US4429067A
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Polyethylene terephthalate molding compositions
Assignee: EIDP Inc
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Filing: 1982-10-27
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Granted: 1984-01-31
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Expires: 2002-10-27
Abstract
Abstract Use of a selected benzoate oligomer has been found to reduce mold deposits and to lower volatility without impairing crystallization rates of polyethylene terephthalate molding blends which contain an ionic hydrocarbon copolymer or ionic salt of a hydrocarbon acid, over polyethylene terephthalate blends which contained the ionic component and other additives.
Inventors
- 👤 Sumner A. Barenberg
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 15:31
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08K5/10; C08L; C08L23/00; C08L23/02; C08L23/025; C08L25/00; C08L25/02; C08L67/00; C08L67/02
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
234 words
A polyethylene terephthalate dry blend consisting essentially of (a) 20-90% by weight of components (a), (b) and (c) of at least one polyethylene terephthalate having an inherent viscosity of at least 0.4 dl/g, as measured by ASTM D-2857, (b) 1-10% by weight of components (a), (b) and (c) of at least one sodium or potassium salt of a hydrocarbon carboxylic acid of 9-25 carbon atoms or at least one sodium or potassium salt of an ionic hydrocarbon copolymer of an α-olefin of 2-5 carbon atoms and an α,β-ethylenically unsaturated carboxylic acid of 3-5 carbon atoms in which the carboxyl groups have been at least partially neutralized with Na + or K + cations, provided the amount present is sufficient to provide a H H /H C ratio of less than 0.25 to the blend, (c) 0.1-10% by weight of components (a), (b) and (c) of at least one benzoate oligomer of the formula ##STR15## wherein --R-- is selected from the class consisting of ##STR16## wherein --R" is H-- or alkyl of 1-3 carbon atoms or ##STR17## --R 1 -- is selected from the class consisting of alkylene of 2-6 carbon atoms, arylene or alicyclic alkylene of 6-8 carbon atoms, and X is a cardinal number of between 1 ad 5, provided that the amount present is sufficient to lower the TpK of a blend of (a) and (b) by at least about 4° C.
Claim 2
Dependent Claim
234 words
A polyethylene terephthalate dry blend consisting essentially of (a) 20-90% by weight of components (a), (b) and (c) of at least one polyethylene terephthalate having an inherent viscosity of at least 0.4 dl/g, as measured by ASTM D-2857, (b) 1-10% by weight of components (a), (b) and (c) of at least one sodium or potassium salt of a hydrocarbon carboxylic acid of 9-25 carbon atoms or at least one sodium or potassium salt of an ionic hydrocarbon copolymer of an α-olefin of 2-5 carbon atoms and an α,β-ethylenically unsaturated carboxylic acid of 3-5 carbon atoms in which the carboxyl groups have been at least partially neutralized with Na + or K + cations, provided the amount present is sufficient to provide a H H /H C ratio of less than 0.25 to the blend, (c) 0.1-10% by weight of components (a), (b) and (c) of at least one benzoate oligomer of the formula ##STR15## wherein --R-- is selected from the class consisting of ##STR16## wherein --R" is H-- or alkyl of 1-3 carbon atoms or ##STR17## --R 1 -- is selected from the class consisting of alkylene of 2-6 carbon atoms, arylene or alicyclic alkylene of 6-8 carbon atoms, and X is a cardinal number of between 1 ad 5, provided that the amount present is sufficient to lower the TpK of a blend of (a) and (b) by at least about 4° C.
Claim 3
Dependent Claim
31 words
The blend of claim 1 wherein reinforcing or filling material is additionally present in an amount of between about 5 and 55 percent by weight of composition and is glass fiber.
Claim 4
Dependent Claim
23 words
The composition of claim 1 wherein component (b) is a sodium or potassium salt of the ionic hydrocarbon copolymer defined in claim 1.
Claim 5
Dependent Claim
26 words
The composition of claim 3 wherein the sodium or potassium salt is the salt of a copolymer of an olefin and an acrylic or methacrylic acid.
Claim 6
Dependent Claim
40 words
The composition of claim 1 wherein component (c) is at least one benzoate oligomer of the formula ##STR18## wherein n is a cardinal number of between 2 and 6 and X is a cardinal number of between 1 and 10.
Claim 7
Dependent Claim
16 words
The composition of claim 5 wherein n in the formula is 4 and X is 2.
Claim 8
Dependent Claim
12 words
A melt blended composition made from the dry blend of claim 1.
Claim 9
Dependent Claim
12 words
A melt blended composition made from the dry blend of claim 2.
Claim 10
Dependent Claim
12 words
A melt blended composition made from the dry blend of claim 3.
Claim 11
Dependent Claim
12 words
A melt blended composition made from the dry blend of claim 4.
Claim 12
Dependent Claim
12 words
A melt blended composition made from the dry blend of claim 5.
Claim 13
Dependent Claim
12 words
A melt blended composition made from the dry blend of claim 6.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-30 | 1987-08-01 | 1988-01-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-30 | 1991-08-01 | 1992-01-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-30 | 1995-08-01 | 1996-01-31 | $7700.00 | Window Closed / Lapsed |