US4098750A
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US
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Organic oxalate plasticized polycarbonate composition
Assignee: General Electric Co
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Filing: 1976-12-08
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Granted: 1978-07-04
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Expires: 1996-12-08
Abstract
Abstract A plasticized polycarbonate composition comprising in admixture a high molecular weight aromatic carbonate polymer and a minor amount of organic oxalates.
Inventors
- 👤 Victor Mark
- 👤 Phillip Steven Wilson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 11:41
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/11; C08K5/36; C08K5/37; C08K5/375
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
278 words
A plasticized polycarbonate composition comprising in admixture a high molecular weight aromatic carbonate polymer prepared by reacting a dihydric phenol with a carbonate precursor and having an I.V. of 0.40 to 1.0 dl./g. in methylene chloride at 25° C., and a minor amount of an organic oxalate of the following formula: ##STR15## wherein R and R" are independently selected from the group consisting of C 1 to C 30 alkyl, aryl of 6 to 14 carbon atoms and substituted aryl wherein the substituents are C 1 to C 30 alkyl, halogen, C 1 to C 30 alkoxy, aryloxy of 6 to 14 carbon atoms, alkylthio of 1 to 30 carbon atoms, arylthio of 6 to 14 carbon atoms, R' is selected from the group consisting of C 1 to C 30 alkylene, arylene of 6 to 14 carbon atoms, alkarylene of 7 to 30 carbon atoms, aralkylene of 7 to 30 carbon atoms and ##STR16## wherein W is selected from the group consisting of: ##STR17## wherein A is ##STR18## and R 4 is hydrogen of C 1 -C 4 alkyl; R is independently selected from the group consisting of hydrogen, C 1 -C 15 alkyl, aryl of 6-14 carbon atoms and substituted aryl wherein the substituents are C 1 -C 5 alkyl; (b) --CH 2 CH 2 --; (c) --CH 2 B-CH 2 --; wherein B is C 1 -C 16 alkylene or arylene of 6 to 14 carbon atoms; ##STR19## wherein a is an integer of 3 to 15; (e) --O--; (f) --S--; ##STR20## X and Y are independently selected from the group consisting of halogen and C 1 -C 12 alkyl; n is 0 or 1.
Claim 2
Dependent Claim
278 words
A plasticized polycarbonate composition comprising in admixture a high molecular weight aromatic carbonate polymer prepared by reacting a dihydric phenol with a carbonate precursor and having an I.V. of 0.40 to 1.0 dl./g. in methylene chloride at 25° C., and a minor amount of an organic oxalate of the following formula: ##STR15## wherein R and R" are independently selected from the group consisting of C 1 to C 30 alkyl, aryl of 6 to 14 carbon atoms and substituted aryl wherein the substituents are C 1 to C 30 alkyl, halogen, C 1 to C 30 alkoxy, aryloxy of 6 to 14 carbon atoms, alkylthio of 1 to 30 carbon atoms, arylthio of 6 to 14 carbon atoms, R' is selected from the group consisting of C 1 to C 30 alkylene, arylene of 6 to 14 carbon atoms, alkarylene of 7 to 30 carbon atoms, aralkylene of 7 to 30 carbon atoms and ##STR16## wherein W is selected from the group consisting of: ##STR17## wherein A is ##STR18## and R 4 is hydrogen of C 1 -C 4 alkyl; R is independently selected from the group consisting of hydrogen, C 1 -C 15 alkyl, aryl of 6-14 carbon atoms and substituted aryl wherein the substituents are C 1 -C 5 alkyl; (b) --CH 2 CH 2 --; (c) --CH 2 B-CH 2 --; wherein B is C 1 -C 16 alkylene or arylene of 6 to 14 carbon atoms; ##STR19## wherein a is an integer of 3 to 15; (e) --O--; (f) --S--; ##STR20## X and Y are independently selected from the group consisting of halogen and C 1 -C 12 alkyl; n is 0 or 1.
Claim 3
Dependent Claim
28 words
The composition of claim 1 wherein the organic oxalate is present in an amount of from 0.05 to about 5.0 parts per hundred parts of aromatic carbonate polymer.
Claim 4
Dependent Claim
14 words
The composition of claim 1 wherein the aromatic carbonate polymer is derived from bisphenol-A.
Claim 5
Dependent Claim
19 words
The composition of claim 1 wherein the aromatic carbonate polymer is a copolymer derived from bisphenol-A and tetrabromo bisphenol-A.
Claim 6
Dependent Claim
14 words
The composition of claim 1 wherein the organic oxalate has the following formula: ##STR21##
Claim 7
Dependent Claim
14 words
The composition of claim 1 wherein the organic oxalate has the following formula: ##STR22##
Claim 8
Dependent Claim
14 words
The composition of claim 1 wherein the organic oxalate has the following formula: ##STR23##
Claim 9
Dependent Claim
14 words
The composition of claim 1 wherein the organic oxalate has the following formula: ##STR24##
References Cited (Backward Citations)
US3275596A
Cited
US3186961A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-03 | 1982-01-02 | 1982-07-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-03 | 1986-01-02 | 1986-07-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-03 | 1990-01-02 | 1990-07-04 | $7700.00 | Window Closed / Lapsed |