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Acrylic modified anionic water dispersible styrene allyl alcohol copolymers

Assignee: Valspar Corp
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Filing: 1982-09-29
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Granted: 1983-11-08
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Expires: 2002-09-29
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Abstract

Abstract This invention provides a graft copolymer of at least one acrylic monomer and a random copolymer of a styrene and allyl alcohol, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both. It also provides anionic aqueous dispersions of such graft copolymers and coating compositions containing them.

Inventors

  • 👤 Michael A. Tobias

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 04:47
CPC Classifications
C; C09; C09D; C09D151/00; C09D151/003; C08; C08F; C08F257/00; C08F257/02; C08F261/00; C08F261/02; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 102 words
A coating composition comprising: (A) a water-dispersible graft copolymer of an acrylic monomer or monomers and a random copolymer of a styrene and between about 20 weight percent and 30 weight percent of the random copolymer of allyl alcohol, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both, said graft copolymer being neutralized with ammonia, ammonium hydroxide, or a tertiary amine; and (B) a cross-linking agent; said composition being diluted with water to a solids content of between about 10 weight percent and about 40 weight percent.
Claim 2
Dependent Claim 102 words
A coating composition comprising: (A) a water-dispersible graft copolymer of an acrylic monomer or monomers and a random copolymer of a styrene and between about 20 weight percent and 30 weight percent of the random copolymer of allyl alcohol, in which at least about 8 percent of the total weight of said graft copolymer is derived from acrylic acid, methacrylic acid, or both, said graft copolymer being neutralized with ammonia, ammonium hydroxide, or a tertiary amine; and (B) a cross-linking agent; said composition being diluted with water to a solids content of between about 10 weight percent and about 40 weight percent.
Claim 3
Dependent Claim 20 words
A composition according to claim 1 wherein the styrene in the random copolymer component of said graft copolymer is styrene.
Claim 4
Dependent Claim 18 words
A composition according to claim 2 wherein the acrylic monomer in said graft copolymer component is methacrylic acid.
Claim 5
Dependent Claim 25 words
A composition according to claim 2 wherein the acrylic monomers in said graft copolymer component are methacrylic acid, methyl methacrylate, butyl acrylate, and hydroxyethyl methacrylate.
Claim 6
Dependent Claim 21 words
A composition according to claim 2 wherein the acrylic monomers in said graft copolymer compound are methacrylic acid and butyl acrylate.
Claim 7
Dependent Claim 12 words
A substrate coated with the coating composition of claim 1 and baked.
Claim 8
Dependent Claim 12 words
A substrate coated with the coating composition of claim 2 and baked.
Claim 9
Dependent Claim 12 words
A substrate coated with the coating composition of claim 3 and baked.
Claim 10
Dependent Claim 12 words
A substrate coated with the coating composition of claim 4 and baked.
Claim 11
Dependent Claim 12 words
A substrate coated with the coating composition of claim 5 and baked.
Claim 12
Dependent Claim 18 words
A coated substrate of claim 6, 7, 8, 9, or 10, wherein said substrate is a metal substrate.

References Cited (Backward Citations)

US2461423A Cited
US4308185A Cited
US4212781A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-11-07 1987-05-09 1987-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-11-07 1991-05-09 1991-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-11-07 1995-05-09 1995-11-08 $7700.00 Window Closed / Lapsed

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