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US4441118A Expired / Lapsed US ⏱️ 0.0 years remaining

Composite copper nickel alloys with improved solderability shelf life

Assignee: Olin Corp
•
Filing: 1983-01-13
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Granted: 1984-04-03
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Expires: 2003-01-13
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Abstract

Abstract A composite structure having improved solderability shelf life and contact resistance is formed by coating a copper alloy substrate material with a tin-containing material. The copper alloy substrate material consists essentially of about 15% to about 30% nickel and the balance essentially copper. The copper alloy may further include up to about 25% zinc. The nickel in the alloy retards the growth of copper-tin and/or copper-zinc-tin intermetallic compounds and the diffusion of the copper through the coating. The coating may be formed from tin or tin alloys including tin solders, e.g. 60% Tin-40% lead solder.

Inventors

  • 👤 Julius C. Fister
  • 👤 John F. Breedis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:30
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/01; B23; B23K; B23K35/00; B23K35/001; B23K35/007; H; H10; H10W; H10W70/00; H10W70/40; H10W70/456; H10W70/457; H10W72/00; H10W72/071; H10W72/075; H10W72/07531; H10W72/07532; H10W72/07533; H10W72/50; H10W72/531; H10W72/533; H10W72/534; H10W74/00; H10W90/00; H10W90/701; H10W90/751; H10W90/756; Y; Y10; Y10S; Y10S428/00; Y10S428/922; Y10S428/9265; Y10S428/929; Y10T; Y10T428/00; Y10T428/12; Y10T428/12493; Y10T428/12687; Y10T428/12771; Y10T428/12861; Y10T428/12903; Y10T428/1291

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 93 words
A composite structure having a reduced growth of copper-tin intermetallic compounds, said composite structure comprising: a substrate formed from a copper base alloy; said copper base alloy consisting essentially of 19% to about 28% nickel and the balance essentially copper; a coating covering at least a portion of said substrate; said coating being formed from a tin-containing material; and said nickel in said alloy retarding the growth of said copper-tin intermetallic compounds and diffusion of said copper through said coating and thereby improving the solderability shelf life and contact resistance of said structure.
Claim 2
Dependent Claim 93 words
A composite structure having a reduced growth of copper-tin intermetallic compounds, said composite structure comprising: a substrate formed from a copper base alloy; said copper base alloy consisting essentially of 19% to about 28% nickel and the balance essentially copper; a coating covering at least a portion of said substrate; said coating being formed from a tin-containing material; and said nickel in said alloy retarding the growth of said copper-tin intermetallic compounds and diffusion of said copper through said coating and thereby improving the solderability shelf life and contact resistance of said structure.
Claim 3
Dependent Claim 24 words
The composite structure of claim 1 further comprising: said copper alloy consisting essentially of 19% to about 26% nickel and the balance essentially copper.
Claim 4
Dependent Claim 30 words
The composite structure of claim 1 wherein: said copper alloy further includes up to about 25% zinc, whereby said nickel in said alloy retards the growth of copper-zinc-tin intermetallic compounds.
Claim 5
Dependent Claim 22 words
The composite structure of claim 1 further comprising: said tin-containing material being selected from the group consisting of tin and tin alloys.
Claim 6
Dependent Claim 25 words
The composite structure of claim 1 wherein: said tin-containing material comprises a tin solder consisting essentially of about 40% lead and the balance essentially tin.
Claim 7
Dependent Claim 26 words
The composite structure of claim 1 further comprising: said coating comprising a stripe of said tin-containing material plated on at least one surface of said substrate.
Claim 8
Dependent Claim 33 words
The composite structure of claim 1 wherein: said substrate comprises a composite having a core and a cladding material; and said copper base alloy forming one of said core and said cladding material.
Claim 9
Dependent Claim 82 words
An integrated circuit assembly for electrical applications, said assembly comprising: a lead frame formed from a composite structure; said composite structure having a substrate formed from a copper alloy consisting essentially of 19% to about 28% nickel and the balance essentially copper and a coating covering at least a portion of said substrate; said coating being formed from a tin-containing material; and said nickel in said alloy retarding the growth of copper-tin intermetallic compounds and diffusion of said copper through said coating.
Claim 10
Dependent Claim 82 words
An integrated circuit assembly for electrical applications, said assembly comprising: a lead frame formed from a composite structure; said composite structure having a substrate formed from a copper alloy consisting essentially of 19% to about 28% nickel and the balance essentially copper and a coating covering at least a portion of said substrate; said coating being formed from a tin-containing material; and said nickel in said alloy retarding the growth of copper-tin intermetallic compounds and diffusion of said copper through said coating.
Claim 11
Dependent Claim 44 words
The integrated circuit assembly of claim 8 further comprising: at least one electrical connector; said lead frame being bonded to said at least one electrical connector; and said bond between said lead frame and each said electrical connector being effected at said coated portion.
Claim 12
Dependent Claim 27 words
The integrated circuit assembly of claim 9 further comprising: a semiconductor chip; and said lead frame being connected to said chip by at least one lead wire.
Claim 13
Dependent Claim 24 words
The integrated circuit assembly of claim 8 wherein said coating comprises: a stripe of said tin-containing material plated on a surface of said substrate.
Claim 14
Dependent Claim 24 words
The integrated circuit assembly of claim 8 wherein: said copper alloy consists essentially of 19% to about 26% nickel and the balance essentially copper.
Claim 15
Dependent Claim 18 words
The integrated circuit assembly of claim 8 wherein: said copper alloy further includes up to about 25% zinc.
Claim 16
Dependent Claim 23 words
The integrated circuit assembly of claim 8 further comprising: said tin-containing material being selected from the group consisting of tin and tin alloys.
Claim 17
Dependent Claim 27 words
The integrated circuit assembly of claim 8 further comprising: said tin-containing material comprising a tin solder consisting essentially of about 40% lead and the balance essentially tin.

References Cited (Backward Citations)

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US3162512A Cited
US3097965A Cited
US3490125A Cited
US3482303A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-03 1987-10-03 1988-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-03 1991-10-03 1992-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-03 1995-10-03 1996-04-03 $7700.00 Window Closed / Lapsed

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