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US4413093A
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Method of stabilizing a polymer from degradation by UV radiation
Assignee: Wyeth Holdings LLC
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Filing: 1983-02-16
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Granted: 1983-11-01
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Expires: 2003-02-16
Abstract
Abstract A method of stabilizing a polymer which is normally subject to degradation by UV radiation by incorporating therein an ultraviolet stabilizingly effective amount of a polymer based upon a monomer of the formula ##STR1## wherein R or R 1 contain a polymerizable double bond.
Inventors
- 👤 Frank F. Loffelman
- 👤 Thomas E. Brady
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 20:41
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
293 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of a polymer prepared by polymerizing, optionally with a comonomer, a compound of the formula (I) ##STR14## wherein R represents C 3 -C.sub.| alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, the groups ##STR15## C 1 -C 18 alkylamino, di(C 1 -C 18 )alkylamino, morpholino, pyrrolidyl, piperidino, a substituted C 1 -C 18 alkylamino, or a substituted di(C 1 -C 18 )alkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the group ##STR16## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxylalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or the group ##STR17## Y and Y', which may be the same, or different, represent oxy, or ##STR18## X represents C 2 -C 12 alkylene, wherein the alkylene chain may be interrupted by an oxo, thio or ##STR19## radical, C 5 -C 10 cycloalkylene, ##STR20## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; with the proviso that at least one substituent in said compound is, or contains, ##STR21##
Claim 2
Independent Claim
293 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of a polymer prepared by polymerizing, optionally with a comonomer, a compound of the formula (I) ##STR14## wherein R represents C 3 -C.sub.| alkenyloxy, C 3 -C 6 alkenylamino, or di(C 3 -C 6 alkenyl)amino; R 1 represents C 1 -C 8 alkyl, C 1 -C 8 alkoxy, halo, C 1 -C 8 alkylthio, C 3 -C 6 alkenyloxy, amino, C 3 -C 6 alkenylamino, di(C 3 -C 6 alkenyl)amino, the groups ##STR15## C 1 -C 18 alkylamino, di(C 1 -C 18 )alkylamino, morpholino, pyrrolidyl, piperidino, a substituted C 1 -C 18 alkylamino, or a substituted di(C 1 -C 18 )alkylamino, wherein the substituents are selected from amino, cyano, carboxy, alkoxycarbonyl wherein the alkoxy moiety has 1 to 8 carbon atoms, and the group ##STR16## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; and R 5 represents hydrogen, C 2 -C 3 hydroxylalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 8 alkyl, or the group ##STR17## Y and Y', which may be the same, or different, represent oxy, or ##STR18## X represents C 2 -C 12 alkylene, wherein the alkylene chain may be interrupted by an oxo, thio or ##STR19## radical, C 5 -C 10 cycloalkylene, ##STR20## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; with the proviso that at least one substituent in said compound is, or contains, ##STR21##
Claim 3
Dependent Claim
30 words
The method of claim 1 wherein the stabilizing polymer is incorporated in a concentration of from about 0.2% to 2% based on the weight of the polymer to be stabilized.
Claim 4
Dependent Claim
14 words
The method of claim 1 wherein the polymer to be stabilized is a polyolefin.
Claim 5
Dependent Claim
10 words
The method of claim 3 wherein the polyolefin is polypropylene.
Claim 6
Dependent Claim
20 words
The method of claim 1 wherein the stabilizing polymer is a polymer of a monomer of the formula (II) ##STR22##
Claim 7
Dependent Claim
9 words
The composition produced by the method of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-31 | 1987-05-02 | 1987-11-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-31 | 1991-05-02 | 1991-11-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-31 | 1995-05-02 | 1995-11-01 | $7700.00 | Window Closed / Lapsed |