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Method of stabilizing a polymer from degradation by UV radiation

Assignee: Wyeth Holdings LLC
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Filing: 1983-02-16
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Granted: 1983-11-01
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Expires: 2003-02-16
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Abstract

Abstract A method of stabilizing a polymer which is normally subject to degradation by UV radiation by incorporating therein an ultraviolet stabilizingly effective amount of a polymer based upon a monomer of the formula ##STR1## wherein R or R 1 contain a polymerizable double bond.

Inventors

  • 👤 Frank F. Loffelman
  • 👤 Thomas E. Brady

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:41
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 293 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of a polymer prepared by polymerizing, optionally with a comonomer, a compound of the formula (I) ##STR14## wherein R represents C 3 -C.sub.| alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, the groups ##STR15## C 1 -C 18 alkylamino, di(C 1 -C 18 )alkylamino, morpholino, pyrrolidyl, piperidino, a substituted C 1 -C 18 alkylamino, or a substituted di(C 1 -C 18 )alkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the group ##STR16## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxylalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or the group ##STR17## Y and Y', which may be the same, or different, represent oxy, or ##STR18## X represents C 2 -C 12 alkylene, wherein the alkylene chain may be interrupted by an oxo, thio or ##STR19## radical, C 5 -C 10 cycloalkylene, ##STR20## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; with the proviso that at least one substituent in said compound is, or contains, ##STR21##
Claim 2
Independent Claim 293 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of a polymer prepared by polymerizing, optionally with a comonomer, a compound of the formula (I) ##STR14## wherein R represents C 3 -C.sub.| alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, the groups ##STR15## C 1 -C 18 alkylamino, di(C 1 -C 18 )alkylamino, morpholino, pyrrolidyl, piperidino, a substituted C 1 -C 18 alkylamino, or a substituted di(C 1 -C 18 )alkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the group ##STR16## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxylalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or the group ##STR17## Y and Y', which may be the same, or different, represent oxy, or ##STR18## X represents C 2 -C 12 alkylene, wherein the alkylene chain may be interrupted by an oxo, thio or ##STR19## radical, C 5 -C 10 cycloalkylene, ##STR20## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; with the proviso that at least one substituent in said compound is, or contains, ##STR21##
Claim 3
Dependent Claim 30 words
The method of claim 1 wherein the stabilizing polymer is incorporated in a concentration of from about 0.2% to 2% based on the weight of the polymer to be stabilized.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein the polymer to be stabilized is a polyolefin.
Claim 5
Dependent Claim 10 words
The method of claim 3 wherein the polyolefin is polypropylene.
Claim 6
Dependent Claim 20 words
The method of claim 1 wherein the stabilizing polymer is a polymer of a monomer of the formula (II) ##STR22##
Claim 7
Dependent Claim 9 words
The composition produced by the method of claim 1.

References Cited (Backward Citations)

US2712004A Cited
US2712537A Cited
US4086204A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-31 1987-05-02 1987-11-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-31 1991-05-02 1991-11-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-31 1995-05-02 1995-11-01 $7700.00 Window Closed / Lapsed

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