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Carboxyl-containing compositions and their polymerization

Assignee: Novartis Corp
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Filing: 1982-06-07
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Granted: 1984-03-06
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Expires: 2002-06-07
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Abstract

Abstract Polymerizable compositions comprise (a) a compound containing (i) at least one acryloyloxy or methacryloyloxy group, (ii) at least one allyl, methallyl, or 1-propenyl group attached, either directly or through an oxygen atom or an oxycarbonyl group, to a carbon atom which forms part of an aromatic or cycloaliphatic nucleus, and (iii) at least one carboxylic acid group, (b) a compound containing at least two mercaptan groups directly attached to aliphatic carbon atoms, in a proportion as to supply at least 0.8 such --SH group per allyl, methallyl, and 1-propenyl group in (a) but less than 1.0 such --SH group in (a) per acryloyl, methacryloyl, allyl, methallyl, and 1-propenyl group. Examples of (a) are 2,2-bis(3-allyl-4-(3-(methacryloyloxy)-2-(2-carboxyethylcarbonyloxy)propoxy)phenyl)propane, 1-(allyloxycarbonyl)-2,4-bis(3-(methacryloyloxy)-2-(2-carboxyethylcarbonyloxy)propoxycarbonyl)benzene, and diallyl bis(3-(methacryloyloxy)-2-(2-carboxyethylcarbonyloxy)propyl) esters of benzophenone-3,4,3',4'-tetracarboxylic acid. Examples of (b) are pentaerythritol tetrathioglycollate, trimethylolpropane trithioglycollate, and 3,6-dioxa-1,8-dimercapto-octane. The compositions may be polymerized by means of actinic irradiation in the presence of an added or "built-in" photosensitizer or by the action of a free-radical catalyst. They are especially useful in the production of printed circuits.

Inventors

  • 👤 Edward Irving

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:39
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/0275; C; C08; C08F; C08F2/00; C08F2/46; C08F2/56; C09; C09D; C09D4/00; Y; Y10; Y10S; Y10S525/00; Y10S525/921

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 136 words
A polymerizable composition comprising (a) a compound containing in the molecule (i) at least one group selected from acryloyloxy and methacryloyloxy groups, (ii) at least one group selected from allyl, methallyl, and 1-propenyl groups each of which is attached, either directly or through an oxygen atom or an oxycarbonyl group (--OCO--), to a carbon atom which forms part of an aromatic or cycloaliphatic nucleus, and (iii) at least one carboxylic acid (--COOH) group, (b) a compound containing, per molecule, at least two mercaptan groups directly attached to an aliphatic carbon atom or atoms, in a proportion as to supply at least 0.8 such mercaptan group per group selected from allyl, methallyl and 1-propenyl groups in (a) but less than 1.0 such mercaptan group per group selected from acryloyl, methacryloyl, allyl, methallyl, and 1-propenyl groups in (a).
Claim 2
Dependent Claim 136 words
A polymerizable composition comprising (a) a compound containing in the molecule (i) at least one group selected from acryloyloxy and methacryloyloxy groups, (ii) at least one group selected from allyl, methallyl, and 1-propenyl groups each of which is attached, either directly or through an oxygen atom or an oxycarbonyl group (--OCO--), to a carbon atom which forms part of an aromatic or cycloaliphatic nucleus, and (iii) at least one carboxylic acid (--COOH) group, (b) a compound containing, per molecule, at least two mercaptan groups directly attached to an aliphatic carbon atom or atoms, in a proportion as to supply at least 0.8 such mercaptan group per group selected from allyl, methallyl and 1-propenyl groups in (a) but less than 1.0 such mercaptan group per group selected from acryloyl, methacryloyl, allyl, methallyl, and 1-propenyl groups in (a).
Claim 3
Dependent Claim 21 words
A composition of claim 1 in which the total of the groups (i) and (ii) in (a) is at least three.
Claim 4
Dependent Claim 48 words
A composition of claim 1 in which the or each said acryloyloxy or methacryloyloxy group is attached to an aromatic, cycloaliphatic, or heterocyclic nucleus through a group of formula ##STR27## where R denotes either a hydrogen atom or a monovalent acyl residue of an at least dicarboxylic acid.
Claim 5
Dependent Claim 90 words
A composition of claim 3 wherein R in formula I is further of formula --CO--R.sup.1 --COOH II where R 1 denotes an alkylene, arylene, or aralkylene group, any of which groups may be substituted by one or more allyl, methallyl, or 1-propenyl groups or by one or more carboxylic acid groups, the said alkylene group and the alkylene portion of the aralkylene group having from 2 to 10 carbon atoms, and the said arylene group and the arylene portion of the aralkylene group having from 6 to 10 carbon atoms.
Claim 6
Dependent Claim 70 words
A composition of claim 1, in which component (a) is a polyhydric phenol, at least two phenolic hydroxyl groups of which are esterified with acryloyl or methacryloyl groups through a carboxylic acid-containing group of formula ##STR28## where R denotes a monovalent acyl radical of an at least dicarboxylic acid, and at least two phenolic hydroxyl groups of which are directly etherified with groups chosen from allyl, methallyl, and 1-propenyl groups.
Claim 7
Dependent Claim 83 words
A composition of claim 1 in which component (a) is a polyhydric phenol, at least two phenolic hydroxyl groups of which are esterified with groups chosen from acryloyl and methacryloyl groups through a carboxylic acid-containing group of formula ##STR29## where R denotes a monovalent acyl radical of an at least dicarboxylic acid, the polyhydric phenol being substituted directly on carbon atoms in one or more benzene or naphthalene nucleus or nuclei by at least two groups selected from allyl, methallyl, and 1-propenyl groups.
Claim 8
Dependent Claim 29 words
A composition of claim 1 wherein component (b) is an ester of a monomercaptanalkylenecarboxylic acid with a polyhydric alcohol or of an aliphatic monomercaptanmonohydric alcohol with a polycarboxylic acid.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-06 1987-09-05 1988-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-06 1991-09-05 1992-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-06 1995-09-05 1996-03-06 $7700.00 Window Closed / Lapsed

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