Aromatic polyols made from waste streams from the manufacture of terephthalic acids, alkylene glycols and dibasic acids

Claim 2

A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising a. esterifying a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and b. transesterifying a terephthalic ester waste stream with the polyester polyol reaction product from the previous step.

Claim 3

The mixture of aromatic polyols of claim 1 in which the alkylene glycol has the formula ##STR4## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3.

Claim 4

The mixture of polyols of claim 1 in which the alkylene glycol is a glycol waste stream.

Claim 5

The mixture of polyols of claim 1 in which the terephthalic ester waste stream is a residue from the manufacture of dimethyl terephthalate.

Claim 6

The mixture of polyols of claim 4 in which the dimethyl terephthalate residue contains dimethyl terephthalate and one or more by-products selected from the group consisting of substituted benzenes, polycarbomethoxy diphenyls, benzyl esters of the toluate family, dicarbomethoxy fluorenone, carbomethoxy benzocoumarins and carbomethoxy polyphenyls.

Claim 7

The mixture of polyols of claim 1 in which the terephthalic ester waste stream is selected from the group consisting of residue from the manufacture of polyethylene terephthalate.

Claim 8

The mixture of polyols of claim 1 in which the reactions are conducted at a temperature between 160° to 240° C. and at a pressure between one atmosphere and subatmospheric.

Claim 9

The mixture of polyols of claim 1 in which the average hydroxyl number of the resultant mixture is between 100 and 400.

Claim 10

A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising a. esterifying a residue from dibasic acid manufacture which comprises one or more acids selected from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol waste stream containing alkylene glycols of the formula ##STR5## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, to produce a polyester polyol, and b. transesterifying a terephthalic ester residue which is selected from the group consisting of manufacturing waste streams of dimethyl terephthalate or polyethylene terephthalate and mixtures thereof, with the polyester polyol reaction product from the previous step, such that the reactions are conducted at a temperature between 160° to 240° C. and at a pressure between one atmosphere and subatmospheric and in which the average hydroxyl number of the resultant polyol mixture is between 100 and 400.

Claim 11

A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising a. esterifying a residue from dibasic acid manufacture which comprises one or more acids selected from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol waste stream containing alkylene glycols of the formula ##STR5## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, to produce a polyester polyol, and b. transesterifying a terephthalic ester residue which is selected from the group consisting of manufacturing waste streams of dimethyl terephthalate or polyethylene terephthalate and mixtures thereof, with the polyester polyol reaction product from the previous step, such that the reactions are conducted at a temperature between 160° to 240° C. and at a pressure between one atmosphere and subatmospheric and in which the average hydroxyl number of the resultant polyol mixture is between 100 and 400.

Claim 14

The method of claim 10 in which a. the alkylene glycol is a glycol waste stream comprising alkylene glycols of the formula ##STR6## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, and b. the terephthalic ester waste stream is a residue from the manufacture of dimethyl terephthalate or polyethylene terephthalate.

Claim 15

The method of claim 10 in which the reactions are conducted at a temperature between 160° and 240° C. and at a pressure between one atmosphere and subatmospheric.

Claim 16

The method of claim 10 in which the average hydroxyl number of the resultant mixture is between 100 and 400.

Claim 17

A rigid polyurethane foam obtained by reacting in the presence of a blowing agent and a catalyst of polyurethane formation an organic polyisocyanate and a polyol blend comprising a. from about 5 to 100 percent by weight of a mixture of aromatic polyols having ester functionalities which is the reaction product from (1) esterifying a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and (2) transesterifying a terephthalic ester waste stream with the polyester polyol reaction product from the previous step, and b. from about 95 to 0 percent by weight of a nitrogen-containing polyol which is the reaction product from (1) reacting one mode of phenol or nonylphenol with one to 2 moles of diethanolamine to give a Mannich reaction product and (2) subsequently reacting one mole of the Mannich reaction product with 2 to 3 moles of propylene oxide.

Claim 18

A rigid polyurethane foam obtained by reacting in the presence of a blowing agent and a catalyst of polyurethane formation an organic polyisocyanate and a polyol blend comprising a. from about 5 to 100 percent by weight of a mixture of aromatic polyols having ester functionalities which is the reaction product from (1) esterifying a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and (2) transesterifying a terephthalic ester waste stream with the polyester polyol reaction product from the previous step, and b. from about 95 to 0 percent by weight of a nitrogen-containing polyol which is the reaction product from (1) reacting one mode of phenol or nonylphenol with one to 2 moles of diethanolamine to give a Mannich reaction product and (2) subsequently reacting one mole of the Mannich reaction product with 2 to 3 moles of propylene oxide.

Claim 19

The rigid polyurethane foam of claim 14 in which the polyol blend has an average hydroxyl number in the range from 100 to 400.

Claim 20

The rigid polyurethane foam of claim 14 in which the blowing agent is trichlorofluoromethane.

Claim 21

A rigid polyisocyanurate foam which is obtained by reacting in the presence of a blowing agent and a trimerization catalyst of polyisocyanurate formation, an organic polyisocyanate and a mixture of aromatic polyols having ester functionalities which is the reaction product of the process comprising a. esterifying a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and b. transesterifying a terephthalic ester waste stream with the polyester polyol reaction product from the previous step.

Claim 22

A rigid polyisocyanurate foam which is obtained by reacting in the presence of a blowing agent and a trimerization catalyst of polyisocyanurate formation, an organic polyisocyanate and a mixture of aromatic polyols having ester functionalities which is the reaction product of the process comprising a. esterifying a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and b. transesterifying a terephthalic ester waste stream with the polyester polyol reaction product from the previous step.

Claim 23

The rigid polyisocyanurate foam of claim 17 in which the mixture of aromatic polyols have an average hydroxyl number in the range of 100 to 400.

Claim 24

The rigid polyisocyanurate foam of claim 17 in which the blowing agent is trichlorofluoromethane.