US4419101A
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Chlorine-substituted nitro-para-phenylenediamines, a process for their preparation and their use in dyeing keratin fibres
Assignee: L' O R E A L
•
Filing: 1982-05-24
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Granted: 1983-12-06
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Expires: 2002-05-24
Abstract
Abstract The invention provides new chlorine-substituted nitro-para-phenylenediamines of the formula: ##STR1## in which R 1 and R 2 , which are identical or different, denote hydrogen, a lower alkyl group or a monohydroxylated or polyhydroxylated alkyl group and n is an integer from 2 to 4, and the cosmetically acceptable salts of these compounds. These compounds can be used for hair dyeing.
Inventors
- 👤 Andree Bugaut
- 👤 Jean Cotteret
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 05:24
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/418; A61Q; A61Q5/00; A61Q5/06; A61Q5/065; A61Q5/10; C; C09; C09B; C09B51/00; C09B53/00
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
52 words
A nitro-para-phenylenediamine derivative which corresponds to the formula (I): ##STR6## in which R 1 and R 2 , which are identical or different, denote hydrogen, a lower alkyl group or a monohydroxylated or polyhydroxylated alkyl group and n is an integer from 2 to 4 inclusive, or a cosmetically acceptable salt thereof.
Claim 2
Dependent Claim
52 words
A nitro-para-phenylenediamine derivative which corresponds to the formula (I): ##STR6## in which R 1 and R 2 , which are identical or different, denote hydrogen, a lower alkyl group or a monohydroxylated or polyhydroxylated alkyl group and n is an integer from 2 to 4 inclusive, or a cosmetically acceptable salt thereof.
Claim 3
Dependent Claim
20 words
A derivative according to claim 1 in which the alkyl group denotes a group having 1 to 4 carbon atoms.
Claim 4
Dependent Claim
21 words
A derivative according to claim 1 or 2 in which R 1 and R 2 denote hydrogen or an ethyl group.
Claim 5
Dependent Claim
16 words
A derivative according to claim 1 which is 2-chloro-4-amino-5-nitro-N-β-aminoethyl aniline or a cosmetically acceptable salt thereof.
Claim 6
Dependent Claim
16 words
A derivative according to claim 1 which is 2-chloro-4-amino-5-nitro-N-β-diethylaminoethyl aniline or a cosmetically acceptable salt thereof.
Claim 7
Dependent Claim
30 words
A composition suitable for dyeing keratin fibres which comprises a diluent or carrier and at least one derivative as defined in claim 1 in an amount effective for dyeing hair.
Claim 8
Dependent Claim
31 words
A composition according to claim 6 for dyeing human hair which comprises a cosmetically acceptable medium and at least one said derivative in an amount from 0.001 to 5% by weight.
Claim 9
Dependent Claim
29 words
A composition according to claim 6 or 7, which comprises at least one of water, a lower alkanol or a polyol, glycol or glycol ether, or a mixture thereof.
Claim 10
Dependent Claim
32 words
A composition according to claim 6 or 7 which also comprises at least one of a surface-active agent, thickener, penetrating agent, sequestering agent, film-forming agent, buffer, perfume or alkalising or acidifying agent.
Claim 11
Dependent Claim
34 words
A composition according to claim 6 for use in the direct dyeing of the hair, which also comprises at least one other direct dyestuff which is an azo, anthraquinone, aminoquinone, or nitro benzene dyestuff.
Claim 12
Dependent Claim
24 words
A composition according to claim 6 which is in the form of an aqueous, alcoholic or aqueous-alcoholic solution containing at least one cosmetic resin.
Claim 13
Dependent Claim
16 words
A composition according to claim 10 or 11 which has a pH of 3 to 11.5.
Claim 14
Dependent Claim
16 words
A composition according to claim 10 or 11 which has a pH of 5 to 11.5.
Claim 15
Dependent Claim
20 words
A composition according to claim 6 for use in oxidation dyeing, which also comprises at least one oxidation dyestuff precursor.
Claim 16
Dependent Claim
19 words
A composition according to claim 14 which has a pH of 7 to 11.5 and contains a reducing agent.
Claim 17
Dependent Claim
47 words
Process for dyeing keratin fibres, which comprises applying thereto a composition as defined in claim 6, in an amount effective to dye hair, leaving it on the fibres for 5 to 70 minutes and then rinsing, optionally washing and rinsing again, the fibres and then drying them.
Claim 18
Dependent Claim
30 words
Process for dyeing keratin fibres which comprises applying a composition as defined in claim 11, in an amount effective to dye hair, to washed and rinsed fibres and drying them.
Claim 19
Dependent Claim
54 words
Process for dyeing keratin fibres, which comprises applying thereto a composition as defined in claim 14, in an amount effective to dye hair, to which an oxidising agent has optionally been added, leaving it on the fibres for 10 to 50 minutes and rinsing, optionally shampooing and rinsing the fibres again, and drying them.
Claim 20
Dependent Claim
38 words
Process for the preparation of a derivative as defined in claim 1 which comprises condensing a halogen derivative of the formula ##STR7## with 2-chloro-4-amino-5-nitroaniline where X is halogen and n is an integer of 2 to 4 inclusive.
Claim 21
Dependent Claim
63 words
Process for the preparation of a derivative as defined in claim 1 in which R 1 and R 2 are different from hydrogen, which comprises reacting a halogen derivative of the formula ##STR8## where X is halogen and n is an integer of 2 to 4, with an alkali metal, or alkaline earth metal salt of 2-chloro-4-amino-5-nitro-N-arylsulphonyl-aniline, and hydrolysing the substituted arylsulphonamide obtained.
References Cited (Backward Citations)
GB1127080A
Cited
GB1262752A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1986-12-05 | 1987-06-06 | 1987-12-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-12-05 | 1991-06-06 | 1991-12-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-12-05 | 1995-06-06 | 1995-12-06 | $7700.00 | Window Closed / Lapsed |