Pressure sensitive hot melt adhesives

Claim 2

A composition comprising (a) an organic polymer containing at least one carboxylic group per polymer molecule, and (b) at least one miscible metal salt of an o-methoxy aryl acid in a ratio of at least 10 -3 moles of total metal salt to moles of polymer carboxylic acid.

Claim 3

A composition according to claim 1 containing (a) at least 60% by weight of an organic polymer containing on the average at least one carboxylic acid group per polymer molecule and (b) 0.10% to 10% by weight of polymer of at least one miscible metal salt of an o-methoxy aryl acid.

Claim 4

A composition according to claim 1 containing (a) at least 60% by weight of an organic polymer comprising at least 60% by weight of monomer residues selected from the group consisting of (C 1 -C 18 )alkyl esters of acrylic and methacrylic acid, containing 0.1 to 10% by weight of carboxylic acid bearing monomer residues, (b) 0.10% to 10% by weight of polymer of at least one miscible metal salt of an o-methoxy aryl acid such that the metallic portion is selected from the group consisting of Groups I A, II A, I B, II B, III B, IV B, V B, VI B, and VIII of the periodic table.

Claim 5

A composition according to claim 3 containing (a) at least 80% by weight of an organic polymer comprising at least 80% by weight monomer residues selected from a class consisting of the (C 1 -C 18 )alkyl esters of acrylic and methacrylic acid and containing 0.1 to 10% by weight of carboxylic acid bearing monomer residues, (b) 0.10% to 10% by weight of polymer of at least one miscible metal salt of an o-methoxy aryl acid such that the metallic portion is selected from the group consisting of Groups I A, II A, II B, I B, IV B, VI B, VII B, and VIII of the periodic table.

Claim 6

A composition according to claim 1 containing (a) at least 50% by weight of an organic polymer comprising at least 80% by weight monomer residues selected from a class consisting of the (C 1 -C 18 )alkyl esters of acrylic and methacrylic acid and containing 0.1 to 10% by weight of carboxylic acid bearing monomer residues such that the glass transition temperature of the polymer is less than 5° C., (b) 0.10% to 10% by weight of polymer of at least one miscible metal salt of an o-methoxy aryl acid such that the metallic portion is selected from the group consisting of groups I A, II A, I B, II B, IV B, VI B, VII B and VIII of the periodic table.

Claim 7

A composition according to claim 1 containing (a) an organic polymer containing at least 60% by weight of monomer residues from the (C 1 -C 18 )alkyl esters of acrylic and methacrylic acid and containing on the average at least one carboxylic acid group per polymer molecule, (b) 0.10% to 10% by weight of polymer of at least one miscible metal salt of an o-methoxy aryl acid having the formula ##STR3## where n=1, 2, or 3 and where R 1 , R 2 , R 3 , and R 4 are independently hydrogen, halogen, nitro, cyano, amino, (C 1 -C 4 )alkyl, (C 1 -C 4 )alkoxy, (C 2 -C 4 )alkenyl, (C 5 -C 8 )cycloalkyl, (C 5 -C 8 )cycloalkenyl, (C 5 -C 8 )cycloalkynyl, phenyl or phenyl(C 1 -C 4 )alkyl, optionally substituted with up to three substituents on the phenyl ring selected from the group consisting of (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl, (C 1 -C 4 )alkoxy, hydrogen, halogen, nitro, or (C 1 -C 4 )alkyloxy (C 1 -C 4 ) alkyl; provided that neither R 1 nor R 4 is (C 1 -C 8 )alkoxy; provided further that R 1 and R 4 may, taken together, form a (C 4 -C 8 )alkyl, (C 5 -C 8 )alkynyl, or (C 2 -C 4 )alkoxy(C 2 -C 4 )alkyl chain; and such that the metallic portion, M n+ , is selected from the group consisting of Groups I A, II A, I B, II B, IV B, VI B, VII B and VIII of the periodic table.

Claim 8

A composition according to claim 6 such that the substituents, R 1 , R 2 , R 3 , and R 4 of the o-methoxy aryl acid anion are independently hydrogen, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl (C 1 -C 4 )alkoxy, halogen, phenyl, benzyl or phenethyl, where the phenyl ring is substituted with up to two substituents selected from the group consisting of hydrogen, (C 1 -C 3 )alkyl, and halogen; provided that neither R 1 nor R 4 is (C 1 -C 4 )alkoxy; and the metal ion is Zn ++ , Zr ++ , Mg ++ , Ca ++ , Na + or K + .

Claim 9

A composition according to claim 7 such that the anion substituents R 1 , R 2 , R 3 , and R 4 of the o-methoxy aryl acid are independently hydrogen, methoxy or chlorine, provided that neither R 1 nor R 4 is methoxy; and the metal ion is Zn ++ .

Claim 10

A composition according to claim 7 such that the o-methoxy aryl acid anion is 2-methoxybenzoate, 2,4-dimethoxybenzoate, 4-chloro-2-methoxybenzoate, or 3-methoxy-2-naphthenoate and the metal ion is Zn ++ .

Claim 11

A composition according to claim 1 containing (a) at least 50% by weight of an organic polymer containing at least 80% by weight of monomer residues from the (C 1 -C 18 )alkyl esters of acrylic and methacrylic acid and containing on the average at least one carboxylic acid group per polymer molecule, (b) 0.10% to 10%, by weight of polymer, of at least one miscible metal salt of an o-methoxy aryl acid given by the formula ##STR4## where n=1 or 2 and where R 1 , R 2 , R 3 , and R 4 are independently hydrogen, halogen, nitro, cyano, amino, (C 1 -C 8 )alkyl, (C 1 -C 8 )alkoxy, (C 2 -C 8 )alkenyl, (C 5 -C 8 )cycloalkyl, (C 5 -C 8 )cycloalkenyl, (C 5 -C 8 )cycloalkynyl, phenyl or phenyl-(C 1 -C 4 )alkyl, optionally substituted with up to three substituents on the phenyl ring selected from the group consisting of (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 1 -C 4 )alkynyl, (C 1 -C 4 )alkoxy, hydrogen, halogen, nitro, or (C 1 -C 4 )alkyloxy (C 1 -C 4 )alkyl; provided that neither R 1 or R 4 is (C 1 -C 8 )alkoxy, and provided further that R 1 and R 4 may, taken together, form a (C 4 -C 8 )alkyl, (C 5 -C 8 )alkenyl, (C 5 -C 8 )alkynyl, or (C 2 -C 4 )alkoxy(C 2 -C 4 )alkyl chain; such that the metallic portion, M n+ , is selected from the group consisting of Zn 2+ , Zr 2+ , Ca 2+ and Mg 2+ and (c) optional fillers, extender pigments, tackifying agents, organic solvents, antioxidants, ultraviolet inhibitors, and plasticizers.

Claim 12

A composition according to claim 1 containing (a) at least 80% by weight of an organic polymer containing at least 80% by weight of monomer residues from the (C 1 -C 18 )alkyl esters of acrylic and methacrylic acids such that the glass transition temperature of the polymer is 0° C. or less and which contains on the average at least one carboxylic acid group per polymer molecule, (b) 0.10 to 10%, by weight of polymer of at least one miscible metal salt of an o-methoxy aryl acid given by the formula ##STR5## where n=1, 2, or 3 and where R 1 , R 2 , R 3 , and R 4 are independently hydrogen, (C 1 -C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 1 -C 4 )alkoxy, halogen, or phenyl, benzyl or phenethyl where the phenyl ring is substituted with up to two substituents selected from the group consisting of hydrogen, halogen and (C 1 -C 3 )alkyl provided that neither R 1 nor R 4 is (C 1 -C 4 )alkoxy; such that the metallic portion, M n+ , is selected from the group consisting of Zn 2+ , Zr 2+ , Cu 2+ , Mg 2+ , Ca 2+ , Na 2+ , K + , Mn 2+ , Ni 2+ , and Co 3+ and (c) optional fillers, extender pigments, tackifying agents, organic solvents, antioxidants, ultraviolet inhibitors and plasticizers.

Claim 13

A composition according to claim 11 containing (a) at least 90% by weight of an organic polymer containing monomer residues selected from the group consisting of butyl acrylate, butyl methacrylate, 2-ethylhexylacrylate, isodecyl methacrylate, acrylic acid, methacrylic acid, itaconic and maleic acid and acryloxypropanoic acid such that the polymer contains between 0.5% and 4%, by weight of carboxylic acid residue, (b) and between 0.5 and 4%, by weight of polymer of a miscible metal salt of an o-methoxy-aryl acid salt selected from the group consisting of zinc 2-methoxybenzoate, zinc 2,4-dimethoxybenzoate, zinc 4-chloro-2-methoxybenzoate and zinc 3-methoxy-2-naphthenoate.