← Back to Patent Explorer
US4436653A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable liquid detergent compositions

Assignee: Procter and Gamble Co
•
Filing: 1982-03-18
•
Granted: 1984-03-13
•
Expires: 2002-03-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Stable liquid detergent compositions containing nonionic, amine oxide and alcohol polyethoxylate sulfate surfactants and a water-soluble detergency builder are disclosed. The compositions are single phase isotropic liquids which exhibit improved freeze-thaw stability. The polyethoxylate sulfate surfactant enhances detergency performance on textiles that have been softened with a conventional cationic fabric softener.

Inventors

  • 👤 Ronald L. Jacobsen
  • 👤 Dean C. Hanley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 07:17
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086; C11D1/00; C11D1/66; C11D1/75; C11D1/83; C11D1/02; C11D1/12; C11D1/29; C11D1/72; C11D3/26; C11D3/33

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 334 words
A stable liquid detergent composition comprising: (a) from about 3% to about 20% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 2% to about 15% of an amine oxide surfactant having the formula ##STR5## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 1% to about 10% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacelate or citrate detergency builder capable of sequestering calcium and magnesium ions in water solution; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 2
Dependent Claim 334 words
A stable liquid detergent composition comprising: (a) from about 3% to about 20% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 2% to about 15% of an amine oxide surfactant having the formula ##STR5## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 1% to about 10% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacelate or citrate detergency builder capable of sequestering calcium and magnesium ions in water solution; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 3
Dependent Claim 26 words
The composition of claim 1 wherein, in the nonionic surfactant, R is a C 10-15 alkyl group and n is from about 3 to about 8.
Claim 4
Dependent Claim 17 words
The composition of claim 1 wherein the amine oxide surfactant is a C 12-16 alkyl dimethylamine oxide.
Claim 5
Dependent Claim 20 words
The composition of claim 1 wherein, in the alcohol polyethoxylate sulfate surfactant, m is from about 2 to about 3.
Claim 6
Dependent Claim 20 words
The composition of claim 1 wherein the water-soluble detergency builder is sodium or potassium nitrilotriacetate or citrate, or mixtures thereof.
Claim 7
Dependent Claim 108 words
The composition of claim 1 comprising from about 5% to about 10% of an ethoxylated alcohol nonionic surfactant of the formula R(OC 2 H 4 ) n OH wherein R is a C 10-15 alkyl group and n is from about 3 to about 8, from about 3% to about 10% of a C 12-16 alkyl dimethylamine oxide, and from about 2% to about 6% of an alcohol polyethoxylate sulfate surfactant of the formula R 4 O(C 2 H 4 O) m SO 3 M wherein R 4 is a C 10-18 alkyl group, m is from about 2 to about 3 and M is sodium or potassium.
Claim 8
Dependent Claim 28 words
The composition of claim 6 wherein the nonionic, amine oxide and polyethoxylate sulfate surfactants and the builder together represent less than about 28% by weight of the composition.
Claim 9
Dependent Claim 35 words
The composition of claims 1 or 7 comprising from about 5% to about 16% of a hydrotrope selected from the group consisting of sodium and potassium toluene sulfonate, xylene sulfonate, cumene sulfonate, and mixtures thereof.
Claim 10
Dependent Claim 320 words
A stable liquid detergent composition comprising: (a) from about 5% to about 10% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 3% to about 10% of an amine oxide surfactant having the formula ##STR6## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 2% to about 6% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacetate; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 11
Dependent Claim 320 words
A stable liquid detergent composition comprising: (a) from about 5% to about 10% of an ethoxylated alcohol or ethoxylated alkyl phenol nonionic surfactant of the formula R(OC 2 H 4 ) n OH, wherein R is selected from the group consisting of aliphatic hydrocarbon radicals containing from about 8 to about 15 carbon atoms and alkyl phenyl radicals in which the alkyl group contains from about 8 to about 12 carbon atoms, n is from about 3 to about 9, and said nonionic surfactant has an HLB value of from about 10 to about 13; (b) from about 3% to about 10% of an amine oxide surfactant having the formula ##STR6## wherein R 1 is an alkyl, hydroxyalkyl, alkoxyhydroxypropyl, alkoxyhydroxyethyl, alkyl amido or alkyl carboxylate radical in which the alkyl and alkoxy portions contain from about 8 to about 18 carbon atoms, R 2 and R 3 are selected from the group consisting of methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, or said groups joined together to form a cyclic structure in which the nitrogen is part of a heterocyclic ring, and n is from 0 to about 10; (c) from about 2% to about 6% of an alcohol polyethoxylate sulfate surfactant having the formula R 4 O(C 2 H 4 O) m SO 3 M, wherein R 4 is an alkyl or hydroxyalkyl radical containing from about 10 to about 18 carbon atoms, m is from about 2 to about 10 and M is a compatible cation; (d) from about 10% to about 20% of a water-soluble nitrilotriacetate; provided that components (a), (b), (c) and (d) together represent less than about 40% by weight of the composition; (e) from 0% to about 25% of a hydrotrope; (f) up to about 89% water; said liquid detergent composition being in isotropic form and having a pH of from about 8 to about 13 in a 0.2% water solution at 20° C.
Claim 12
Dependent Claim 26 words
The composition of claim 9 wherein, in the nonionic surfactant, R is a C 10-15 alkyl group and n is from about 3 to about 8.
Claim 13
Dependent Claim 17 words
The composition of claim 9 wherein the amine oxide surfactant is a C 12-16 alkyl dimethylamine oxide.
Claim 14
Dependent Claim 20 words
The composition of claim 9 wherein, in the alcohol polyethoxylate sulfate surfactant, m is from about 2 to about 3.
Claim 15
Dependent Claim 28 words
The composition of claim 12 wherein the nonionic, amine oxide and polyethoxylate sulfate surfactants and the nitrilotriacetate together represent less than about 28% by weight of the composition.
Claim 16
Dependent Claim 33 words
The composition of claims 9 comprising from about 5% to about 16% of a hydrotrope selected from the group consisting of sodium and potassium toluene sulfonate, xylene sulfonate, cumene sulfonate, and mixtures thereof.
Claim 17
Dependent Claim 33 words
The composition of claims 13 comprising from about 5% to about 16% of a hydrotrope selected from the group consisting of sodium and potassium toluene sulfonate, xylene sulfonate, cumene sulfonate, and mixtures thereof.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-13 1987-09-12 1988-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-13 1991-09-12 1992-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-13 1995-09-12 1996-03-13 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag