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US4414090A Expired / Lapsed US ⏱️ 0.0 years remaining

Separator membranes for redox-type electrochemical cells

Assignee: Rai Research Corp
•
Filing: 1981-10-01
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Granted: 1983-11-08
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Expires: 2001-10-01
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Abstract

Abstract This disclosure is directed to improved redox type electrochemical cells, preferably those of the iron (+3)/iron (+2) electrolyte variety, incorporating polymeric, ion-exchange separator membranes produced by radiation grafting techniques.

Inventors

  • 👤 Vincent F. D'Agostino
  • 👤 Joseph Y. Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 09:59
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/20; C08J5/22; C08J5/2206; C08J5/2218; C08J5/2231; C08J5/2243; C08J2339/00; C08J2339/04; C08J2339/08; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 46 words
In an improved redox electrochemical cell incorporating two chemically-inert electrodes of opposite polarity, at least one aqueous acidic electrolyte, and a separator membrane between the adjacent electrodes, the improvement comprising a separator membrane formed from a polyolefin film grafted with a vinyl-substituted monomer via gamma irradiation.
Claim 2
Dependent Claim 46 words
In an improved redox electrochemical cell incorporating two chemically-inert electrodes of opposite polarity, at least one aqueous acidic electrolyte, and a separator membrane between the adjacent electrodes, the improvement comprising a separator membrane formed from a polyolefin film grafted with a vinyl-substituted monomer via gamma irradiation.
Claim 3
Dependent Claim 32 words
The redox cell of claim 1 in which the polyolefin film is selected from the group comprising polypropylene, high density polyethylene, low density polyethylene, a perfluorinated polyolefin or a partially fluorinated polyolefin.
Claim 4
Dependent Claim 12 words
The redox cell of claim 1 which the vinyl-substituted monomer is 4-vinylpyridine.
Claim 5
Dependent Claim 13 words
The redox cell of claim 1 in which the vinyl-substituted monomer is 2-vinylpyridine.
Claim 6
Dependent Claim 14 words
The redox cell of claim 1 in which the vinyl-substituted monomer is 2-vinylbenzyl chloride.
Claim 7
Dependent Claim 14 words
The redox cell of claim 1 in which the vinyl-substituted monomer is 4-vinylbenzyl chloride.
Claim 8
Dependent Claim 14 words
The redox cell of claim 1 in which the vinyl-substituted monomer is methacrylic acid.
Claim 9
Dependent Claim 13 words
The redox cell of claim 1 which the vinyl-substituted monomer is acrylic acid.
Claim 10
Dependent Claim 24 words
The redox cell of claim 1 in which the separator membrane is formed by grafting polypropylene with 4-vinylpyridine to 10-100% of the membrane weight.
Claim 11
Dependent Claim 26 words
The redox cell of claim 1 in which the separator membrane is formed by grafting high density polyethylene with 4-vinylpyridine to 29-146% of the membrane weight.
Claim 12
Dependent Claim 26 words
The redox cell of claim 1 in which the separator membrane is formed by grafting low density polyethylene to 4-vinylpyridine to 28-114% of the membrane weight.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-11-07 1987-05-09 1987-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-11-07 1991-05-09 1991-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-11-07 1995-05-09 1995-11-08 $7700.00 Window Closed / Lapsed

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