US4430473A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Composites made from thermosetting compositions containing hemiformals of phenol
Assignee: Union Carbide Corp
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Filing: 1982-01-19
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Granted: 1984-02-07
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Expires: 2002-01-19
Abstract
Abstract There are described composites containing from about 20 to about 70 weight percent of a reinforcing material, such as glass, carbon, graphite, or aromatic polyamide fiber, and from about 30 to about 80 weight percent of a thermosetting composition which contains hemiformals of phenol and methylolated phenol and a polymer miscible with the hemiformal.
Inventors
- 👤 George L. Brode
- 👤 Sui-Wu Chow
- 👤 Warren F. Hale
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 03:45
CPC Classifications
C; C08; C08L; C08L59/00; C08G; C08G4/00; C08G8/00; C08G8/04; C08K; C08K5/00; C08K5/04; C08K5/06; C08K5/13; C08K7/00; C08K7/02; C08L61/00; C08L61/04; C08L61/06; C08L61/20; C08L67/00; C08L69/00; C08L71/00
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
299 words
A reinforced composite made by a liquid injection molding process said composite comprising from 20 to 70 weight percent of a reinforcing material, based in the weight of the composite, and from 30 to 80 weight percent, based on the weight of the composite, of a liquid thermosetting solution, the solution comprising: (I) from 40 to 80 weight percent, based on the total weight of the solution, of a hemiformal composition of a phenol having any one of the formulas: ##STR15## wherein n is a positive number of greater than 1, b is 1 to about 5, and c is 1 to about 3, d is 0 to about 2, the sum of c and d is at least 1 and no greater than 3, the sum of c, d and x is at least 1 and no greater than 5, x is 0 to 3, R is a monovalent radical selected from the group consisting of alkyl from 1 to 18 carbon atoms, cycloalkyl from 5 to 8 carbon atoms, aryl containing from 1 to 3 aromatic rings, aralkyl, alkaryl, alkoxy containing from 1 to 18 carbon atoms, aroxy containing 1 to 3 aromatic nuclei, a halide radical, alkyl sulfides having from 1 to 18 carbon atoms, aryl sulfides having from 1 to 3 aromatic nuclei, and a radical derived from linseed oil or tung oil, wherein x is 0 for at least 50 mole percent, based on the hemiformal composition, of the hemiformal composition; and (II) from 20 to 60 weight percent, based on the total weight of the solution, of a polymer capable of forming solution with the hemiformal composition of (1), said polymer being from the group; phenol-formaldehyde resoles, phenol formaldehyde novolacs, aromatic polyesters, aromatic polycarbonates, unsaturated polyesters, aromatic polyethers, urea-formaldehyde resins and melamine-formaldehyde resins.
Claim 2
Dependent Claim
299 words
A reinforced composite made by a liquid injection molding process said composite comprising from 20 to 70 weight percent of a reinforcing material, based in the weight of the composite, and from 30 to 80 weight percent, based on the weight of the composite, of a liquid thermosetting solution, the solution comprising: (I) from 40 to 80 weight percent, based on the total weight of the solution, of a hemiformal composition of a phenol having any one of the formulas: ##STR15## wherein n is a positive number of greater than 1, b is 1 to about 5, and c is 1 to about 3, d is 0 to about 2, the sum of c and d is at least 1 and no greater than 3, the sum of c, d and x is at least 1 and no greater than 5, x is 0 to 3, R is a monovalent radical selected from the group consisting of alkyl from 1 to 18 carbon atoms, cycloalkyl from 5 to 8 carbon atoms, aryl containing from 1 to 3 aromatic rings, aralkyl, alkaryl, alkoxy containing from 1 to 18 carbon atoms, aroxy containing 1 to 3 aromatic nuclei, a halide radical, alkyl sulfides having from 1 to 18 carbon atoms, aryl sulfides having from 1 to 3 aromatic nuclei, and a radical derived from linseed oil or tung oil, wherein x is 0 for at least 50 mole percent, based on the hemiformal composition, of the hemiformal composition; and (II) from 20 to 60 weight percent, based on the total weight of the solution, of a polymer capable of forming solution with the hemiformal composition of (1), said polymer being from the group; phenol-formaldehyde resoles, phenol formaldehyde novolacs, aromatic polyesters, aromatic polycarbonates, unsaturated polyesters, aromatic polyethers, urea-formaldehyde resins and melamine-formaldehyde resins.
Claim 3
Dependent Claim
53 words
A reinforced composite as in claim 1 wherein (I) of the solution is present in a concentration of from 50 to 70 weight percent, based on the weight of the solution, and (II) is present in a concentration of from 30 to 50 weight percent based on the weight of the liquid solution.
Claim 4
Dependent Claim
55 words
A reinforced composite as in claim 1 or claim 2 wherein the reinforcing material is present in a concentration of from 45 to 70 weight percent, based on the weight of the composite, and the solution is present in a concentration of from 30 to 55 weight percent based on the weight of the solution.
Claim 5
Dependent Claim
22 words
A reinforced composite as in claim 1 wherein the reinforcing material is glass fiber, graphite fiber, carbon fiber or aromatic polyamide fiber.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-06 | 1987-08-08 | 1988-02-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-06 | 1991-08-08 | 1992-02-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-06 | 1995-08-08 | 1996-02-07 | $7700.00 | Window Closed / Lapsed |