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US4444971A
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Acrylic and methacrylic quaternary chloromethyl ammonium chloride cationic monomers and polymers thereof
Assignee: Texaco Development Corp
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Filing: 1983-07-25
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Granted: 1984-04-24
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Expires: 2003-07-25
Abstract
Abstract The present invention is directed to a new class of cationic monomers and to polymers thereof. The monomers are quaternary chloromethyl ammonium chlorides having the following general formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH 2 Cl Cl.sup.⊖ (1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently lower alkyl The present invention is also directed to homopolymers and copolymers of the above described class of monomers.
Inventors
- 👤 Edward E. McEntire
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 09:52
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/52; C08F20/54; C08F20/60; C08F20/10; C08F20/34
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
44 words
A compound having the formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH.sub.2 Cl Cl.sup.63 ( 1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently are C 1 -C 4 alkyl
Claim 2
Dependent Claim
44 words
A compound having the formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH.sub.2 Cl Cl.sup.63 ( 1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently are C 1 -C 4 alkyl
Claim 3
Dependent Claim
40 words
A compound as in claim 1 of the formula: ##STR5## wherein in the formula of claim 1 R 1 is methyl, X is nitrogen, R 2 is hydrogen, n is 3 and R 3 and R 4 independently are methyl.
Claim 4
Dependent Claim
30 words
A compound as in claim 1 of the formula: ##STR6## wherein in the formula of claim 1 R 1 =methyl, X=oxygen, n=2, R 3 and R 4 independently are methyl.
Claim 5
Dependent Claim
33 words
The compound as in claim 1 of the formula: ##STR7## wherein in the formula of claim 1 R 1 =hydrogen, X=nitrogen, R 2 =hydrogen and R 3 and R 4 independently are methyl.
Claim 6
Independent Claim
95 words
A method of preparing a novel compound having the formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH.sub.2 Cl Cl.sup.⊖ (1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently are C 1 to C 4 alkyl which comprises noncatalytically reacting methylene chloride with a feed compound having the formula: ##STR8## where R 1 =H or CH 3 X=O or NR 2 R 2 =H or C 1 -C 4 alkyl n=2-6 R 3 , R 4 =independently, C 1 -C 4 alkyl
Claim 7
Independent Claim
95 words
A method of preparing a novel compound having the formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH.sub.2 Cl Cl.sup.⊖ (1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently are C 1 to C 4 alkyl which comprises noncatalytically reacting methylene chloride with a feed compound having the formula: ##STR8## where R 1 =H or CH 3 X=O or NR 2 R 2 =H or C 1 -C 4 alkyl n=2-6 R 3 , R 4 =independently, C 1 -C 4 alkyl
Claim 8
Dependent Claim
39 words
A method as in claim 5 wherein, the feed compound has the formula: ##STR9## wherein R 1 =methyl, X=N, R 2 =H, n=3, R 3 and R 4 independently equal methyl, and the novel compound has the formula: ##STR10##
Claim 9
Dependent Claim
40 words
A method as in claim 5 wherein, the feed compound has the formula: ##STR11## wherein R 1 =methyl, X=O, n=2, R 3 and R 4 independently equal methyl in the above formulae, and the novel compound has the formula: ##STR12##
Claim 10
Dependent Claim
38 words
A method as in claim 5 wherein, the feed compound has the formula: ##STR13## wherein R 1 =H, X=N, R 2 =H, R 3 and R 4 independently equal methyl, and the novel compound has the formula: ##STR14##
Claim 11
Dependent Claim
47 words
A polymer of a compound having the formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH.sub.2 Cl Cl.sup.⊖ ( 1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently C 1 to C 4 alkyl
Claim 12
Dependent Claim
47 words
A polymer of a compound having the formula: CH.sub.2 ═CR.sub.1 COX(CH.sub.2).sub.n N.sup.⊕ R.sub.3 R.sub.4 CH.sub.2 Cl Cl.sup.⊖ ( 1) where R 1 =H, CH 3 X=O, NR 2 where R 2 =H, lower alkyl n=2-6 R 3 , R 4 =independently C 1 to C 4 alkyl
Claim 13
Dependent Claim
39 words
A polymer as in claim 9 of a monomer of the formula: ##STR15## wherein in the formula of claim 9 R 1 =CH 3 , X=N, R 2 =H, n=3, and R 3 and R 4 independently equal methyl.
Claim 14
Dependent Claim
33 words
A polymer as in claim 9 of a monomer of the formula: ##STR16## wherein in the formula of claim 9 R 1 =methyl, X=oxygen, n=2, R 3 and R 4 independently equal methyl.
Claim 15
Dependent Claim
36 words
A polymer as in claim 9 of a monomer of the formula: ##STR17## wherein in the formula of claim 9 R 1 =H, X=N, R 2 =hydrogen, n=3, R 3 and R 4 independently equal methyl.
Claim 16
Dependent Claim
2 words
Polychloromethyldimethylmethacrylamidoammonium chloride.
Claim 17
Dependent Claim
2 words
Polychloromethyldimethylmethacrylamidoammonium chloride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-04-24 | 1987-10-24 | 1988-04-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-04-24 | 1991-10-24 | 1992-04-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-04-24 | 1995-10-24 | 1996-04-24 | $7700.00 | Window Closed / Lapsed |