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US3959433A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of warm runner injection molding phenolic resins with para-substituted phenol

Assignee: Union Carbide Corp
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Filing: 1974-09-06
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Granted: 1976-05-25
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Expires: 1994-09-06
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Abstract

Abstract There is disclosed a thermosetting phenolic resin composition, suitable for use in injection molding, which resin composition contains a molding grade phenolic resin and an effective amount of a reactive compound (e.g., para-t-butylphenol) that is capable of reducing the viscosity of molding compositions containing said phenolic resin composition to a processable viscosity at a temperature at which the period of time within which said molding composition cures to a thermoset state is longer than the period of time that said molding composition is in the runner during a normal injection molding operation. There is also disclosed molding compositions containing said phenolic resin composition, and an injection molding process utilizing the same.

Inventors

  • 👤 Marvin Edward Sauers

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 07:49
CPC Classifications
C; C08; C08J; C08J5/00; B; B29; B29C; B29C45/00; B29C45/0001; C08K; C08K5/00; C08K5/04; C08K5/13; C08J2361/00; C08J2361/04; C08J2361/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 303 words
In an injection molding process wherein a molding composition is fused and plasticized in injection means, wherein the fused and plasticized molding composition is injected through a runner system into a mold cavity, and wherein the runner system is maintained at a temperature at which the period of time within which said molding composition cures to a thermoset state is longer than the normal residence time of said molding composition in said runner system during said injection molding process, the improvement which comprises employing as said molding composition a composition suitable for use in injection molding, and which contains a phenolic resin composition comprising (a) a molding grade phenolic resin, and (b) an effective amount of a reactive phenolic compound that is capable of reducing the viscosity of molding compositions containing said molding grade phenolic resin to a processable viscosity at a temperature at which the period of time within which said molding composition cures to a thermoset state is longer than the period of time that said molding composition is in the runner during a normal injection molding operation, wherein said molding composition is adapted for use in an injection molding operation wherein the molding composition is fused and plasticized in injection means, and is injected by said injection means into a mold cavity through a runner which connects said injection means with said mold cavity, wherein said reactive phenolic compound is a compound having a melting point within the range of from about 35° to about 160°C., wherein said reactive phenolic compound is a parasubstituted phenol wherein the para substituent is alkyl, cycloalkyl, cycloalkenyl, phenyl, alkylphenyl, or hydroxyphenylalkyl, and wherein said reactive phenolic compound is employed in an amount within the range of from about 5 to about 35 parts by weight, per 100 parts of said molding grade phenolic resin.
Claim 2
Dependent Claim 303 words
In an injection molding process wherein a molding composition is fused and plasticized in injection means, wherein the fused and plasticized molding composition is injected through a runner system into a mold cavity, and wherein the runner system is maintained at a temperature at which the period of time within which said molding composition cures to a thermoset state is longer than the normal residence time of said molding composition in said runner system during said injection molding process, the improvement which comprises employing as said molding composition a composition suitable for use in injection molding, and which contains a phenolic resin composition comprising (a) a molding grade phenolic resin, and (b) an effective amount of a reactive phenolic compound that is capable of reducing the viscosity of molding compositions containing said molding grade phenolic resin to a processable viscosity at a temperature at which the period of time within which said molding composition cures to a thermoset state is longer than the period of time that said molding composition is in the runner during a normal injection molding operation, wherein said molding composition is adapted for use in an injection molding operation wherein the molding composition is fused and plasticized in injection means, and is injected by said injection means into a mold cavity through a runner which connects said injection means with said mold cavity, wherein said reactive phenolic compound is a compound having a melting point within the range of from about 35° to about 160°C., wherein said reactive phenolic compound is a parasubstituted phenol wherein the para substituent is alkyl, cycloalkyl, cycloalkenyl, phenyl, alkylphenyl, or hydroxyphenylalkyl, and wherein said reactive phenolic compound is employed in an amount within the range of from about 5 to about 35 parts by weight, per 100 parts of said molding grade phenolic resin.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein the reactive phenolic compound is p-t-butylphenol.
Claim 4
Dependent Claim 12 words
The process of claim 1 wherein the reactive phenolic compound is p-cumylphenol.
Claim 5
Dependent Claim 32 words
The process of claim 1 wherein the reactive phenolic compound is at least one member of the group consisting of p-ethylphenol, p-isopropylphenol, p-t-butylphenol, p-cumylphenol, para-phenylphenol, styrenated phenol, para-cyclohexylphenol, para-cyclohexenylphenol, bisphenol-A, and beta-naphthol.
Claim 6
Dependent Claim 12 words
The process of claim 1 wherein the phenolic resin is a resole.
Claim 7
Dependent Claim 12 words
The process of claim 1 wherein the phenolic resin is a novolak.
Claim 8
Dependent Claim 36 words
The process of claim 6 wherein the reactive phenolic compound is employed in an amount within the range of from about 10 to about 15 parts by weight per 100 parts by weight of said novolak.

References Cited (Backward Citations)

US2736718A Cited
US2809178A Cited
US2970121A Cited
US3299167A Cited
US3351605A Cited
US3660552A Cited
US3812228A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-25 1979-11-24 1980-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-25 1983-11-24 1984-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-25 1987-11-24 1988-05-25 $7700.00 Window Closed / Lapsed

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