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US4419497A
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Process for producing novel hydrogenated resin from five-member cyclic compounds having a conjugated double bond and/or Diels-Alder addition products thereof
Assignee: Eneos Corp
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Filing: 1982-05-17
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Granted: 1983-12-06
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Expires: 2002-05-17
Abstract
Abstract According to the present invention, there is disclosed a process for producing a novel resin which comprises the step of copolymerizing a five-member cyclic compound (component A) having a conjugated double bond and represented by the general formula (A) given below: <IMAGE> GENERAL FORMULA (A) wherein R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers not less than 1 and are in the relation of m+n=6; and/or a Diels-Alder addition product thereof (A) with a co-dimer (component B) of said five-member cyclic compound and 1,3-butadiene by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 200 DEG C. to 350 DEG C. Also disclosed are a process for hydrogenating said novel resin to produce a novel hydrogenated resin and resin compositions containing said hydrogenated resin.
Inventors
- 👤 Shozo Tsuchiya
- 👤 Akio Oshima
- 👤 Hideo Hayashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 16:07
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/04; C08F232/00; C08L; C08L45/00; C08L55/00; C08L55/04; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2804; Y10T428/2852; Y10T428/2878; Y10T428/2883
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
107 words
A process for producing a novel hydrogenated resin which comprises the steps of: (i) copolymerizing a five-member cyclic compound (component A) selected from the group consisting of cyclopentadiene, dicyclopentadiene, and mixtures thereof, with a co-dimer (component B) of cyclopentadiene and 1,3-butadiene selected from the group consisting of tetrahydroindene, vinylnorbornene, and mixtures thereof, by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 220° to 350° C. to obtain a resin; and (ii) hydrogenating said resin to hydrogenate substantially all the carbon-carbon double bonds in the resin.
Claim 2
Dependent Claim
107 words
A process for producing a novel hydrogenated resin which comprises the steps of: (i) copolymerizing a five-member cyclic compound (component A) selected from the group consisting of cyclopentadiene, dicyclopentadiene, and mixtures thereof, with a co-dimer (component B) of cyclopentadiene and 1,3-butadiene selected from the group consisting of tetrahydroindene, vinylnorbornene, and mixtures thereof, by heating a mixture of 20 to 90 parts by weight of said component A and 80 to 10 parts by weight of said component B at a temperature of from 220° to 350° C. to obtain a resin; and (ii) hydrogenating said resin to hydrogenate substantially all the carbon-carbon double bonds in the resin.
Claim 3
Dependent Claim
31 words
The process according to claim 1 wherein component A comprises at least 80% by weight of said five-member cyclic compound selected from the group consisting of cyclopentadiene, dicyclopentadiene, and mixtures thereof.
Claim 4
Dependent Claim
57 words
The process according to claim 1, wherein said mixture is a residual fraction obtained from a reaction mixture of Diels-Alder reaction of 1,3-butadiene with cyclopentadiene by distilling off the major part of vinylnorbornene as the main reaction product of said Diels-Alder reaction, said residual fraction containing 10 to 70% of dicyclopentadiene and 30 to 80% of tetrahydroindene.
Claim 5
Dependent Claim
19 words
The process of claim 3 wherein said 1,3-butadiene and cyclopentadiene mixture is heated to from 80° to 150° C.
Claim 6
Dependent Claim
21 words
The process of claim 4 wherein said residual fraction contains 20 to 40% of dicyclopentadiene and 55 to 75% of tetrahydroindene.
Claim 7
Dependent Claim
40 words
The process according to claim 1, wherein the hydrogenation at the step (ii) is effected at a temperature of from 0° C. to 350° C. and at a hydrogen pressure of from the atmospheric pressure to 200 kg/cm 2 G.
Claim 8
Dependent Claim
16 words
The process of claim 6 wherein hydrogenation (ii) is effected at 150° C. to 260° C.
Claim 9
Dependent Claim
21 words
The process according to claim 1, wherein said hydrogenated resin has a softening point ranging from 50° C. to 160° C.
Claim 10
Dependent Claim
21 words
The process according to claim 8, wherein said hydrogenated resin has a softening point ranging from 60° C. to 130° C.
Claim 11
Dependent Claim
19 words
The process of claim 9 wherein said hydrogenated resin has a softening point from 90° C. to 110° C.
Claim 12
Dependent Claim
28 words
The process of claim 1 wherein said mixture contains 30 to 70 parts by weight of component (A) and 70 to 30 parts by weight of component (B).
Claim 13
Dependent Claim
17 words
The process of claim 11 wherein said mixture is heated to from 220° C. to 320° C.
Claim 14
Dependent Claim
17 words
The process of claim 12 wherein said mixture is heated to from 250° C. to 300° C.
Claim 15
Dependent Claim
15 words
The process of claim 11 wherein said mixture is heated from 1/2 to 15 hours.
Claim 16
Dependent Claim
15 words
The process of claim 14 wherein said mixture is heated from 1 to 7 hours.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-12-05 | 1987-06-06 | 1987-12-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-12-05 | 1991-06-06 | 1991-12-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-12-05 | 1995-06-06 | 1995-12-06 | $7700.00 | Window Closed / Lapsed |