Photoconductive composition sensitized by a thiobarbituric acid derivative

Claim 2

A photoconductive composition comprising a mixture of a photoconductive substance and a thiobarbituric acid derivative in a sensitizing amount represented by the formula (I): ##STR20## wherein R 1 is an alkyl group containing 1 to 12 carbon atoms, an alkoxyl group containing 1 to 5 carbon atoms, or a phenyl group; X is a hydrogen atom, a halogen atom, a cyano group or a nitro group; Ar is a divalent, trivalent or tetravalent group derived from benzene, naphthalene, pyridine, furan or thiophene; and n is 1, 2 or 3, wherein the photoconductive substance is a polymer with a pi electron system in a main or side chain thereof.

Claim 3

The photoconductive composition as claimed in claim 1, wherein the thiobarbituric acid derivative is present in said mixture in an amount of 0.02 to 1.5 moles per mole of the constitutional repeating unit containing the π electron system present in the photoconductive polymer.

Claim 4

The photoconductive composition as claimed in claims 1 or 2, wherein said alkyl group for R 1 is a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, an octyl group, a nonyl group, a decyl group, a dodecyl group, an isopropyl group, an isobutyl group, an isoamyl group, a chloromethyl group, a chloroethyl group or a hydroxyethyl group, said alkoxyl group for R 1 is a methoxy group, an ethoxy group or a propoxy group, said halogen atom for X is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom and said Ar is an m-phenylene group, a p-phenylene group, a 1,2,4-benzenetriyl group, a 1,2-naphthalene group, a 2,4-pyridinediyl group, a 2,5-furandiyl group or a 2,5-thiophenediyl group.

Claim 5

The photoconductive composition as claimed in claims 1 or 2, wherein R 1 is a methyl group, an ethyl group or a phenyl group, X is a hydrogen atom, a chlorine atom, a bromine atom, a cyano group or a nitro group, n is 1 or 2, and Ar is a p-phenylene group, a 2,4-pyridinediyl group, a 2,5-furandiyl group or a 2,5-thiophenediyl group.

Claim 6

The photoconductive composition as claimed in claims 1 or 2, wherein said thiobarbituric derivative represented by the formula (I) is 5-(4'-cyanobenzylidene)-1,3-diethylthiobarbituric acid, 5-(4'-nitrobenzylidene)-1,3-diethylthiobarbituric acid or 5-(5'-nitrofurfurylidene)-1,3-diethylthiobarbituric acid.

Claim 7

An electrophotographic light-sensitive medium comprising a support with an electrically conductive surface thereon and a layer of the photoconductive composition as claimed in claims 1 or 2.

Claim 8

The electrophotographic light-sensitive medium as claimed in claim 6 wherein said alkyl group for R 1 is a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, an octyl group, a nonyl group, a decyl group, a dodecyl group, an isopropyl group, an isobutyl group, an isoamyl group, a chloromethyl group, a chloroethyl group or a hydroxyethyl group, said alkoxyl group for R 1 is a methoxy group, an ethoxy group or a propoxy group, said halogen atom for X is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom and said Ar is a m-phenylene group, a p-phenylene group, a 1,2,4-benzenetriyl group, a 1,2-naphthalene group, a 2,4-pyridinediyl group, a 2,5-furandiyl group or a 2,5-thiophenediyl group.

Claim 9

The electrophotographic light-sensitive medium as claimed in claim 6, wherein R 1 is a methyl group, an ethyl group or a phenyl group, X is a hydrogen atom, a chlorine atom, a bromine atom, a cyano group or a nitro group, n is 1 or 2, and Ar is a p-phenylene group, a 2,4-pyridinediyl group, a 2,5-furandiyl group or a 2,5-thiophenediyl group.

Claim 10

The electrophotographic light-sensitive medium as claimed in claim 6, wherein said thiobarbituric derivative represented by the formula (I) is 5-(4'-cyanobenzylidene)-1,3-diethylthiobarbituric acid, 5-(4'-nitrobenzylidene)-1,3-diethylthiobarbituric acid or 5-(5'-nitrofurfurylidene)-1,3-diethylthiobarbituric acid.

Claim 11

The electrophotographic light-sensitive medium as claimed in claim 6, wherein the π electron system is present in a moiety derived from an aromatic hydrocarbon selected from the group consisting of naphthalene, anthracene, pyrene, perylene, acenaphthene, phenylanthracene, and diphenylanthracene or derived from a heterocyclic selected from the group consisting of carbazole, indole, acridine, 2-phenyl indole, N-phenylcarbazole, their halogen atom derivatives, and their lower alkyl group derivatives.

Claim 12

The electrophotographic light-sensitive medium as claimed in claim 6, wherein said photoconductive substance is a poly-N-vinyl carbazole or an N-vinyl carbazole copolymer.

Claim 13

The photoconductive composition as claimed in claims 1 or 2, wherein X is the cyano group.

Claim 14

The photoconductive composition as claimed in claims 1 or 2, wherein X is the nitro group.