Patent US4420498A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4420498A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming a decorative metallic nitride coating

Assignee: Toshiba Corp
•
Filing: 1982-06-22
•
Granted: 1983-12-13
•
Expires: 2002-06-22
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract There is disclosed a method for forming a decorative metallic nitride coating on the surface of a substrate comprising the steps of disposing said substrate to be coated as a cathode in a material gas atmosphere at a pressure of 0.1 to 10 Torr, with said substrate maintained at a temperature of 200° to 1000° C., and applying a voltage of 200 to 8000 V to said substrate to prepare a direct current glow discharge space in the vicinity of said substrate, the improvement which comprises using as said material gas a mixed gas of a halide of titanium, zirconium or hafnium; hydrogen; and nitrogen, and controlling the current density of the electric current flowing through said substrate to be within the range of 0.01 to 1 mA/cm 2 . The method according to the present invention provides a uniform and beautiful metallic nitride coating which has a metallic luster stable with time, is excellent in mar resistance, and is suitable for decoration. Further, according to the method of this invention, a decorative metallic nitride coating capable of varying a tone on a metallic luster surface over a wide range can be formed.

Inventors

  • 👤 Masahiko Hirose
  • 👤 Tsuyoshi Yasui
  • 👤 Yoshiharu Ochi
  • 👤 Masatoshi Nakagawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 04:55
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/44; C23C16/50; C23C16/503; C23C16/22; C23C16/30; C23C16/34

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 127 words
A method for forming a decorative metallic nitride coating on the surface of a substrate comprising the steps of disposing said substrate to be coated as a cathode in a material gas atmosphere at a pressure of 0.1 to 10 Torr, with said substrate maintained at a temperature of 200° to 1000° C., and applying a voltage of 200 to 8000 V to said substrate to prepare a direct current glow discharge space in the vicinity of said substrate, the improvement which comprises using as said material gas a mixed gas of a halide of titanium, zirconium or hafnium; hydrogen; and nitrogen, and controlling the current density of the electric current flowing through said substrate to be within the range of 0.01 to 1 mA/cm 2 .
Claim 2
Independent Claim 127 words
A method for forming a decorative metallic nitride coating on the surface of a substrate comprising the steps of disposing said substrate to be coated as a cathode in a material gas atmosphere at a pressure of 0.1 to 10 Torr, with said substrate maintained at a temperature of 200° to 1000° C., and applying a voltage of 200 to 8000 V to said substrate to prepare a direct current glow discharge space in the vicinity of said substrate, the improvement which comprises using as said material gas a mixed gas of a halide of titanium, zirconium or hafnium; hydrogen; and nitrogen, and controlling the current density of the electric current flowing through said substrate to be within the range of 0.01 to 1 mA/cm 2 .
Claim 3
Dependent Claim 29 words
A method according to claim 1, wherein the current density of the electric current flowing through said substrate is within the range of 0.05 to 0.65 mA/cm 2 .
Claim 4
Dependent Claim 27 words
A method according to claim 1, wherein the composition of said material gas has a molar ratio of a metallic halide:hydrogen:nitrogen being 1:12 to 100:1 to 100.
Claim 5
Dependent Claim 27 words
A method according to claim 3, wherein the composition of said material gas has a molar ratio of a metallic halide:hydrogen:nitrogen being 1:12 to 50:1 to 30.
Claim 6
Dependent Claim 23 words
A method according to claim 1 wherein the halide is selected from the group consisting of titanium tetrachloride, zirconium tetrachloride and hafnium tetrachloride.
Claim 7
Dependent Claim 23 words
A method according to claim 1 which further comprises a step of carrying out a glow discharge post-treatment with a hydrogen gas alone.
Claim 8
Dependent Claim 42 words
A method according to claim 6 wherein the glow discharge post-treatment is carried out under the following conditions: pressure: 0.1 to 10 Torr temperature: 100° to 800° C. voltage: 200 V to 2 KV current density: 0.15 to 10 mA/cm 2 .

References Cited (Backward Citations)

DE863997C Cited
US3437511A Cited
US4226082A Cited
US4197175A Cited
DE2825513A1 Cited
US4212687A Cited
DE2842393A1 Cited
US4254159A Cited
JPS552715A Cited
US4269899A Cited
US4346123A Cited
US4333962A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-12 1987-06-13 1987-12-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-12 1991-06-13 1991-12-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-12 1995-06-13 1995-12-13 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag