US4426511A
Expired / Lapsed
US
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Heat-resisting aromatic polyester resin and process for preparing the same
Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1981-10-21
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Granted: 1984-01-17
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Expires: 2001-10-21
Abstract
Abstract A heat resisting aromatic polyester resin comprising (a) recurring units of the formula (I): ##STR1## wherein X is a bivalent group selected from the group consisting of an unsubstituted or substituted bivalent hydrocarbon group having 1 to 10 carbon atoms,--O--, --S--, --SO 2 --and--CO--, and (b) recurring units of the formula (II): ##STR2## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, their substituted groups, a halogen atom and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR3## in the formulas (I) and (II) may be replaced with units: ##STR4## the ratio of (a)/[(a)+(b)]being from 0.05 to 0.95 by mole. The polyester resin is substantially amorphous and soluble in some organic solvents, and has an excellent heat resistance. The polyester resin is prepared by reacting terephthaloyl chloride with alkali metal salts of at least two kinds of particular bivalent phenolic compounds in the presence of a phase transfer catalyst.
Inventors
- 👤 Masahiro Asada
- 👤 Miyuki Matsuura
- 👤 Kazuya Yonezawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 06:56
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/19; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; C08G63/78; C08G63/82; C08G63/87
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
146 words
An aromatic polyester resin comprising (a) recurring units of the following formula (I): ##STR15## wherein X is a bivalent group selected from the group consisting of a bivalent hydrocarbon group having 1 to 10 carbon atoms, --O--, --S--, --SO 2 -- and --CO--, and (b) recurring units of the following formula (II): ##STR16## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR17## in the formulas (I) and (II) may be replaced with units: ##STR18## the ratio of (a)/[(a)+(b)] being from 0.05 to 0.95 by mole.
Claim 2
Dependent Claim
146 words
An aromatic polyester resin comprising (a) recurring units of the following formula (I): ##STR15## wherein X is a bivalent group selected from the group consisting of a bivalent hydrocarbon group having 1 to 10 carbon atoms, --O--, --S--, --SO 2 -- and --CO--, and (b) recurring units of the following formula (II): ##STR16## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR17## in the formulas (I) and (II) may be replaced with units: ##STR18## the ratio of (a)/[(a)+(b)] being from 0.05 to 0.95 by mole.
Claim 3
Dependent Claim
18 words
The polyester resin of claim 1, wherein the ratio of (a)/[(a)+(b)] is from 0.15 to 0.85 by mole.
Claim 4
Dependent Claim
55 words
The polyester resin of claim 1, wherein the component (b) consists of 99 to 1% by mole of the recurring units (II) in which the group R is a group other than a halogen atom and 1 to 99% by mole of the recurring units (II) in which the group R is a halogen atom.
Claim 5
Dependent Claim
55 words
The polyester resin of claim 1, wherein the component (b) consists of 50 to 99% by mole of the recurring units (II) in which the group R is a group other than a halogen atom and 50 to 1% by mole of the recurring units (II) in which the group R is a halogen atom.
Claim 6
Dependent Claim
55 words
The polyester resin of claim 1, wherein the recurring units (II) are those having the following formula: ##STR19## wherein X is as defined above, R 1 , R 2 , R 3 and R 4 are an alkyl group having 1 to 4 carbon atoms or an alkoxyl group having 1 to 4 carbon atoms.
Claim 7
Dependent Claim
18 words
The polyester resin of claim 1, wherein the intrinsic viscosity of the resin is from 0.1 to 5.0.
Claim 8
Dependent Claim
20 words
The polyester resin of claim 1, wherein the recurring units (a) and (b) are chained in a substantially regular arrangement.
Claim 9
Dependent Claim
182 words
A process for preparing an aromatic polyester resin which comprises reacting terephthaloyl chloride with an alkali metal salt of at least one member selected from bisphenol compounds of the following formula (III): ##STR20## wherein X is a bivalent group selected from the group consisting of a bivalent hydrocarbon group having 1 to 10 carbon atoms, --O--, --S--, --SO 2 -- and --CO--, and an alkali metal salt of at least one member selected from bisphenol compounds of the following formula (IV): ##STR21## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, at a temperature of 0° to 100° C. in the presence of a phase transfer catalyst, wherein the ratio of the alkali metal salt of the bisphenol compound (III) to the alkali metal salt of bisphenol compound (IV) is 0.05/0.95 to 0.95/0.05 by mole.
Claim 10
Dependent Claim
182 words
A process for preparing an aromatic polyester resin which comprises reacting terephthaloyl chloride with an alkali metal salt of at least one member selected from bisphenol compounds of the following formula (III): ##STR20## wherein X is a bivalent group selected from the group consisting of a bivalent hydrocarbon group having 1 to 10 carbon atoms, --O--, --S--, --SO 2 -- and --CO--, and an alkali metal salt of at least one member selected from bisphenol compounds of the following formula (IV): ##STR21## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, at a temperature of 0° to 100° C. in the presence of a phase transfer catalyst, wherein the ratio of the alkali metal salt of the bisphenol compound (III) to the alkali metal salt of bisphenol compound (IV) is 0.05/0.95 to 0.95/0.05 by mole.
Claim 11
Dependent Claim
55 words
The process of claim 8, wherein the bisphenol compounds (IV) are those having the following formula: ##STR22## wherein X is as defined above, and R 1 , R 2 , R 3 and R 4 are an alkyl group having 1 to 4 carbon atoms, or an alkoxyl group having 1 to 4 carbon atoms.
Claim 12
Dependent Claim
82 words
The process of claim 8, wherein the alkali metals salts of at least one bisphenol compound (III) and at least one bisphenol compound (IV) are reacted with a less amount of terephthaloyl chloride than the total amount of said alkali metal salts, and terephthaloyl chloride is added to the resulting reaction mixture in such an amount that the total number of moles of terephthaloyl chloride is equal to the total number of moles of the alkali metal salts and is subsequently reacted.
Claim 13
Dependent Claim
84 words
The process of claim 8, wherein the alkali metal salts of at least one bisphenol compound (III) and at least one bisphenol compound (IV) are reacted with an excess amount of terephthaloyl chloride, and at least one alkali metal salt of the bisphenol compounds (III) and (IV) is added to the resulting reaction mixture in such an amount that the total number of moles of the alkali metal salts is equal to the number of moles of said terephthaloyl chloride and is subsequently reacted.
Claim 14
Dependent Claim
28 words
The process of claim 8, wherein the phase transfer catalyst is a member selected from the group consisting of quaternary ammonium salts, quaternary phosphonium salts and crown ethers.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-16 | 1987-07-18 | 1988-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-16 | 1991-07-18 | 1992-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-16 | 1995-07-18 | 1996-01-17 | $7700.00 | Window Closed / Lapsed |