Decomposition of polycarbonates to form terminally unsaturated alcohols

Claim 2

A process for the preparation of terminally unsaturated alcohols, said process comprising thermally decomposing a polycarbonate represented by the formula: ##STR3## wherein R is a bivalent alkylene radical having from 3 to about 19 carbon atoms, R 1 is hydrogen or an alkyl group and n is an integer from about 2 to about 500 in the presence of a titanium containing catalyst selected from the group consisting of titanates, condensates of said titanates, titanium chelates and titanium acylates.

Claim 3

The process of claim 1 wherein said titanium catalyst is selected from the group consisting of tetraisopropyltitanate, tetra-n-butyltitanate, tetrakis (2-ethylhexyltitinate), titanium acetylacetonate, lactic acid titanium chelate, triethanolamine titanium chelate, titanium ethylacetoacetate chelate, tetraoctylene glycol titanate and titanium acylates of the formula Ti(OCOR") 4 wherein R" is a C 1 -C 10 alkyl group.

Claim 4

The process of claim 1 wherein the thermal decomposition is carried out at a temperature in the range of from about 285° C. to about 350° C.

Claim 5

The process of claim 1 wherein said titanium catalyst is tetraisopropyltitanate.

Claim 6

A process for the preparation of terminally unsaturated alcohols, said process comprising the steps of: (i) contacting a diol with a dialkyl carbonate in the presence of a titanium containing catalyst to form a polycarbonate; and (ii) thermally decomposing the polycarbonate formed in step (i) in the presence of a titanium containing catalyst wherein said titanium catalyst in steps (i) and (ii) is independently selected from the group consisting of titanates, condensates of said titanates, titanium chelates and titanium acylates.

Claim 7

A process for the preparation of terminally unsaturated alcohols, said process comprising the steps of: (i) contacting a diol with a dialkyl carbonate in the presence of a titanium containing catalyst to form a polycarbonate; and (ii) thermally decomposing the polycarbonate formed in step (i) in the presence of a titanium containing catalyst wherein said titanium catalyst in steps (i) and (ii) is independently selected from the group consisting of titanates, condensates of said titanates, titanium chelates and titanium acylates.

Claim 8

The process of claim 5 wherein said diol is represented by the formula: HOCH.sub.2 CHR'--R--CH.sub.2 OH wherein R is a bivalent alkylene radical having from 3 to about 19 carbon atoms and R' is hydrogen or an alkyl group.

Claim 9

The process of claim 5 wherein the dialkyl carbonate contains from 3 to about 9 carbon atoms.

Claim 10

The process of claim 5 wherein said titanium catalyst in steps (i) and (ii) is selected from the group consisting of tetraisopropyltitanate, tetra-n-butyltitanate, tetrakis (2-ethylhexytitanate), titanium acetylacetonate, lactic acid titanium chelate, triethanolamine titanium chelate, titanium ethylacetoacetate chelate, tetraoctylene glycol titanate and titanium acylates of the formula Ti(OCOR") 4 wherein R" is a C 1 -C 10 alkyl group.

Claim 11

The process of claim 5 wherein step (i) is carried out at a temperature in the range of from about 115° C. to about 225° C. and step (ii) is carried out at a temperature in the range of from about 285° C. to about 350° C.

Claim 12

The process of claim 5 wherein said diol is selected from the group consisting of 1,6-hexanediol, 1,10-decanediol, 1,8-octanediol, 1,9-nonanediol, 1,12-dodecanediol, 1,20-eicosanediol and mixtures thereof, and the dialkyl carbonate is selected from the group consisting of dimethyl carbonate, diethyl carbonate, dipropyl carbonate, dibutyl carbonate and ethylene carbonate.

Claim 13

The process of claim 10 wherein said titanium catalyst in steps (i) and (ii) is tetraisopropyltitanate.

Claim 14

The process of claim 1 wherein the resulting terminally unsaturated alcohol is continuously removed from the reaction mixture during the decomposition of said polycarbonate.

Claim 15

The process of claim 5 wherein the resulting terminally unsaturated alcohol is continuously removed from the reaction mixture during the decomposition of said polycarbonate.