Patent US4446197A successfully refreshed from Google Patents.
US4446197A
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US
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Ion beam deposition or etching re rubber-metal adhesion
Assignee: Goodyear Tire and Rubber Co
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Filing: 1982-07-23
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Granted: 1984-05-01
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Expires: 2002-07-23
Abstract
Abstract Metal to rubber adhesion is improved by metal substrates having a coating thereon such as brass, copper, and the like. The coating is applied by an ion beam sputter deposition or, in the alternative, such a coating is partially removed through ion beam etching. The present invention is particularly useful in tire cord construction, metal reinforced belts and hoses, and the like, since articles made therefrom have superior and unexpected moisture aged rubber-to-metal adhesion properties.
Inventors
- 👤 David A. Benko
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 21:40
CPC Classifications
D; D07; D07B; D07B1/00; D07B1/06; D07B1/0606; D07B1/0666; D07B2205/00; D07B2205/30; D07B2205/3021; D07B2205/306; D07B2205/3067; D07B2205/3071; D07B2205/3085; D07B2205/3089; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12493; Y10T428/12535; Y10T428/12556; Y10T428/12562; Y10T428/12771; Y10T428/12861; Y10T428/12903; Y10T428/12917; Y10T428/12924
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
31 words
A metal item having rubber adhered to a surface thereof, comprising: the metal item, said metal surface treated by an ion beam treatment, the rubber adhered to said treated metal surface.
Claim 2
Dependent Claim
31 words
A metal item having rubber adhered to a surface thereof, comprising: the metal item, said metal surface treated by an ion beam treatment, the rubber adhered to said treated metal surface.
Claim 3
Dependent Claim
18 words
A metal item according to claim 1, wherein said ion beam treatment is a sputter deposition of metal.
Claim 4
Dependent Claim
59 words
A metal item according to claim 2, wherein said treatment is said ion beam deposition of a coating metal, wherein said coating metal is selected from the group consisting of copper, steel, zinc, nickel, aluminum, cobalt, iron, and alloys thereof including brass, and wherein the thickness of said coating metal ranges from about 5 to about 4,000 angstrom units.
Claim 5
Dependent Claim
57 words
A metal item according to claim 3, wherein said rubber is selected from the group consisting of dienes having from 4 to 12 carbon atoms, and interpolymers thereof, interpolymers made from dienes having from 4 to 12 carbon atoms and vinyl substituted aromatics having from 8 to 12 carbon atoms, nitrile rubber, polychloroprene, EPDM, and combinations thereof.
Claim 6
Dependent Claim
34 words
A metal item according to claim 1, wherein said metal surface is a substrate and has a metallic coating thereon, and wherein said ion beam treatment is a sputter etching of said metallic coating.
Claim 7
Dependent Claim
29 words
A metal item according to claim 4, wherein said ion is selecting from the group consisting of a tire cord a tire bead, and wherein said coating is copper.
Claim 8
Dependent Claim
47 words
A metal item according to claim 5, wherein said metal surface coating is selected from the group consisting of copper, steel, zinc, iron, nickel, aluminum, cobalt, and alloys thereof including brass, and wherein the thickness of said coating ranges from about 5 to about 4,000 angstrom units.
Claim 9
Dependent Claim
57 words
A metal item according to claim 7, wherein said rubber is selected from the group consisting of dienes having from 4 to 12 carbon atoms, and interpolymers thereof, interpolymers made from dienes having from 4 to 12 carbon atoms and vinyl substituted aromatics having from 8 to 12 carbon atoms, nitrile rubber, polychloroprene, EPDM, and combinations thereof.
Claim 10
Dependent Claim
29 words
A metal item according to claim 8 wherein said item is selected from the group consisting of a tire cord, a tire bead, and wherein said coating is copper.
Claim 11
Dependent Claim
39 words
A metal item according to claim 6, wherein said coating thickness is from about 500 to about 1000 angstrom units and wherein said rubber is selected from the group consisting of natural or synthetic cis-1,4-polyisoprene, polybutadiene, or styrene-butadiene rubber.
Claim 12
Dependent Claim
39 words
A metal item according to claim 9, wherein said coating thickness is from about 500 to about 1000 angstrom units and wherein said rubber is selected from the group consisting of natural or synthetic cis-1,4-polyisoprene, polybutadiene, or styrene-butadiene rubber.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-01 | 1987-10-31 | 1988-05-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-01 | 1991-10-31 | 1992-05-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-01 | 1995-10-31 | 1996-05-01 | $7700.00 | Window Closed / Lapsed |