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US4446280A
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Crosslinking composition containing activated carboxylic ester polymer and amine-terminated triazine resin
Assignee: Wyeth Holdings LLC
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Filing: 1982-05-12
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Granted: 1984-05-01
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Expires: 2002-05-12
Abstract
Abstract The use of amine-terminated triazine resin as crosslinking agent in coating formulations containing activated carboxylic ester polymers provides improved coating properties.
Inventors
- 👤 Susan M. Cady
- 👤 Werner J. Blank
- 👤 Peter J. Schirmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 15:00
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/30; C08F8/32
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
200 words
A crosslinking coating composition comprising (1) a vinyl polymer containing from about 1 to 100 weight percent of repeating units derived from a monomer of the formula ##STR4## wherein the R group is selected from hydrogen and methyl, R' is selected from hydrogen, alkyls of 1-6 carbon atoms, cycloalkyls of 5-6 carbon atoms, and 2-hydroxyalkyls of 2-6 carbon atoms, and R 2 is selected from alkyls of 1-6 carbon atoms, cycloalkyls of 5-6 carbon atoms, and 2-hydroxy alkyls of 2-6 carbon atoms, and the balance of repeating units from one or more copolymerizable ethylenically-unsaturated comonomers and (2) as crosslinking agent an effective amount of a mixture of amine-terminated triazine resins of the average formula ##STR5## wherein R 4 is hydrogen, NH 2 , R 5 H, group an aromatic, or aliphatic group of 1-18 carbon atoms, a cycloaliphatic group of 5-6 carbon atoms, or hydroxyalkylamine, R 5 is individually, a bridging unit derived from primary diamines selected from aliphatic of 2-14 carbon atoms, aromatic of 6-15 carbon atoms, cycloaliphatic of 5-15 carbon atoms, or --NH(CH 2 ) 3 --O--(CH 2 ) y --O(CH 2 ) 3 NH--, y is an integer of 2-12, and x is an integer of 0-10.
Claim 2
Dependent Claim
200 words
A crosslinking coating composition comprising (1) a vinyl polymer containing from about 1 to 100 weight percent of repeating units derived from a monomer of the formula ##STR4## wherein the R group is selected from hydrogen and methyl, R' is selected from hydrogen, alkyls of 1-6 carbon atoms, cycloalkyls of 5-6 carbon atoms, and 2-hydroxyalkyls of 2-6 carbon atoms, and R 2 is selected from alkyls of 1-6 carbon atoms, cycloalkyls of 5-6 carbon atoms, and 2-hydroxy alkyls of 2-6 carbon atoms, and the balance of repeating units from one or more copolymerizable ethylenically-unsaturated comonomers and (2) as crosslinking agent an effective amount of a mixture of amine-terminated triazine resins of the average formula ##STR5## wherein R 4 is hydrogen, NH 2 , R 5 H, group an aromatic, or aliphatic group of 1-18 carbon atoms, a cycloaliphatic group of 5-6 carbon atoms, or hydroxyalkylamine, R 5 is individually, a bridging unit derived from primary diamines selected from aliphatic of 2-14 carbon atoms, aromatic of 6-15 carbon atoms, cycloaliphatic of 5-15 carbon atoms, or --NH(CH 2 ) 3 --O--(CH 2 ) y --O(CH 2 ) 3 NH--, y is an integer of 2-12, and x is an integer of 0-10.
Claim 3
Dependent Claim
24 words
The composition of claim 1 wherein vinyl polymer contains from about 10 to 60 weight percent of said monomer containing activated carboxylic ester group.
Claim 4
Dependent Claim
33 words
The composition of claim 1 wherein said comonomer is selected from alkyl acrylates and alkyl methacrylates, styrene, acrylonitrile, maleic and fumaric acids, and functional acrylates such as hydroxyethyl acrylate, acrylic acid and acrylamide.
Claim 5
Dependent Claim
13 words
The composition of claim 1 wherein said monomer is methyl acrylamidoglycolate methyl ether.
Claim 6
Dependent Claim
13 words
The composition of claim 1 wherein said monomer is ethyl acrylamidoglycolate ethyl ether.
Claim 7
Dependent Claim
13 words
The composition of claim 1 wherein said monomer is butyl acrylamidoglycolate butyl ether.
Claim 8
Dependent Claim
35 words
The composition of claim 1 wherein said monomer is a mixture consisting of monomers wherein R' and R 2 are the same or different and are selected from alkyls of 1 to 4 carbon atoms.
Claim 9
Dependent Claim
50 words
The composition of claim 1 wherein said amine-terminated triazine resin is selected from compounds wherein R 5 is NH 2 and R 6 H, R 6 is --NH(CH 2 ) 6 NH-- and --NH(CH 2 ) 3 O(CH 2 ) 2 O(CH 2 ) 3 NH-- and x is 0-3.
Claim 10
Dependent Claim
11 words
A cross-linked coating obtained by curing the composition of claim 1.
Claim 11
Dependent Claim
12 words
The cross-linked coating of claim 9 obtained by curing at elevated temperature.
Claim 12
Dependent Claim
11 words
The crosslinked coating obtained by curing the composition of claim 4.
Claim 13
Dependent Claim
11 words
The crosslinked coating obtained by curing the composition of claim 5.
Claim 14
Dependent Claim
13 words
The crosslinked coating obtained by curing the composition of claims 4 and 8.
Claim 15
Dependent Claim
14 words
The cross-linked coating of claims 4 & 8 obtained by curing at room temperature.
Claim 16
Dependent Claim
11 words
The crosslinked coating obtained by curing the composition of claim 7.
Claim 17
Dependent Claim
16 words
The crosslinked coating obtained by curing the compositions of claims 7 and 8 at room temperature.
Claim 18
Dependent Claim
16 words
The crosslinked coating obtained by curing the compositions of claims 7 and 8 at elevated temperature.
References Cited (Backward Citations)
US3422139A
Cited
US3407155A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-01 | 1987-10-31 | 1988-05-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-01 | 1991-10-31 | 1992-05-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-01 | 1995-10-31 | 1996-05-01 | $7700.00 | Window Closed / Lapsed |