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US4447310A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of distillates by the integration of supercritical extraction and gasification through methanol to gasoline

Assignee: Mobil Oil AS
•
Filing: 1982-06-23
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Granted: 1984-05-08
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Expires: 2002-06-23
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Abstract

Abstract A process for producing a wide slate of fuel products from coal is provided by integrating a methanol-to-gasoline conversion process with coal liquefaction and coal gasification. The coal liquefaction comprises contacting the coal with a solvent under supercritical conditions whereby a dense-gas phase solvent extracts from the coal a hydrogen-rich extract which can be upgraded to produce a distillate stream. The remaining coal is gasified under oxidation conditions to produce a synthesis gas which is converted to methanol. The methanol is converted to gasoline by contact with a zeolite catalyst. Solvent for coal extraction is process derived from the upgraded distillate fraction or gasoline fraction of the methanol-to-gasoline conversion.

Inventors

  • 👤 Francis J. Derbyshire
  • 👤 Darrell D. Whitehurst

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:27
CPC Classifications
B; B01; B01D; B01D11/00; B01D11/02; B01D11/0203; C; C10; C10G; C10G1/00; C10G1/002; C10G1/006; Y; Y10; Y10S; Y10S208/00; Y10S208/952

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 193 words
An integrated process for the conversion of solid coal to a wide slate of fuel products comprising: extracting a portion of said coal by contacting said coal with an extraction solvent under supercritical conditions of temperature and pressure whereby said solvent is converted to a dense-gas phase capable of dissolving the coal, separating said solvent and a hydrogen-rich liquid coal extract, said coal extract having a hydrogen concentration greater than said solid coal, a portion of said solid coal remaining an unsolvated, solid coal residue, upgrading at least a portion of said coal extract in the presence of hydrogen to produce a plurality of upgraded fuel products, gasifying said residue under oxidizing conditions to produce a synthesis gas comprising hydrogen and carbon monoxide, shifting the hydrogen to carbon monoxide ratio of a portion of said synthesis gas to produce a hydrogen-enriched gas, combining said hydrogen-enriched gas with said synthesis gas, converting said combined gas to methanol, passing at least a portion of said methanol in contact with a catalyst capable of converting said methanol to gasoline products and recycling at least a portion of said gasoline products for use as said extraction solvent.
Claim 2
Dependent Claim 193 words
An integrated process for the conversion of solid coal to a wide slate of fuel products comprising: extracting a portion of said coal by contacting said coal with an extraction solvent under supercritical conditions of temperature and pressure whereby said solvent is converted to a dense-gas phase capable of dissolving the coal, separating said solvent and a hydrogen-rich liquid coal extract, said coal extract having a hydrogen concentration greater than said solid coal, a portion of said solid coal remaining an unsolvated, solid coal residue, upgrading at least a portion of said coal extract in the presence of hydrogen to produce a plurality of upgraded fuel products, gasifying said residue under oxidizing conditions to produce a synthesis gas comprising hydrogen and carbon monoxide, shifting the hydrogen to carbon monoxide ratio of a portion of said synthesis gas to produce a hydrogen-enriched gas, combining said hydrogen-enriched gas with said synthesis gas, converting said combined gas to methanol, passing at least a portion of said methanol in contact with a catalyst capable of converting said methanol to gasoline products and recycling at least a portion of said gasoline products for use as said extraction solvent.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein said extraction solvent is additionally obtained from process-derived solvents, external solvents or mixtures thereof.
Claim 4
Dependent Claim 30 words
The process of claim 2 wherein said process-derived solvent is selected from the group consisting of solvent-derived from said upgraded fuel products, solvent derived from said methanol, and mixtures thereof.
Claim 5
Dependent Claim 20 words
The process of claim 3 wherein said solvent derived from said upgraded fuel products contains compounds capable of donating hydrogen.
Claim 6
Dependent Claim 14 words
The process of claim 1 wherein said extract is substantially free of solid matter.
Claim 7
Dependent Claim 18 words
The process of claim 3 wherein a portion of said extraction solvent is derived from an external source.
Claim 8
Dependent Claim 20 words
The process of claim 6 wherein said solvent derived from an external source comprises benzene, toluene, xylene, or mixtures thereof.
Claim 9
Dependent Claim 33 words
The process of claim 1 wherein said dissolved coal is separated from said extraction solvent by decreasing the pressure and temperature to a point whereby the liquid coal extract separates from said solvent.
Claim 10
Dependent Claim 18 words
The process of claim 1 wherein said liquid coal extract is catalytically upgraded in the presence of hydrogen.
Claim 11
Dependent Claim 17 words
The process of claim 1 wherein the hydrogen supplied for upgrading is provided from said hydrogen-enriched gas.
Claim 12
Dependent Claim 23 words
The process of claim 1 wherein said feed coal may be derived from the group consisting of lignites, bituminous coals and sub-bituminous coals.
Claim 13
Dependent Claim 21 words
The process of claim 1 wherein said feed coal is dried, premixed with a premixing solvent and comminuted before being liquiefied.
Claim 14
Dependent Claim 12 words
The process of claim 12 wherein said premixing solvent comprises distillate oils.
Claim 15
Dependent Claim 11 words
The process of claim 13 wherein said premixing solvent is process-derived.
Claim 16
Dependent Claim 19 words
The process of claim 1 wherein said gasoline products are produced by contacting said methanol with a zeolite catalyst.
Claim 17
Dependent Claim 12 words
The process of claim 15 wherein said zeolite catalyst is ZSM- 5.
Claim 18
Dependent Claim 16 words
The process of claim 1 wherein said coal extract contains at least 6% hydrogen by weight.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-08 1987-11-07 1988-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-08 1991-11-07 1992-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-08 1995-11-07 1996-05-08 $7700.00 Window Closed / Lapsed

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