US4436653A
Expired / Lapsed
US
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Stable liquid detergent compositions
Assignee: Procter and Gamble Co
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Filing: 1982-03-18
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Granted: 1984-03-13
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Expires: 2002-03-18
Abstract
Abstract Stable liquid detergent compositions containing nonionic, amine oxide and alcohol polyethoxylate sulfate surfactants and a water-soluble detergency builder are disclosed. The compositions are single phase isotropic liquids which exhibit improved freeze-thaw stability. The polyethoxylate sulfate surfactant enhances detergency performance on textiles that have been softened with a conventional cationic fabric softener.
Inventors
- 👤 Ronald L. Jacobsen
- 👤 Dean C. Hanley
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 07:17
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086; C11D1/00; C11D1/66; C11D1/75; C11D1/83; C11D1/02; C11D1/12; C11D1/29; C11D1/72; C11D3/26; C11D3/33
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
334 words
A stable liquid detergent composition comprising: (a) from about 3% to about 20% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 2% to about 15% of an amine oxide surfactant having the formula ##STR5## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 1% to about 10% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacelate or citrate detergency builder capable of sequestering calcium and magnesium ions in water solution; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 2
Dependent Claim
334 words
A stable liquid detergent composition comprising: (a) from about 3% to about 20% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 2% to about 15% of an amine oxide surfactant having the formula ##STR5## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 1% to about 10% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacelate or citrate detergency builder capable of sequestering calcium and magnesium ions in water solution; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 3
Dependent Claim
26 words
The composition of claim 1 wherein, in the nonionic surfactant, R is a C 10-15 alkyl group and n is from about 3 to about 8.
Claim 4
Dependent Claim
17 words
The composition of claim 1 wherein the amine oxide surfactant is a C 12-16 alkyl dimethylamine oxide.
Claim 5
Dependent Claim
20 words
The composition of claim 1 wherein, in the alcohol polyethoxylate sulfate surfactant, m is from about 2 to about 3.
Claim 6
Dependent Claim
20 words
The composition of claim 1 wherein the water-soluble detergency builder is sodium or potassium nitrilotriacetate or citrate, or mixtures thereof.
Claim 7
Dependent Claim
108 words
The composition of claim 1 comprising from about 5% to about 10% of an ethoxylated alcohol nonionic surfactant of the formula R(OC 2 H 4 ) n OH wherein R is a C 10-15 alkyl group and n is from about 3 to about 8, from about 3% to about 10% of a C 12-16 alkyl dimethylamine oxide, and from about 2% to about 6% of an alcohol polyethoxylate sulfate surfactant of the formula R 4 O(C 2 H 4 O) m SO 3 M wherein R 4 is a C 10-18 alkyl group, m is from about 2 to about 3 and M is sodium or potassium.
Claim 8
Dependent Claim
28 words
The composition of claim 6 wherein the nonionic, amine oxide and polyethoxylate sulfate surfactants and the builder together represent less than about 28% by weight of the composition.
Claim 9
Dependent Claim
35 words
The composition of claims 1 or 7 comprising from about 5% to about 16% of a hydrotrope selected from the group consisting of sodium and potassium toluene sulfonate, xylene sulfonate, cumene sulfonate, and mixtures thereof.
Claim 10
Dependent Claim
320 words
A stable liquid detergent composition comprising: (a) from about 5% to about 10% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 3% to about 10% of an amine oxide surfactant having the formula ##STR6## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 2% to about 6% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacetate; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 11
Dependent Claim
320 words
A stable liquid detergent composition comprising: (a) from about 5% to about 10% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 3% to about 10% of an amine oxide surfactant having the formula ##STR6## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 2% to about 6% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacetate; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 12
Dependent Claim
26 words
The composition of claim 9 wherein, in the nonionic surfactant, R is a C 10-15 alkyl group and n is from about 3 to about 8.
Claim 13
Dependent Claim
17 words
The composition of claim 9 wherein the amine oxide surfactant is a C 12-16 alkyl dimethylamine oxide.
Claim 14
Dependent Claim
20 words
The composition of claim 9 wherein, in the alcohol polyethoxylate sulfate surfactant, m is from about 2 to about 3.
Claim 15
Dependent Claim
28 words
The composition of claim 12 wherein the nonionic, amine oxide and polyethoxylate sulfate surfactants and the nitrilotriacetate together represent less than about 28% by weight of the composition.
Claim 16
Dependent Claim
33 words
The composition of claims 9 comprising from about 5% to about 16% of a hydrotrope selected from the group consisting of sodium and potassium toluene sulfonate, xylene sulfonate, cumene sulfonate, and mixtures thereof.
Claim 17
Dependent Claim
33 words
The composition of claims 13 comprising from about 5% to about 16% of a hydrotrope selected from the group consisting of sodium and potassium toluene sulfonate, xylene sulfonate, cumene sulfonate, and mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-03-13 | 1987-09-12 | 1988-03-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-03-13 | 1991-09-12 | 1992-03-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-03-13 | 1995-09-12 | 1996-03-13 | $7700.00 | Window Closed / Lapsed |