Patent US4414266A successfully refreshed from Google Patents.
US4414266A
Expired / Lapsed
US
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Method of manufacture of reinforced sheet plastics material and the production of moulded articles therefrom
Assignee: Ford Motor Co
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Filing: 1980-08-19
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Granted: 1983-11-08
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Expires: 2000-08-19
Abstract
Abstract Polyethylene terephthalate (PET) sheet material incorporating fibrous reinforcement, e.g. 20 to 60% glass fibre, is holding superimposing layers of reinforcement and molten PET in contact under pressure and then cooling the layers to below the glass transition temperature of PET at a rate sufficient to avoid crystallization of the PET. The resulting sheet material contains PET in its amorphous phase and can be moulded to form articles such as motor vehicle body panels by heating the sheet in a mould to a temperature above its glass transition temperature but below its melting point and holding the sheet at that temperature until the PET undergoes crystallization.
Inventors
- 👤 Emmit W. Archer
- 👤 Derek F. Gentle
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 06:42
CPC Classifications
B; B29; B29C; B29C70/00; B29C51/00; B29C51/14; B29C70/04; B29C70/28; B29C70/40; B29C70/42; B29C70/46; B29C70/50; B29C70/504; B29C70/506; B32; B32B; B32B27/00; B32B27/12; B32B27/36; B32B38/00; B32B38/0036; B32B38/004; B29K; B29K2309/00; B29K2309/08; B32B2250/00; B32B2250/40; B32B2262/00; B32B2262/10; B32B2262/101; B32B2305/00; B32B2305/08; B32B2307/00; B32B2307/70; B32B2307/704; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31616
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
55 words
A method of manufacturing a reinforced sheet material which comprises holding superimposed layers of fibrous reinforcing material and molten polyethylene terephthalate, in contact under pressure, and cooling the superimposed layers to below the glass transition point of the polyethylene terephthalate, the cooling being effected at a rate sufficient to avoid crystallization of the polyethylene terephthalate.
Claim 2
Independent Claim
55 words
A method of manufacturing a reinforced sheet material which comprises holding superimposed layers of fibrous reinforcing material and molten polyethylene terephthalate, in contact under pressure, and cooling the superimposed layers to below the glass transition point of the polyethylene terephthalate, the cooling being effected at a rate sufficient to avoid crystallization of the polyethylene terephthalate.
Claim 3
Dependent Claim
20 words
A method according to claim 1 wherein the layers are cooled to below 160° C. in less than 20 seconds.
Claim 4
Dependent Claim
53 words
A method according to claim 1 or claim 2 wherein the layers are superimposed, heated and cooled by feeding a sheet of polyethylene terephalate and a mat of reinforcing fibrous mat into one or more nips formed between two movable members which advance the layers through a heating zone and a cooling zone.
Claim 5
Dependent Claim
24 words
A method according to claim 3 wherein the nip is formed by two continuous movable belts which extend through the heating and cooling zones.
Claim 6
Independent Claim
23 words
A method according to claims 1 or 2 wherein a layer of fibrous reinforcing material is sandwiched between two layers of polyethlene terephalate.
Claim 7
Independent Claim
23 words
A method according to claims 1 or 2 wherein a plurality of layers of reinforcing material lying between two layers of polyethylene terephalate.
Claim 8
Independent Claim
23 words
A method according to claims 1 or 2 wherein the reinforcing material comprises glass fibre having a staple length greater than 1 cm.
Claim 9
Independent Claim
16 words
A method according to claims 1 or 2 wherein the reinforcing material comprises continuous glass fibre.
Claim 10
Independent Claim
17 words
A method according to claims 1 or 2 wherein sheet material contains 20 to 60% reinforcing material.
Claim 11
Dependent Claim
14 words
A method according to claim 3 wherein the reinforcing material comprises continuous glass fibre.
Claim 12
Dependent Claim
26 words
A method according to claim 10 wherein the molten polyethylene terephthalate is formed by two continuous movable belts which extend through the heating and cooling zones.
Claim 13
Dependent Claim
21 words
A method according to claim 11 wherein a layer of fibrous reinforcing material is sandwiched between two layers of polyethylene terephalate.
Claim 14
Dependent Claim
31 words
A method according to claim 12 wherein a plurality of layers of reinforcing material are incorporated in the sheet, each layer of reinforcing material lying between two layers of polyethylene terephalate.
Claim 15
Dependent Claim
21 words
A method according to claim 13 wherein the reinforcing material comprises glass fibre having a staple length greater than 1 cm.
Claim 16
Dependent Claim
13 words
A method according to claim 14 wherein the reinforcing material comprises glass fibre.
Claim 17
Dependent Claim
16 words
A method according to claim 15 wherein the sheet material contains 20 to 60% reinforcing material.
Claim 18
Dependent Claim
23 words
Reinforced sheet produced by a method according to claim 16, wherein said polyethylene terephthalate comprises no more than 10% crystalline phase polyethylene terephthalate.
Claim 19
Dependent Claim
23 words
Reinforced sheet produced by a method according to claim 1, wherein said polyethylene terephthalate comprises no more than 10% crystalline phase polyethylene terephthalate.
Claim 20
Independent Claim
78 words
A method of producing a moulded article which comprises manufacturing a reinforced sheet material by a method according to claims 1 or 2, and forming the sheet by heating the sheet in a mould to a temperature with the range of from about its glass transition temperature to below its melting point, and maintaining the sheet with the said temperature range for a period sufficient to allow crystallization of the polyethylene terephthalate, and cooling the crystallized polyethylene terephthalate.
Claim 21
Dependent Claim
30 words
A method according to claim 19 wherein the polyethylene terephthalate is maintained within a temperature range of from 150° to 170° C. for a period of 10 to 30 seconds.
Claim 22
Dependent Claim
22 words
Moulded articles produced by a method according to claim 19, wherein said polyethylene terephthalate has a weight-average molecular weight greater than 45,000.
Claim 23
Dependent Claim
22 words
Moulded articles produced by a method according to claim 20, wherein said polyethylene terephthalate has a weight-average molecular weight greater than 45,000.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-11-07 | 1987-05-09 | 1987-11-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-11-07 | 1991-05-09 | 1991-11-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-11-07 | 1995-05-09 | 1995-11-08 | $7700.00 | Window Closed / Lapsed |