Process for separating carbon dioxide and acid gases from a carbonaceous off-gas

Claim 2

A process for the low temperature distillation separation of a carbonaceous off-gas stream containing a quantity of acid gases, such as carbon dioxide, hydrogen sulfide and carbonyl sulfide by separating said off-gas stream into an essentially sulfur free, light fuel gas, an acid gas and a heavy hydrocarbon stream, comprising the steps of: (a) compressing and aftercooling an off-gas containing acid gases, light fuel gases and heavy hydrocarbons; (b) drying the compressed and aftercooled off-gas to remove moisture therefrom; (c) subcooling the combined off-gas and a recycle stream against product streams in a heat exchanger; (d) separating the subcooled off-gas in a distillation column into an initial fuel gas stream as an overhead fraction, a carbon dioxide and sulfide stream as a liquid sidestream containing the major portion of said quantity of acid gases and an initial heavy hydrocarbon and carbon dioxide stream as a bottom liquid fraction; (e) expanding the carbon dioxide and sulfide liquid side stream in an auto refrigeration cycle for the subcooling of the off-gas in the heat exchanger of step (c) before releasing the stream as a carbon dioxide and sulfide product stream; (f) cooling and separating said initial fuel gas stream into a final fuel gas stream containing a minor portion of said quantity of acid gases and a carbon dioxide stream which is recycled to said column as reflux to the distillation column; (g) separating said initial heavy hydrocarbon and carbon dioxide stream into a carbon dioxide stream containing the balance of said quantity of acid gases which is recycled to the compression stage of the process and a substantially pure heavy hydrocarbon stream which is a product stream of said process.

Claim 3

The process according to claim 1 wherein the compression and aftercooling of the off-gases occurs in multiple stages.

Claim 4

A process for the low temperature distillation separation of a carbonaceous, pressurized off-gas stream containing a quantity of acid gases, such as carbon dioxide, hydrogen sulfide and carbonyl sulfide by separating said off-gas stream into an essentially sulfur free, light fuel gas, an acid gas and a heavy hydrocarbon stream, comprising the steps of: (a) subcooling a pressurized off-gas containing acid gases, light fuel gases and heavy hydrocarbons and a recycle stream combined with said off-gases against product streams in a heat exchanger; (b) separating the subcooled off-gas in a distillation column into an initial fuel gas stream as an overhead fraction, a carbon dioxide and sulfide stream as a liquid sidestream containing the major portion of said quantity of acid gases and an initial heavy hydrocarbon and carbon dioxide stream as a bottom liquid fraction; (c) expanding the carbon dioxide and sulfide liquid sidestream in an auto refrigeration cycle for the subcooling of the off-gas in the heat exchanger of step (a) before releasing the stream as a carbon dioxide and sulfide product stream; (d) cooling and separating said initial fuel gas stream into a final fuel gas stream containing a minor portion of said quantity of acid gases and a carbon dioxide stream which is recycled to said column as reflux to the distillation column; (e) separating said initial heavy hydrocarbon and carbon dioxide stream into a carbon dioxide stream containing the balance of said quantity of acid gases which is recycled to the compression stage of the process and a substantially pure heavy hydrocarbon stream which is a product stream of said process.

Claim 5

A process for the low temperature distillation separation of a carbonaceous, pressurized off-gas stream containing a quantity of acid gases, such as carbon dioxide, hydrogen sulfide and carbonyl sulfide by separating said off-gas stream into an essentially sulfur free, light fuel gas, an acid gas and a heavy hydrocarbon stream, comprising the steps of: (a) subcooling a pressurized off-gas containing acid gases, light fuel gases and heavy hydrocarbons and a recycle stream combined with said off-gases against product streams in a heat exchanger; (b) separating the subcooled off-gas in a distillation column into an initial fuel gas stream as an overhead fraction, a carbon dioxide and sulfide stream as a liquid sidestream containing the major portion of said quantity of acid gases and an initial heavy hydrocarbon and carbon dioxide stream as a bottom liquid fraction; (c) expanding the carbon dioxide and sulfide liquid sidestream in an auto refrigeration cycle for the subcooling of the off-gas in the heat exchanger of step (a) before releasing the stream as a carbon dioxide and sulfide product stream; (d) cooling and separating said initial fuel gas stream into a final fuel gas stream containing a minor portion of said quantity of acid gases and a carbon dioxide stream which is recycled to said column as reflux to the distillation column; (e) separating said initial heavy hydrocarbon and carbon dioxide stream into a carbon dioxide stream containing the balance of said quantity of acid gases which is recycled to the compression stage of the process and a substantially pure heavy hydrocarbon stream which is a product stream of said process.

Claim 6

A process according to claim 1 or 3 wherein the carbon dioxide and sulfide liquid sidestream is expanded to cool the initial light fuel stream to separate a carbon dioxide reflux stream for the distillation column and to provide a portion of the refrigeration for the cooling of the off-gas in the main heat exchanger.

Claim 7

The process according to claim 1 or 3 wherein the off-gas is derived from an in-situ oil shale retorting operation.

Claim 8

The process according to claim 1 or 3 wherein the autorefrigeration is produced by expanding the carbon dioxide and sulfide stream in an expander turbine to generate refrigeration for the main heat exchanger and for export.

Claim 9

The process of claim 1 or 3 wherein the subcooled off-gas is separated in a two-tiered distillation column.

Claim 10

The process of claim 7 wherein sulfides are removed from the off-gas in the upper portion of the distillation column and heavy hydrocarbons are removed from the bottom portion of the distillation column.

Claim 11

The process according to claim 1 or 3 wherein the off-gas is derived from a coal gasification operation.

Claim 12

The process according to claim 1 or 3 wherein the off-gas is derived from an oxygen fireflooding operation.

Claim 13

The process according to claim 1 or 3 wherein the off-gas is derived from a carbon dioxide miscible flood enhanced oil recovery operation.

Claim 14

The process of claim 1 or 3 wherein the initial heavy hydrocarbon and carbon dioxide stream is expanded and heat exchanged against the initial fuel gas stream so as to recover refrigeration for the distillation column.

Claim 15

The process of claim 1 or 3 wherein the feed off-gas comprises 90% or greater of carbon dioxide with the remaining composition comprising fuel components and sulfides.

Claim 16

A process for recycling a portion of an oil shale retort off-gas stream containing a quantity of acid gases, such as carbon dioxide, hydrogen sulfide and carbonyl sulfide by low temperature distillation separation of said off-gas stream into an essentially sulfur free, light fuel gas, an acid gas and a heavy hydrocarbon stream, comprising the steps of: (a) compressing and aftercooling an off-gas from an oil shale retort containing acid gases, light fuel gases and heavy hydrocarbons; (b) drying the compressed and aftercooled off-gas to remove moisture therefrom; (c) subcooling the combined off-gas and a recycle stream against product streams in a heat exchanger; (d) separating the subcooled off-gas in a two tiered distillation column into an initial fuel gas stream as an overhead fraction, an initial carbon dioxide and sulfide acid gas stream as a liquid sidestream containing the major portion of said quantity of acid gases and an initial heavy hydrocarbon and carbon dioxide stream as a bottom liquid fraction; (e) expanding the initial carbon dioxide and sulfide stream in order to cool the initial fuel gas stream in a heat exchanger; (f) cooling and separating said initial fuel gas stream into a final fuel gas stream containing a minor portion of said quantity of acid gases and a carbon dioxide stream which is recycled to said column as reflux to the distillation column; (g) further expanding the carbon dioxide and sulfide side stream in an expander turbine to produce auto refrigeration for the subcooling of the off-gas in the heat exchanger of step (c); (h) separating said initial heavy hydrocarbon and carbon dioxide stream into a carbon dioxide stream containing the balance of said quantity of acid gases which is recycled to the compression stage of the process and a substantially pure heavy hydrocarbon stream which is a product stream of said process; (i) recycling said carbon dioxide and sulfide stream to an oil shale retort as a product stream.

Claim 17

A process for recycling a portion of an oil shale retort off-gas stream containing a quantity of acid gases, such as carbon dioxide, hydrogen sulfide and carbonyl sulfide by low temperature distillation separation of said off-gas stream into an essentially sulfur free, light fuel gas, an acid gas and a heavy hydrocarbon stream, comprising the steps of: (a) compressing and aftercooling an off-gas from an oil shale retort containing acid gases, light fuel gases and heavy hydrocarbons; (b) drying the compressed and aftercooled off-gas to remove moisture therefrom; (c) subcooling the combined off-gas and a recycle stream against product streams in a heat exchanger; (d) separating the subcooled off-gas in a two tiered distillation column into an initial fuel gas stream as an overhead fraction, an initial carbon dioxide and sulfide acid gas stream as a liquid sidestream containing the major portion of said quantity of acid gases and an initial heavy hydrocarbon and carbon dioxide stream as a bottom liquid fraction; (e) expanding the initial carbon dioxide and sulfide stream in order to cool the initial fuel gas stream in a heat exchanger; (f) cooling and separating said initial fuel gas stream into a final fuel gas stream containing a minor portion of said quantity of acid gases and a carbon dioxide stream which is recycled to said column as reflux to the distillation column; (g) further expanding the carbon dioxide and sulfide side stream in an expander turbine to produce auto refrigeration for the subcooling of the off-gas in the heat exchanger of step (c); (h) separating said initial heavy hydrocarbon and carbon dioxide stream into a carbon dioxide stream containing the balance of said quantity of acid gases which is recycled to the compression stage of the process and a substantially pure heavy hydrocarbon stream which is a product stream of said process; (i) recycling said carbon dioxide and sulfide stream to an oil shale retort as a product stream.