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US4423226A Expired / Lapsed US ⏱️ 0.0 years remaining

Zinc chloride complex compounds

Assignee: Hoechst AG
•
Filing: 1981-03-16
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Granted: 1983-12-27
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Expires: 2001-03-16
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Abstract

Abstract Zinc chloride complex compounds to which the structure of the general formula (1) ##STR1## can be assigned, in which the individual radicals in the formula have the following meanings: Rhu 1 is a hydrogen atom or an optionally substituted lower alkyl group; R 2 is a hydrogen atom, an optionally substituted lower alkyl group or an optionally substituted phenyl radical; R 3 is a hydrogen atom or an optionally substituted lower alkyl group; R 4 is a hydrogen atom, an optionally substituted lower alkyl group or an optionally substituted phenyl radical; R 5 is a hydrogen atom or a halogen atom or a lower alkyl group or a lower alkoxy group, or R 1 and R 5 together form the o-phenylene radical; R 6 is a hydrogen atom or a halogen atom or a lower alkyl group or a lower alkoxy group; Z is a hydrogen atom or a halogen atom or a lower alkyl group or a cyano, carboxylic acid, carbamoyl or sulfamoyl group or a carbamoyl or sulfamoyl group which is monosubstituted or disubstituted by lower alkyl, or a trifluoromethyl or lower carbalkoxy group, a lower alkoxy group which can be substituted by cyano, an acyloxy group, an acylamino group, a lower alkylamino group or a lower dialkylamino group. They are prepared by reacting a nitroso compound of the formula (2) ##STR2## in which R 3 , R 4 , R 6 and Z have the meanings mentioned above, with an m-aminophenol of the formula (3) ##STR3## in which R 1 , R 2 and R 5 have the meanings mentioned above, in the presence of zinc chloride and in the absence of a base. The zinc chloride complex compounds of the formula (1) can be converted by eliminating the radical Z in the formula or by removing, by oxidative means, this radical Z, in the formula, which is in the ortho-position in relation to the nitrogen atom, or the other hydrogen atom which is in the ortho-position, into the phenoxazine dyestuffs of the formula (4) ##STR4## in which R 1 , R 2 , R 3 , R 4 , R 5 and R 6 have the meanings mentioned above and Z 1 denotes a halogen atom, a lower alkyl group, a cyano, carboxylic acid, carbamoyl or sulfamoyl group, a carbamoyl or sulfamoyl group which is monosubstituted or disubstituted by lower alkyl, or a trifluoromethyl or lower carbalkoxy group or a hydrogen atom and X.sup.(-) represents and anion.

Inventors

  • 👤 Reinhard Mohr
  • 👤 Rudolf Neeb

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 05:34
CPC Classifications
C; C07; C07D; C07D265/00; C07D265/28; C07D265/34; C07D265/38; C07D209/00; C07D209/56; C07D209/80; C07D209/82; C07D209/88; C09; C09B; C09B19/00

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 215 words
A zinc chloride complex compound corresponding to the general formula (1) ##STR34## wherein: R 1 is hydrogen or lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, R 2 is hydrogen or lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, or is phenyl unsubstituted or substituted by substituents belonging to the group comprising chlorine, lower alkyl, lower alkoxy, carbamoyl, sulfamoyl, carbamoyl monosubstituted or disubstituted by lower alkyl, and sulfamoyl monosubstituted or disubstituted by lower alkyl, R 3 is hydrogen or lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, R 4 is hydrogen, lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, or is phenyl unsubstituted or substituted by substituents belonging to the group comprising chlorine, lower alkyl, lower alkoxy, carbamoyl, sulfamoyl, carbamoyl monosubstituted or disubstituted by lower alkyl, and sulfamoyl monosubstituted or disubstituted by lower alkyl, R 5 is hydrogen, halogen, lower alkyl or lower alkoxy, or R 1 and R 5 together form the o-phenylene, R 6 is hydrogen, halogen, lower alkyl or lower alkoxy, Z is lower alkoxy or lower alkoxy substituted by cyano, or is acyloxy, acylamino, lower alkylamino or lower dialkylamino.
Claim 2
Dependent Claim 215 words
A zinc chloride complex compound corresponding to the general formula (1) ##STR34## wherein: R 1 is hydrogen or lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, R 2 is hydrogen or lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, or is phenyl unsubstituted or substituted by substituents belonging to the group comprising chlorine, lower alkyl, lower alkoxy, carbamoyl, sulfamoyl, carbamoyl monosubstituted or disubstituted by lower alkyl, and sulfamoyl monosubstituted or disubstituted by lower alkyl, R 3 is hydrogen or lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, R 4 is hydrogen, lower alkyl unsubstituted or substituted by chlorine, hydroxy, lower alkoxy, cyano, lower alkanoyloxy, carbamoyl or phenyl, or is phenyl unsubstituted or substituted by substituents belonging to the group comprising chlorine, lower alkyl, lower alkoxy, carbamoyl, sulfamoyl, carbamoyl monosubstituted or disubstituted by lower alkyl, and sulfamoyl monosubstituted or disubstituted by lower alkyl, R 5 is hydrogen, halogen, lower alkyl or lower alkoxy, or R 1 and R 5 together form the o-phenylene, R 6 is hydrogen, halogen, lower alkyl or lower alkoxy, Z is lower alkoxy or lower alkoxy substituted by cyano, or is acyloxy, acylamino, lower alkylamino or lower dialkylamino.

References Cited (Backward Citations)

US3894012A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-26 1987-06-27 1987-12-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-26 1991-06-27 1991-12-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-26 1995-06-27 1995-12-27 $7700.00 Window Closed / Lapsed

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