Vulcanizing fluorocarbon elastomers with one or a mixture of aromatic compounds having hydroxyl and oxyallyl groups

Claim 2

A composition comprising fluorocarbon elastomer gum and as a vulcanizing agent therefor a composition comprising one or a mixture of aromatic compounds having hydroxyl and oxyallyl groups directly bonded to aromatic ring-carbon atoms.

Claim 3

A composition comprising elastomeric copolymer gum of vinylidene fluoride and at least one terminally unsaturated monoolefin comonomer and as a vulcanizing agent therefor a composition comprising one or a mixture of aromatic compounds having hydroxyl and oxyallyl groups directly bonded to aromatic ring-carbon atoms.

Claim 4

A composition comprising elastomeric copolymer gum of vinylidene fluoride and at least one terminally unsaturated monoolefin comonomer and as a vulcanizing agent therefor a composition comprising one or a mixture of aromatic compounds having hydroxyl and oxyallyl groups directly bonded to aromatic ring-carbon atoms.

Claim 5

The composition of claim 2 wherein said aromatic compounds are represented by the general formula Ar(OR).sub.n where Ar is a n-valent aromatic nucleus, each R is the same or different and is selected from the group consisting of a hydrogen atom and an allyl group, and n is a number from 1 to 4, with the proviso that if in a select compound of said formula n is 1, or if n is 2, 3, or 4 and each R is the same, then said vulcanizing agent composition comprises said select compound and at least one other compound of said formula which has at least one R that is different from the R of said select compound.

Claim 6

The composition of claim 2 wherein said aromatic compounds are represented by the general formula ##STR23## where R is a hydrogen atom or an allyl group, A is thio, oxy, sulfinyl, sulfonyl, or carbonyl moiety, or a divalent organic radical, x and y are zero, 1, or 2, and m and n are zero or 1, with the provisos: (1) that if (n+y) is at least 1 and if y is zero, then x is at least 1, and (2) that if in a select compound of said formula there is no hydroxyl substituent, then said vulcanizing agent composition comprises said hydroxyl-free select compound and at least one other compound within the scope of said formula having at least one hydroxyl substituent.

Claim 7

The composition according to claim 2 wherein said vulcanizing agent comprises a mixture of ##STR24##

Claim 8

The composition according to claim 2 wherein said copolymer is a copolymer of vinylidene fluoride and hexafluoropropene.

Claim 9

The composition according to claim 2 wherein said copolymer is a copolymer of vinylidene fluoride, hexafluoropropene, and tetrafluoroethylene.

Claim 10

The composition according to claim 2 wherein the ratio of hydroxyl groups to oxyallyl groups in said vulcanizing agent composition is in the range of 0.3/1 to 10/1.

Claim 11

The composition according to claim 2 wherein the ratio of hydroxyl groups to oxyallyl groups in said vulcanizing agent composition is in the range of 0.7/1 to 2/1.

Claim 12

The composition according to claim 2 wherein said vulcanizing agent is present in said composition in the amount of 0.2 to 10 parts per 100 parts of said gum.

Claim 13

The composition according to claim 2 further comprising an organo-onium compound as a co-curing agent.

Claim 14

The composition according to claim 2 further comprising 0.1 to 5 parts of (C 6 H 5 ) 3 (C 6 H 5 CH 2 )P + Cl - per 100 parts of said gum.

Claim 15

The composition according to claim 2 further comprising carbon black, MgO, and Ca(OH) 2 .

Claim 16

A composition comprising a copolymer gum of vinylidene fluoride and 15 to 50 mole percent of hexafluoropropene comonomer, 0.5 to 6 parts of a vulcanizing agent consisting essentially of a mixture of ##STR25## the ratio of hydroxyl groups to oxyallyl groups in said mixture being in the range of 0.7/1 to 2/1, 0.1 to 5 parts of (C 6 H 5 ) 3 (C 6 H 5 CH 2 )P + Cl - , 0 to 100 parts of carbon black, 0 to 25 parts of MgO, and 0 to 25 parts of Ca(OH) 2 , the sum of the latter two parts being 3 to 40.

Claim 17

A composition comprising a copolymer gum of vinylidene fluoride and 15 to 50 mole percent of hexafluoropropene comonomer, 0.5 to 6 parts of a vulcanizing agent consisting essentially of a mixture of ##STR25## the ratio of hydroxyl groups to oxyallyl groups in said mixture being in the range of 0.7/1 to 2/1, 0.1 to 5 parts of (C 6 H 5 ) 3 (C 6 H 5 CH 2 )P + Cl - , 0 to 100 parts of carbon black, 0 to 25 parts of MgO, and 0 to 25 parts of Ca(OH) 2 , the sum of the latter two parts being 3 to 40.

Claim 18

A shaped article of a cured fluoroelastomer made by curing the composition of claim 2.

Claim 19

A process for vulcanizing a fluorocarbon elastomer gum, which comprises admixing with said gum as a vulcanizing agent therefor a composition comprising one or a mixture of aromatic compounds having hydroxyl and oxyallyl groups bonded directly to aromatic ring-carbon atoms.

Claim 20

A process for vulcanizing a fluorocarbon elastomer gum, which comprises admixing with said gum as a vulcanizing agent therefor a composition comprising one or a mixture of aromatic compounds having hydroxyl and oxyallyl groups bonded directly to aromatic ring-carbon atoms.

Claim 21

The process of claim 16 wherein said gum is an elastomer copolymer gum of vinylidene fluoride and at least one terminally unsaturated monoolefin comonomer.