claim 2, wherein the thickness of the photoreceptive layer is from 5 to 20 μm.

Claim 7

An electrophotographic photoreceptor as claimed in claim 3, wherein the thickness of the charge transporting layer is from 3 to 50 μm.

Claim 8

An electrophotographic photoreceptor as claimed in claim 3, wherein the thickness of the charge transporting layer is from 5 to 20 μm.

Claim 9

An electrophotographic photoreceptor as claimed in claim 3, wherein the thickness of the charge generating layer is 5 μm or less.

Claim 10

An electrophotographic photoreceptor as claimed in claim 3, wherein the thickness of the charge generating layer is 2 μm or less.

Claim 11

An electrophotographic photoreceptor as claimed in claim 2, wherein the charge transporting material in the photoreceptive layer is contained in an amount of 10 to 150 wt.% with respect to the binder, and further wherein the proportion of the compound having a thiobarbituric acid nucleus in the photoreceptive layer is 1 to 150 wt% with respect to the binder.

Claim 12

An electrophotographic photoreceptor as claimed in claim 2, wherein the proportion of the charge transporting material in the photoreceptive layer is 30 to 100 wt% with respect to the binder, and further wherein the proportion of the compound having a thiobarbituric acid nucleus in the photoreceptive layer is 5 to 50 wt% with respect to the binder.

Claim 13

An electrophotographic photoreceptor as claimed in claim 3, wherein the proportion of the charge transporting material in the charge transporting layer is 30 to 100 wt% with respect to the binder, and further wherein the proportion of the binder in the charge generating layer is 10 parts by weight or less with respect to 1 part by weight of the compound having a thiobarbituric acid nucleus in the case of the compound being dispersed in the binder.

Claim 14

An electrophotographic photoreceptor comprising an electrophotographic photoreceptive layer containing a charge generating material and a charge transporting material, said charge generating material being dispersed homogeneously in said layer and a compound which has a barbituric acid nucleus or a thiobarbituric acid nucleus represented by the following general formula (I): ##STR5## wherein n represents 0, 1 or 2; X represents an oxygen atom or a sulfur atom; R 1 and R 2 independently represent a hydrogen atom, an alkyl group, an aralkyl group or an aryl group; R 3 and R 4 independently represent a hydrogen atom, an alkyl group, an aralkyl group or a phenyl group, wherein the alkyl, aralkyl or phenyl groups may be substituted; and A represents a divalent group derived from a heterocyclic ring selected from a group consisting of imidazoles, 3H-indoles, thiazoles, benzothiazoles, naphthothiazoles, thianaphtheno-7', 6', 4,5-thiazoles, oxazoles, benzoxazoles, naphthoxazoles, selenazoles, benzoselenazoles, naphthoselenazoles, thiazolines, quinolines, isoquinolines, benzimidazoles and pyridines.

Claim 15

An electrophotographic photoreceptor comprising an electrophotographic photoreceptive layer containing a charge generating material and a charge transporting material, said charge generating material being dispersed homogeneously in said layer and a compound which has a barbituric acid nucleus or a thiobarbituric acid nucleus represented by the following general formula (I): ##STR5## wherein n represents 0, 1 or 2; X represents an oxygen atom or a sulfur atom; R 1 and R 2 independently represent a hydrogen atom, an alkyl group, an aralkyl group or an aryl group; R 3 and R 4 independently represent a hydrogen atom, an alkyl group, an aralkyl group or a phenyl group, wherein the alkyl, aralkyl or phenyl groups may be substituted; and A represents a divalent group derived from a heterocyclic ring selected from a group consisting of imidazoles, 3H-indoles, thiazoles, benzothiazoles, naphthothiazoles, thianaphtheno-7', 6', 4,5-thiazoles, oxazoles, benzoxazoles, naphthoxazoles, selenazoles, benzoselenazoles, naphthoselenazoles, thiazolines, quinolines, isoquinolines, benzimidazoles and pyridines.

Claim 16

The electrophotographic photoreceptor as claimed in claim 2, wherein the binder is at least one member selected from the group consisting of a polyamide resin, a polyurethane resin, a polyester resin, and epoxy resin, a polyketone resin, a polycarbonate resin, polyvinyl ketone, polystyrene, poly-N-vinylcarbazole, or polyacrylamide.

Claim 17

The electrophotographic photoreceptor as claimed in claim 1, wherein the charge transporting material is at least one member selected from the group consisting of triphenylamine derivatives, polyarylalkane derivatives, pyrazoline derivatives and hydrazone derivatives.