US4448886A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Biodispersions
Assignee: Diamond Shamrock Chemicals Co
•
Filing: 1981-11-30
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Granted: 1984-05-15
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Expires: 2001-11-30
Abstract
Abstract A process for producing high dispersion metal crystallites dispersed substantially homogeneously in a carbonaceous material matrix is disclosed. The novel metal crystallite dispersions disclosed herein have the added advantage of being locked into the matrix thereby preventing migration of the metal crystallites.
Inventors
- 👤 Lawrence J. Gestaut
- 👤 P. David Simcox
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 22:10
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/04; C25B11/042; C25B11/043; B; B22; B22F; B22F9/00; B22F9/16; C12; C12P; C12P3/00; C22; C22B; C22B3/00; C22B3/18; Y; Y02; Y02P; Y02P10/00; Y02P10/20; Y10; Y10S; Y10S423/00; Y10S423/09; Y10S423/17
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
107 words
A process for producing high dispersion metal crystallites dispersed substantially homogeneously in a carbonaceous material matrix comprising: a. introducing living microbes into a growth medium consisting essentially of a microbe nutrient, an aqueous liquid, and at least one metal in solvated form; b. growing said microbes in said growth medium, allowing said microbes to incorporate said metal; c. harvesting said microbes containing said metal; and d. pyrolyzing said harvested, metal-containing microbes in an inert or reducing atmosphere at a temperature of at least about 300° C. thereby yielding said high dispersion metal crystallites dispersed substantially homogeneously in a carbonaceous material matrix coformed therewith during this pyrolysis step.
Claim 2
Dependent Claim
107 words
A process for producing high dispersion metal crystallites dispersed substantially homogeneously in a carbonaceous material matrix comprising: a. introducing living microbes into a growth medium consisting essentially of a microbe nutrient, an aqueous liquid, and at least one metal in solvated form; b. growing said microbes in said growth medium, allowing said microbes to incorporate said metal; c. harvesting said microbes containing said metal; and d. pyrolyzing said harvested, metal-containing microbes in an inert or reducing atmosphere at a temperature of at least about 300° C. thereby yielding said high dispersion metal crystallites dispersed substantially homogeneously in a carbonaceous material matrix coformed therewith during this pyrolysis step.
Claim 3
Dependent Claim
26 words
A process as claimed in claim 1 wherein said living microbes are selected from the group consisting of yeast, fungi, algae, protozoa, bacteria and mixtures thereof.
Claim 4
Dependent Claim
27 words
A process as claimed in claim 1 wherein said microbe nutrient is selected from the group consisting of sugars, agar, protein digests, vitamins, salts and mixtures thereof.
Claim 5
Dependent Claim
44 words
A process as claimed in claim 1 wherein said aqueous liquid is selected from the group consisting of water, dilute aqueous solutions containing mineral acids, organic acids, alcohols, oils and mixtures thereof, further characterized in that said microbes can live in said aqueous liquid.
Claim 6
Dependent Claim
25 words
A process as claimed in claim 1 wherein said metal in solvated form is provided by using a soluble salt or salts of said metal.
Claim 7
Dependent Claim
29 words
A process as claimed in claim 1 wherein said metal in solvated form is from the group consisting of ruthenium platinum, rhodium, copper, zinc, iron, cobalt, gold, and silver.
Claim 8
Dependent Claim
40 words
A process as claimed in claim 1 wherein said step (d) is carried out at a temperature of from about 300° to about 1200° C. in an atmosphere selected from the group consisting of nitrogen, argon, hydrogen and mixtures thereof.
Claim 9
Dependent Claim
16 words
A process as claimed in claim 1 wherein said metal is a noble or precious metal.
Claim 10
Dependent Claim
11 words
A process as in claim 8 wherein said metal is ruthenium.
Claim 11
Dependent Claim
104 words
A process for producing high dispersion platinum crystallites dispersed substantially homogeneously in a carbonaceous material matrix comprising: a. introducing living microbes into a growth medium consisting essentially of a microbe nutrient, an aqueous liquid, and platinum in solvated form; b. growing said microbes in said growth medium, allowing said microbes to incorporate said platinum; c. harvesting said microbes containing said platinum; and d. pyrolyzing said harvested, platinum-containing microbes in an inert or reducing atmosphere at a temperature of at least about 300° C. thereby yielding said high dispersion platinum crystallites dispersed substantially homogeneously in a carbonaceous material matrix coformed therewith during this pyrolysis step.
Claim 12
Dependent Claim
104 words
A process for producing high dispersion platinum crystallites dispersed substantially homogeneously in a carbonaceous material matrix comprising: a. introducing living microbes into a growth medium consisting essentially of a microbe nutrient, an aqueous liquid, and platinum in solvated form; b. growing said microbes in said growth medium, allowing said microbes to incorporate said platinum; c. harvesting said microbes containing said platinum; and d. pyrolyzing said harvested, platinum-containing microbes in an inert or reducing atmosphere at a temperature of at least about 300° C. thereby yielding said high dispersion platinum crystallites dispersed substantially homogeneously in a carbonaceous material matrix coformed therewith during this pyrolysis step.
Claim 13
Dependent Claim
19 words
A process as claimed in claim 10 wherein said platinum in solvated form is provided by using chloroplatinic acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-15 | 1987-11-14 | 1988-05-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-15 | 1991-11-14 | 1992-05-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-15 | 1995-11-14 | 1996-05-15 | $7700.00 | Window Closed / Lapsed |