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US4444988A Expired / Lapsed US ⏱️ 0.0 years remaining

Use of liquefied propane and butane or butane recycle to control heat of reaction of converting olefins to gasoline and distillate

Assignee: Mobil Oil AS
•
Filing: 1982-07-22
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Granted: 1984-04-24
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Expires: 2002-07-22
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Abstract

Abstract The economics and thermal efficiency of an olefin-to-gasoline-conversion process utilizing catalyst beds is improved by separating the effluent product from the beds into a gas in a liquid phase, cooling the gas phase to form additional liquid and heat exchanging the liquid with the overhead gas from the separator.

Inventors

  • 👤 Leon M. Capsuto
  • 👤 Robert E. Holland
  • 👤 Henry R. Ireland
  • 👤 Samuel A. Tabak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:11
CPC Classifications
C; C10; C10G; C10G29/00; C10G29/20; C10G29/205

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 197 words
A process for producing a hydrocarbon fuel boiling within the range of gasoline and distillate comprising (a) contacting a C 2 -C 5 olefin, mixtures thereof or mixtures thereof with paraffins having from 1 to 5 carbon atoms with a crystalline zeolite selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-35 and ZSM-38 zeolites thereby producing a product stream comprising a liquid phase and a vapor phase; (b) separating said product stream of (a) into a liquid phase and a vapor phase; (c) fractionating said liquid phase of (b) into a desired gasoline fraction; (d) passing the vapor phase of (b) through a cooling zone thereby condensing at least a portion of the propane and butene product to a liquid and forming a two-phase vapor and liquid mixture; (e) separating the two-phase mixture of (d) into a liquid phase and a vapor phase; (f) flowing said liquid phase of (e) in a heat exchange relationship with the vapor phase of (b); (g) fractionating at least a portion of said liquid phase of (e) into a desired gasoline fraction; and (h) recycling a portion of said liquid phase of (e) into contact with said zeolite of (a).
Claim 2
Dependent Claim 197 words
A process for producing a hydrocarbon fuel boiling within the range of gasoline and distillate comprising (a) contacting a C 2 -C 5 olefin, mixtures thereof or mixtures thereof with paraffins having from 1 to 5 carbon atoms with a crystalline zeolite selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-35 and ZSM-38 zeolites thereby producing a product stream comprising a liquid phase and a vapor phase; (b) separating said product stream of (a) into a liquid phase and a vapor phase; (c) fractionating said liquid phase of (b) into a desired gasoline fraction; (d) passing the vapor phase of (b) through a cooling zone thereby condensing at least a portion of the propane and butene product to a liquid and forming a two-phase vapor and liquid mixture; (e) separating the two-phase mixture of (d) into a liquid phase and a vapor phase; (f) flowing said liquid phase of (e) in a heat exchange relationship with the vapor phase of (b); (g) fractionating at least a portion of said liquid phase of (e) into a desired gasoline fraction; and (h) recycling a portion of said liquid phase of (e) into contact with said zeolite of (a).
Claim 3
Dependent Claim 21 words
The process of claim 1 wherein the zeolite of (a) is selected from the group consisting of ZSM-5 and ZSM-11 zeolites.
Claim 4
Dependent Claim 34 words
The process of claim 1 wherein the step of separating of (b) is conducted at temperature between about 250° F. and about 600° F. and a pressure of about 300 and about 2000 psig.
Claim 5
Dependent Claim 34 words
The process of claim 1 wherein the step of separating of (e) is conducted at a temperature between about 75° F. and 300° F. and a pressure of about 100 and about 500 psig.
Claim 6
Dependent Claim 12 words
The process of claim 1 wherein the crystalline zeolite is ZSM-5 zeolite.
Claim 7
Dependent Claim 12 words
The process of claim 1 wherein the crystalline zeolite is ZSM-11 zeolite.

References Cited (Backward Citations)

US1813880A Cited
US2737539A Cited
US3827968A Cited
US4012455A Cited
US3998899A Cited
US4197185A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-24 1987-10-24 1988-04-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-24 1991-10-24 1992-04-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-24 1995-10-24 1996-04-24 $7700.00 Window Closed / Lapsed

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