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Polarographic electrode

Assignee: Photovolt Corp
•
Filing: 1982-08-09
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Granted: 1983-12-06
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Expires: 2002-08-09
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Abstract

Abstract An improved 3-pole membrane electrode for polarographic measurements in which an auxiliary electrode is defined having an arc which is generated by rotation about the center point of a disc-shaped working electrode. A preferable liquid junction form of reference electrode is located in the sector defined by the arc of the auxiliary electrode and the center point of the working electrode; and an analyte permeable membrane is intimately conformed over the sensing face of the improved polarographic electrode.

Inventors

  • 👤 Minchen Wang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 06:59
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/30; G01N27/327; G01N27/3271; Y; Y10; Y10S; Y10S435/00; Y10S435/817

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 109 words
A membrane electrode comprising an analyte permeable membrane conformed to a smooth surface of a solidified filler martrix of an insulator material, which smooth surface is further comprised of the exposed surfaces of embedded electrodes which are flush with the adjacent surface of the filler matrix, the electrodes comprising an auxiliary electrode, working electrode, and reference electrode, the geometry of the auxiliary electrode defining a critical boundary which is an arc generated from a radius rotated about a point which is the center of the working electrode, the reference electrode being in the sector defined by the arc of the auxiliary electrode and the center of the working electrode.
Claim 2
Dependent Claim 109 words
A membrane electrode comprising an analyte permeable membrane conformed to a smooth surface of a solidified filler martrix of an insulator material, which smooth surface is further comprised of the exposed surfaces of embedded electrodes which are flush with the adjacent surface of the filler matrix, the electrodes comprising an auxiliary electrode, working electrode, and reference electrode, the geometry of the auxiliary electrode defining a critical boundary which is an arc generated from a radius rotated about a point which is the center of the working electrode, the reference electrode being in the sector defined by the arc of the auxiliary electrode and the center of the working electrode.
Claim 3
Dependent Claim 26 words
The membrane electrode of claim 1 in which the reference electrode at its exposed surface with the filler matrix comprises an element forming a liquid junction.
Claim 4
Dependent Claim 20 words
The membrane electrode of claim 2 in which said reference electrode is juxtaposed with the auxiliary and working electrodes, respectively.
Claim 5
Dependent Claim 15 words
The membrane electrode of claim 3 in which the working electrode comprises a noble metal.
Claim 6
Dependent Claim 14 words
The membrane electrode of claim 4 comprising as the reference electrode, a Ag/AgCl electrode.
Claim 7
Dependent Claim 15 words
The membrane electrode of claim 5 in which the filler matrix comprises a cured epoxy.
Claim 8
Dependent Claim 15 words
The membrane electrode in claim 4 comprising as the reference electrode, a saturated calomel electrode.
Claim 9
Dependent Claim 16 words
The membrane electrode of claim 1 in which the electrode is designed such that (A.sub.Aux /A.sub.W.E.)≧5.
Claim 10
Dependent Claim 26 words
The membrane electrode of claim 8 in which the geometry of the auxiliary electrode is cresentshaped; and the geometry of the working electrode is a disc.
Claim 11
Dependent Claim 22 words
The membrane electrode of claim 1 in which the membrane comprises immobilized glucose oxidase enzyme sandwiched between analyte permeable film membrane layers.

References Cited (Backward Citations)

US3539455A Cited
US3867273A Cited
US4073713A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-05 1987-06-06 1987-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-05 1991-06-06 1991-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-05 1995-06-06 1995-12-06 $7700.00 Window Closed / Lapsed

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