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US4432848A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiation cured, high temperature pressure-sensitive adhesive

Assignee: Permacel
•
Filing: 1981-11-19
•
Granted: 1984-02-21
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Expires: 2001-11-19
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Abstract

Abstract Pressure-sensitive adhesives with superior high temperature adhesion properties are prepared by radiation curing of an adhesive composition comprising a simple block copolymer as the elastomer component.

Inventors

  • 👤 Ralf Korpman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 16:53
CPC Classifications
C; C08; C08F; C08F287/00; C09; C09J; C09J4/00; C09J4/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 125 words
An adhesive possessing good solvent resistance and high temperature cohesive strength prepared by high energy radiation curing of an adhesive composition comprising (a) an elastomer component comprising an A-B block copolymer wherein A represents a poly(alkenylarene) block and B represents a polyisoprene block, (b) a tackifier resin component comprising a polyisoprene block compatible tackifier resin, said resin being employed in an amount of from about 50 to 100 parts by weight for 100 parts by weight of the elastomer component, and (c) a coupling agent component, said coupling agent component being an acrylic or a methacrylic acid ester of a di- to tetra-functional polyol, in an amount of from about 5 to 25 parts by weight per 100 parts by weight of the elastomer component.
Claim 2
Dependent Claim 125 words
An adhesive possessing good solvent resistance and high temperature cohesive strength prepared by high energy radiation curing of an adhesive composition comprising (a) an elastomer component comprising an A-B block copolymer wherein A represents a poly(alkenylarene) block and B represents a polyisoprene block, (b) a tackifier resin component comprising a polyisoprene block compatible tackifier resin, said resin being employed in an amount of from about 50 to 100 parts by weight for 100 parts by weight of the elastomer component, and (c) a coupling agent component, said coupling agent component being an acrylic or a methacrylic acid ester of a di- to tetra-functional polyol, in an amount of from about 5 to 25 parts by weight per 100 parts by weight of the elastomer component.
Claim 3
Dependent Claim 44 words
An adhesive according to claim 1 wherein the elastomer component consist substantially solely of A-B block copolymer and wherein the amount of radiation employed is from about 3 to 12 megarads with the amount of radiation varying inversely with the amount of coupling agent.
Claim 4
Dependent Claim 66 words
An adhesive according to claim 1 wherein the elastomer component comprises a major portion of an A-B block copolymer and a minor proportion of an A-B-A block copolymer wherein A and B represent poly(alkenylarene) block and polyisoprene block respectively, and wherein the amount of radiation employed is from about 3 to 12 megarads with the amount of radiation varying inversely with the amount of coupling agent.
Claim 5
Dependent Claim 18 words
An adhesive according to claim 1 wherein the coupling agent component of the adhesive composition is trimethylolpropane triacrylate.
Claim 6
Dependent Claim 153 words
An adhesive possessing good solvent resistance and high temperature cohesive strength prepared by high energy radiation curing of an adhesive composition comprising (a) an elastomer component consisting substantially solely of an A-B block copolymer wherein A represents a poly(alkenylarene) block and B represents a polyisoprene block, (b) a tackifier resin component comprising a polyisoprene block compatible tackifier resin, said resin being employed in an amount of from about 50 to 100 parts by weight for 100 parts by weight of the elastomer component, and (c) a coupling agent component, said coupling agent component being an acrylic or methacrylic acid ester of a di- to tetra-functional polyol, in an amount of from about 5 to 25 parts by weight per 100 parts by weight of the elastomer component wherein the amount of radiation employed is about 3 to about 12 megarads with the amount of radiation varying inversely with the amount of coupling agent.
Claim 7
Dependent Claim 153 words
An adhesive possessing good solvent resistance and high temperature cohesive strength prepared by high energy radiation curing of an adhesive composition comprising (a) an elastomer component consisting substantially solely of an A-B block copolymer wherein A represents a poly(alkenylarene) block and B represents a polyisoprene block, (b) a tackifier resin component comprising a polyisoprene block compatible tackifier resin, said resin being employed in an amount of from about 50 to 100 parts by weight for 100 parts by weight of the elastomer component, and (c) a coupling agent component, said coupling agent component being an acrylic or methacrylic acid ester of a di- to tetra-functional polyol, in an amount of from about 5 to 25 parts by weight per 100 parts by weight of the elastomer component wherein the amount of radiation employed is about 3 to about 12 megarads with the amount of radiation varying inversely with the amount of coupling agent.
Claim 8
Dependent Claim 18 words
An adhesive according to claim 5 wherein the coupling agent component of the adhesive composition is trimethylolpropane triacrylate.

References Cited (Backward Citations)

US2956904A Cited
US3787531A Cited
US3681190A Cited
US4069123A Cited
US4133731A Cited
US4151057A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-02-20 1987-08-22 1988-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-02-20 1991-08-22 1992-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-02-20 1995-08-22 1996-02-21 $7700.00 Window Closed / Lapsed

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