US4434278A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Phosphate esters of acrylated epoxides
Assignee: Hi Tek Polymers Inc
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Filing: 1982-09-27
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Granted: 1984-02-28
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Expires: 2002-09-27
Abstract
Abstract Radiation curable monomers useful in coating compositions are prepared by reacting part of the epoxy groups of a polyepoxide resin with acrylic or methacrylic acid followed by esterifying the remaining epoxy groups with phosphoric acid.
Inventors
- 👤 Ronald J. Skiscim
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 18:43
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/14; C08G59/1494; C08F; C08F299/00; C08F299/02; C08F299/026; C08F299/028; Y; Y10; Y10S; Y10S525/00; Y10S525/922
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
87 words
A radiation curable composition prepared by the process of reacting 1 mole of a polyepoxide having n epoxide groups per molecule, wherein n has a value of 2-4, with about n-1 moles of acrylic acid or methacrylic acid, followed by reacting the resulting product with about 0.5 to 1 mole of phosphoric when n is 2 and 1 mole of phosphoric acid when n is 3 or 4 in the presence of at least about 1.0 equivalent of a hydroxyl group-containing material per mole of phosphoric acid.
Claim 2
Dependent Claim
87 words
A radiation curable composition prepared by the process of reacting 1 mole of a polyepoxide having n epoxide groups per molecule, wherein n has a value of 2-4, with about n-1 moles of acrylic acid or methacrylic acid, followed by reacting the resulting product with about 0.5 to 1 mole of phosphoric when n is 2 and 1 mole of phosphoric acid when n is 3 or 4 in the presence of at least about 1.0 equivalent of a hydroxyl group-containing material per mole of phosphoric acid.
Claim 3
Dependent Claim
11 words
The composition of claim 1 wherein the acid is acrylic acid.
Claim 4
Dependent Claim
11 words
The composition of claim 1 wherein the acid is methacrylic acid.
Claim 5
Dependent Claim
12 words
The composition of claim 1 wherein the hydroxyl group-containing material is water.
Claim 6
Dependent Claim
15 words
The composition of claim 1 wherein the hydroxyl-containing material is an aliphatic hydroxyl group-containing compound.
Claim 7
Dependent Claim
18 words
The composition of claim 5 wherein the aliphatic hydroxyl group-containing material is a C 1 -C 20 alcohol.
Claim 8
Dependent Claim
16 words
The composition of claim 1 wherein the polyepoxide is a polyglycidyl ether of a dihydric phenol.
Claim 9
Dependent Claim
65 words
A radiation curable composition prepared by the process of reacting about 1 mole of a polyepoxide having about 2 epoxide groups per molecule with about 1 mole of acrylic acid, followed by reaction of the resulting product with about 1 mole to about 0.5 mole of phosphoric acid in the presence of at least about 1.0 equivalent of hydroxyl group per mole of phosphoric acid.
Claim 10
Dependent Claim
65 words
A radiation curable composition prepared by the process of reacting about 1 mole of a polyepoxide having about 2 epoxide groups per molecule with about 1 mole of acrylic acid, followed by reaction of the resulting product with about 1 mole to about 0.5 mole of phosphoric acid in the presence of at least about 1.0 equivalent of hydroxyl group per mole of phosphoric acid.
Claim 11
Dependent Claim
103 words
A process for preparing an ultraviolet curable monomer which produces good adhesion to metal in cured state coatings, which comprises reacting about 1 mole of a polyepoxide having n epoxide groups per molecule wherein n has a value of about 2 to about 4 with about n-1 moles of acrylic acid, followed by reaction of the resulting product with about 0.5 to about 1 mole of phosphoric acid when n is 2 and 1 mole of phosphoric acid when n is 3 or 4 in the presence of at least about 1 equivalent of a hydroxyl group-containing material per mole of phosphoric acid.
Claim 12
Dependent Claim
103 words
A process for preparing an ultraviolet curable monomer which produces good adhesion to metal in cured state coatings, which comprises reacting about 1 mole of a polyepoxide having n epoxide groups per molecule wherein n has a value of about 2 to about 4 with about n-1 moles of acrylic acid, followed by reaction of the resulting product with about 0.5 to about 1 mole of phosphoric acid when n is 2 and 1 mole of phosphoric acid when n is 3 or 4 in the presence of at least about 1 equivalent of a hydroxyl group-containing material per mole of phosphoric acid.
Claim 13
Dependent Claim
16 words
The process of claim 9 wherein the hydroxyl group-containing material is an aliphatic hydroxyl group-containing compound.
Claim 14
Dependent Claim
11 words
The process of claim 9 wherein the hydroxy-containing material is water.
Claim 15
Dependent Claim
18 words
The process of claim 9 wherein the aliphatic hydroxyl group-containing material is a C 1 -C 20 alcohol.
Claim 16
Dependent Claim
16 words
The process of claim 9 wherein the polyepoxide is a polyglycidyl ether of a dihydric phenol.
Claim 17
Dependent Claim
30 words
The process of claim 9 wherein the reaction is conducted in the presence of a reactive diluent, wherein said reactive diluent contains one to about six unsaturated groups per molecule.
Claim 18
Dependent Claim
33 words
The process of claim 14 wherein the reactive diluent is present in the amount of about 0 to about 75 weight percent based on total weight of acrylated phosphated polyepoxide and reactive diluent.
Claim 19
Dependent Claim
20 words
The process of claim 15 wherein the reactive diluent is present in the amount of 20 to 50 weight percent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-27 | 1987-08-29 | 1988-02-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-27 | 1991-08-29 | 1992-02-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-27 | 1995-08-29 | 1996-02-28 | $7700.00 | Window Closed / Lapsed |