Crosslinked pressure sensitive adhesive compositions

Claim 2

A pressure sensitive adhesive composition comprising a blend of: 1. a pressure sensitive adhesive polymer selected from the class consisting of: i. homopolymers of alkyl esters of acrylic and methacrylic acids and ii. copolymers of at least one alkyl ester of acrylic and methacrylic acid present in an amount of at least 35% by weight of the copolymer together with at least one other polymerizable comonomer; and 2.

Claim 3

from about 0.1-10.0%, as based on the weight of polymer solids, of a quinone compound corresponding to the formulae: ##STR2## wherein R is selected from the group consisting of hydrogen, halogen,

Claim 4

from about 0.1-10.0%, as based on the weight of polymer solids, of a quinone compound corresponding to the formulae: ##STR2## wherein R is selected from the group consisting of hydrogen, halogen,

Claim 5

alkyl radicals, aryl radicals and alkoxy radicals. 2. The adhesive composition of claim 1, wherein said copolymerizable comonomer is selected from the group consisting of vinyl esters, vinyl esters, vinyl halides, vinylidene halides, ethylenically unsaturated carboxylic acids, nitriles of ethylenically unsaturated monocarboxylic acids, anhydrides of ethylenically unsaturated dicarboxylic acids and C 1 -C 4 alkyl half esters of maleic and fumaric acids.

Claim 6

The adhesive composition of claim 1, wherein said adhesive polymer has a Williams plasticity of up to about 2.5.

Claim 7

The adhesive composition of claim 1, which is in the form of an organic solvent solution.

Claim 8

The adhesive composition of claim 1, which is in the form of an aqueous emulsion.

Claim 9

The adhesive composition of claim 1, which is in solid form.

Claim 10

The adhesive composition of claim 1, wherein said quinone compound is present in a concentration of from about 0.5-2.0%, as based on the weight of polymer solids.

Claim 11

The adhesive composition of claim 7, wherein said quinone compound is selected from the group consisting of phenanthrenequinone, 1,4-naphthoquinone and 1,2-naphthoquinone.

Claim 12

A process for improving the adhesive and cohesive properties of pressure sensitive adhesive compositions based on pressure sensitive adhesive polymers containing moieties therein derived from alkyl esters of acrylic and methacrylic acid, said process comprising the steps of: A. blending (1) a pressure sensitive adhesive polymer selected from the class consisting of: i. homopolymers of alkyl esters of acrylic and methacrylic acids and ii. copolymers of at least one alkyl ester of acrylic and methacrylic acid present in an amount of at least 35% by weight of the copolymer together with at least one other copolymerizable comonomer; with (2) from about 0.1-10%, as based on the weight of polymer solids of a quinone compound corresponding to the formulae: ##STR3## wherein R is selected from the group consisting of hydrogen, halogen, alkyl radicals, aryl radicals, and alkoxy radicals; and B. exposing said pressure sensitive adhesive blend to radiation having a wavelength of from about 2000 to 4000 A for a period of time sufficient to effect crosslinking thereof.

Claim 13

A process for improving the adhesive and cohesive properties of pressure sensitive adhesive compositions based on pressure sensitive adhesive polymers containing moieties therein derived from alkyl esters of acrylic and methacrylic acid, said process comprising the steps of: A. blending (1) a pressure sensitive adhesive polymer selected from the class consisting of: i. homopolymers of alkyl esters of acrylic and methacrylic acids and ii. copolymers of at least one alkyl ester of acrylic and methacrylic acid present in an amount of at least 35% by weight of the copolymer together with at least one other copolymerizable comonomer; with (2) from about 0.1-10%, as based on the weight of polymer solids of a quinone compound corresponding to the formulae: ##STR3## wherein R is selected from the group consisting of hydrogen, halogen, alkyl radicals, aryl radicals, and alkoxy radicals; and B. exposing said pressure sensitive adhesive blend to radiation having a wavelength of from about 2000 to 4000 A for a period of time sufficient to effect crosslinking thereof.

Claim 14

The process of claim 9, wherein said copolymerizable comonomer is selected from the group consisting of vinyl esters, vinyl ethers, vinyl halides, vinylidene halides, ethylenically unsaturated carboxylic acids, nitriles of ethylenically unsaturated monocarboxylic acids, anhydrides of ethylenically unsaturated dicarboxylic acids and C 1 -C 4 alkyl half esters of maleic and fumaric acids.

Claim 15

The process of claim 9, wherein prior to irradiation, said adhesive polymer has a Williams plasticity of up to about 2.5.

Claim 16

The process of claim 9, wherein said quinone compound is present in a concentration of from about 0.5-2.0%, as based on the weight of polymer solids.

Claim 17

The process of claim 12, wherein said quinone compound is selected from the group consisting of phenanthrenequinone, 1,4-naphthoquinone and 1,2-naphthoquinone.

Claim 18

The crosslinked pressure sensitive adhesive composition prepared by the process of claim 9.