Meta-phenylenediamines

Claim 2

A compound of the general formula ##STR8## in which R represents an alkyl radical containing from 1 to 4 carbon atoms and n is an integer of from 1 to 3, or an acid salt thereof.

Claim 3

A compound according to claim 1 in which n is 2 and R is a methyl radical or a hydrochloride thereof.

Claim 4

A compound according to claim 1 in which n is 2 and R is an ethyl radical or a hydrochloride thereof.

Claim 5

A composition suitable for dyeing keratin fibres which comprises at least one oxidative base and at least one compound as defined in claim 1.

Claim 6

A composition according to claim 4, in which the compound of formula (I) is present in an amount from 0.005 to 2.5% by weight, relative to the total weight of the composition.

Claim 7

A composition according to claim 4, which has a pH from 8 to 11.5.

Claim 8

A composition according to claim 6 which has a pH from 9 to 11.5.

Claim 9

A composition according to claim 4 in which the oxidative base is a para-phenylenediamine or para-aminophenol.

Claim 10

A composition according to claim 8, in which the oxidative base is a para-phenylenediamine of the general formula: ##STR9## or an acid salt thereof, in which formula R 1 , R 2 and R 3 are identical or different and represent a hydrogen atom, an alkyl radical having from 1 to 4 carbon atoms or an alkoxy radical having 1 or 2 carbon atoms, and R 4 and R 5 are identical or different and represent a hydrogen atom, an alkyl radical, a hydroxyalkyl radical, an alkoxyalkyl radical in which the alkoxy group contains 1 or 2 carbon atoms, a carbamylalkyl radical, a mesylaminoalkyl radical, an acetylaminoalkyl radical, a ureidoalkyl radical or a carbethoxyaminoalkyl radical, the alkyl groups in R 4 and R 5 having from 1 to 4 carbon atoms, with the proviso that R 1 and R 3 represent hydrogen if R 4 and R 5 do not represent a hydrogen atom.

Claim 11

A composition according to claim 8 in which the oxidative base is a para-aminophenol of the general formula ##STR10## or an acid salt thereof, in which formula R 6 represents a hydrogen atom, an alkyl radical containing from 1 to 4 carbon atoms or a halogen atom.

Claim 12

A composition according to claim 4 which contains at least one ortho-phenylenediamine or ortho-aminophenol, which is unsubstituted or substituted on the nucleus or on the amino group, or ortho-diphenol.

Claim 13

A composition according to claim 4 which contain a leuco derivative of an indoaniline or indophenol.

Claim 14

A composition according to claim 12, in which the leuco derivative is 4,4'-dihydroxy-2-amino-5-methyldiphenylamine, 4,4'-dihydroxy-2-N-(β-hydroxyethyl)-amino-5-methyl-2'-chlorodiphenylamine, 2,4'-diamino-4-hydroxy-5-methyldiphenylamine, 2,4-dihydroxy-4'-N-(β-methoxyethyl)aminodiphenylamine or 2,4-dihydroxy-5-methyl-4'-N-(β-methoxyethyl)-aminodiphenylamine.

Claim 15

A composition according to claim 4 which contains at least one direct nitrobenzene dyestuff.

Claim 16

A composition according to claim 4 which contains at least one dyestuff precursor of the naphthalene series.

Claim 17

A composition according to claim 4 whcih contains at least one coupler other than a coupler of formula (I).

Claim 18

A composition according to claim 16 in which the other coupler is resorcinol, meta-aminophenol, 2-methyl-5-aminophenol, 2-methyl-5-N-(β-hydroxyethyl)-aminophenol, 6-hydroxybenzomorpholine, 2,6-dimethyl-5-acetylaminophenol, 2-methyl-5-carbethoxyaminophenol, 2-methoxy-5-carbethoxyaminophenol or 2-methyl-5-ureidophenol.

Claim 19

A composition according to claim 4 which at least one dyestuff precursor of the benzene series containing, on the nucleus, at least three substituents which are hydroxyl, methoxy or amino groups.

Claim 20

A composition according to claim 18, in which the dyestuff precursor is 2,6-diaminohydroquinone dihydrochloride, 2,6-diamino-4-N,N-ethylaminophenol trihydrochloride, 2,4-diaminophenol dihydrochloride, 1,2,4-trihydroxy benzene, 2,4,5-trihydroxytoluene or 4-methoxy-2-amino-N-(β-hydroxyethyl)-aniline.

Claim 21

A composition according to claim 4 which contains at least one penetrating agent, foaming agent, thickener, antioxidant, alkalising or acidifying agent, perfume, sequestering agent or film-forming product.

Claim 22

A composition according to claim 20 which contains ammonia, an alkylamine, an alkanolamine, an alkylalkanolamine, sodium or potassium hydroxide or sodium potassium or ammonium carbonate, or lactic, acetic, tartaric or phosphoric acid.

Claim 23

A composition according to claim 4 which contains at least one water-soluble surface-active agent which is an alkyl-benzenesulphonate, alkylnaphthalenesulphonate, sulphate, ether-sulphate or sulphonate of a fatty alcohol, a quaternary ammonium salt, a diethanolamide of a fatty acid, a polyoxyethyleneated acid or alcohol or a polyoxyethyleneated alkylphenol.

Claim 24

A composition according to claim 22 which contains from 0.5 to 50% by weight of surface-active agent, relative to the total weight of the composition.

Claim 25

A composition according to claim 4 which contains at least one organic solvent which is ethanol, isopropanol, glycerol, ethylene glycol, propylene glycol, ethylene glycol monobutyl ether, or diethylene glycol monoethyl ether or monomethyl ether.

Claim 26

A composition according to claim 24, which contains from 1 to 40% by weight of organic solvent, relative to the total weight of the composition.

Claim 27

A composition according to claim 4 which contains at least one thickener which is sodium alginate, gum arabic, methylcellulose, hydroxyethylcellulose, hydroxypropylmethyl cellulose, the sodium salt of carboxymethylcellulose, an acrylic acid polymer or bentonite.

Claim 28

A composition according to claim 26, which contains from 0.5 to 5% by weight of thickener, relative to the total weight of the composition.

Claim 29

A composition according to claim 4 which contains at least one antioxidant which is sodium sulphite, thioglycolic acid, sodium bisulphite, ascorbic acid or hydroquinone.

Claim 30

A composition according to claim 28, which contains from 0.05 to 1.5% by weight of anti-oxidant, relative to the total weight of the composition.

Claim 31

A composition according to claim 4 which is in the form of a liquid, a cream, a gel or an aerosol.

Claim 32

A composition according to claim 4 which is suitable for application to human hair.

Claim 33

Process for dyeing keratin fibres which comprises mixing, at the time of use, a composition as defined in claim 4 with at least one oxidising agent and applying the resulting mixture to the keratin fibres at a temperature from ambient temperature to about 30° C. and for about 5 to about 45 minutes, rinsing the keratin fibres and, optionally, shampooing and rinsing them.

Claim 34

Process according to claim 32 for dyeing human hair.

Claim 35

Process according to claim 32 in which the oxidising agent is hydrogen peroxide, urea peroxide or a per-salt.