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US4446304A Expired / Lapsed US ⏱️ 0.0 years remaining

Highly stable nylon 4,6 objects

Assignee: DSM BV
•
Filing: 1982-12-20
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Granted: 1984-05-01
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Expires: 2002-12-20
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Abstract

Abstract Shaped articles are described molded from a nylon 4,6 polyamide, substantially consisting of [NH--(CH 2 ) 4 --NH--CO(CH 2 ) 4 --CO] units and having a relative viscosity, measured at 20° C., on a solution in 96% sulfuric acid containing 1 g of polyamide in 100 ml of solution, of at least 2.0, and having highly stable high temperature, zinc-ion and chloride ion resistance characteristics.

Inventors

  • 👤 Reinoud J. Gaymans
  • 👤 Pieter J. Van Asperen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:24
CPC Classifications
B; B29; B29C; B29C67/00; B29C67/24; C; C08; C08G; C08G69/00; C08G69/48; B29K; B29K2077/00

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 90 words
A shaped article formed by compression or injection molding a melt of a polyamide, consisting essentially of a molecular chain of units of --NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO-- and which polyamide in the molded article has a relative viscosity of at least 2.5, measured at 20° C., on a solution in 96% sulfuric acid, containing 1 g of polyamide in 100 ml of solution, and which article has a heat distortion temperature value of at least 100° C., and an IZOD impact resistance value of at least 5 kilojoules per square meter.
Claim 2
Dependent Claim 90 words
A shaped article formed by compression or injection molding a melt of a polyamide, consisting essentially of a molecular chain of units of --NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO-- and which polyamide in the molded article has a relative viscosity of at least 2.5, measured at 20° C., on a solution in 96% sulfuric acid, containing 1 g of polyamide in 100 ml of solution, and which article has a heat distortion temperature value of at least 100° C., and an IZOD impact resistance value of at least 5 kilojoules per square meter.
Claim 3
Dependent Claim 14 words
Article according to claim 1, wherein said relative viscosity is from 3 to 5.
Claim 4
Dependent Claim 21 words
Article according to claim 1, molded at a temperature of between 290 and 330° C., with exclusion of oxygen and moisture.
Claim 5
Dependent Claim 16 words
Article according to claim 1 wherein said polyamide is a homopolyamide of 1,4-butanediamine with adipic acid.
Claim 6
Dependent Claim 13 words
Article according to claim 2, wherein said IZOD value is at least 7.5.
Claim 7
Dependent Claim 100 words
A process for the production of shaped articles made from the melt of a polyamide, which comprises compression or injection molding a nylon 4,6 polyamide consisting essentially of a molecular chain of repeating units of --NH--(CH.sub.2).sub.4 --NH--CO--(CH.sub.2).sub.4 --CO-- and which polyamide in the molded article has a relative viscosity of at least 2.5, measured at 20° C. on a solution in 96% sulfuric acid containing 1 g of polyamide in 100 ml of solution and has a heat distortion temperature value of at least 95° C. and an IZOD impact resistance value of at least 5 kilojoules per square meter.
Claim 8
Dependent Claim 100 words
A process for the production of shaped articles made from the melt of a polyamide, which comprises compression or injection molding a nylon 4,6 polyamide consisting essentially of a molecular chain of repeating units of --NH--(CH.sub.2).sub.4 --NH--CO--(CH.sub.2).sub.4 --CO-- and which polyamide in the molded article has a relative viscosity of at least 2.5, measured at 20° C. on a solution in 96% sulfuric acid containing 1 g of polyamide in 100 ml of solution and has a heat distortion temperature value of at least 95° C. and an IZOD impact resistance value of at least 5 kilojoules per square meter.
Claim 9
Dependent Claim 14 words
Process according to claim 6, wherein said relative viscosity is from 3 to 5.
Claim 10
Dependent Claim 28 words
Process according to claim 6, wherein said polyamide is formed into said shaped article at a temperature of between 290° and 330° C., while excluding oxygen and moisture.
Claim 11
Dependent Claim 16 words
Process according to claim 6 wherein said polyamide is a homopolyamide of 1,4-butanediamine with adipic acid.
Claim 12
Dependent Claim 13 words
Process according to claim 7, wherein said IZOD value is at least 7.5.

References Cited (Backward Citations)

US2130948A Cited
US2172374A Cited
GB614625A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-01 1987-10-31 1988-05-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-01 1991-10-31 1992-05-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-01 1995-10-31 1996-05-01 $7700.00 Window Closed / Lapsed

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