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US4429099A Expired / Lapsed US ⏱️ 0.0 years remaining

Phenol terminated polymers and epoxies therefrom

Assignee: University of Akron
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Filing: 1982-11-22
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Granted: 1984-01-31
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Expires: 2002-11-22
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Abstract

Abstract The invention sets forth novel telechelic (terminally functional) prepolymers which may be reacted to form curable epoxides. On account of the incorporation of saturated elastomer chains into the prepolymers improved epoxides arise having increased moisture resistance and less brittleness than conventional epoxides. These prepolymers may be straight chain or three-armed star, emanating from a common phenyl ring nucleus. Molecular weights of the prepolymers range from about 700 to 50,000 (linear) and from about 1000 to about 75,000 (three-arm star). The epoxides are useful as coatings, in adhesives, as additives, and the like.

Inventors

  • 👤 Joseph P. Kennedy
  • 👤 Suhas Guhaniyogi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:10
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/32; C08G59/3218; C08F; C08F8/00; C08F8/08; C08G59/02; C08G59/04; C08G59/06; C08G59/063; C08G59/22; C08G59/24; C08G59/245

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 46 words
A telechelic prepolymer, comprising: ##STR12## where n is 2 or 3 and Y is ##STR13## wherein R 1 and R 2 may be the same or different and are selected from the group consisting of --H, --OH, and --CH 3 and x is a positive integer.
Claim 2
Dependent Claim 46 words
A telechelic prepolymer, comprising: ##STR12## where n is 2 or 3 and Y is ##STR13## wherein R 1 and R 2 may be the same or different and are selected from the group consisting of --H, --OH, and --CH 3 and x is a positive integer.
Claim 3
Dependent Claim 31 words
A telechelic prepolymer according to claim 1, wherein x is from 2 to about 700 and the telechelic group is selected from the group consisting of resorcinol, phloroglucinol, 1,3-dimethyl-2-hydroxybenzene and phenol.
Claim 4
Dependent Claim 20 words
A telechelic prepolymer as in claim 2, wherein R 1 and R 2 are --H and x is about 30.
Claim 5
Dependent Claim 13 words
A telechelic prepolymer according to claim 3, wherein n is equal to 2.
Claim 6
Dependent Claim 13 words
A telechelic prepolymer according to claim 3, wherein n is equal to 3.
Claim 7
Dependent Claim 47 words
A telechelic epoxy prepolymer, comprising: ##STR14## where n is 2 or 3 and Z is: ##STR15## wherein R 1 and R 2 may be the same or different and are selected from the group consisting of --H, --OH, and --CH 3 and n is a positive integer.
Claim 8
Dependent Claim 47 words
A telechelic epoxy prepolymer, comprising: ##STR14## where n is 2 or 3 and Z is: ##STR15## wherein R 1 and R 2 may be the same or different and are selected from the group consisting of --H, --OH, and --CH 3 and n is a positive integer.
Claim 9
Dependent Claim 24 words
A telechelic epoxy prepolymer according to claim 6 wherein x is between about 2 and 700 and R 1 and R 2 are --H.
Claim 10
Dependent Claim 25 words
A telechelic epoxy prepolymer according to claim 7, wherein prepolymer is cured with amine selected from the group consisting of ethylene diamine and triethylene tetramine.
Claim 11
Dependent Claim 18 words
A telechelic epoxy prepolymer according to claim 8, wherein said amine cured prepolymer is flexible and moisture resistant.
Claim 12
Dependent Claim 17 words
A telechelic epoxy prepolymer according to claim 9, wherein amine cured prepolymer is used as a coating.

References Cited (Backward Citations)

US3060140A Cited
US3309339A Cited
US3370038A Cited
US4316973A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-01-30 1987-08-01 1988-01-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-01-30 1991-08-01 1992-01-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-01-30 1995-08-01 1996-01-31 $7700.00 Window Closed / Lapsed

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