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US4412846A
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Fuels containing N-substituted amino morpholines
Assignee: Lubrizol Corp
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Filing: 1981-05-07
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Granted: 1983-11-01
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Expires: 2001-05-07
Abstract
Abstract Normally liquid fuel compositions containing N-substituted morpholines of the formula ##STR1## wherein R' is a divalent organic radical of at least one to about 30 carbon atoms, R 3 is a hydrogen atom or a hydrocarbyl, a hydroxy-substituted hydrocarbyl or a hydroxy hydrocarbyleneoxy-substituted hydrocarbyl radical of at least one carbon atom and R" is a monovalent hydrocarbon radical of at least thirty carbon atoms, exhibit improved carburetor detergency and anti-icing properties. These fuels also inhibit deposit formation in the intake systems of internal combustion engines. Particularly preferred are gasolines containing morpholines wherein R' is 1,3-propylene, or poly(ethyleneoxy), R" is a hydrocarbyl group of at least about forty carbon atoms and R 3 is hydrogen.
Inventors
- 👤 Franklin P. Abbott
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 13:54
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/20; H01G4/22; H01G4/221; C; C08; C08F; C08F8/00; C08F8/30; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/232; C10L1/233; C10L1/2335; C10L1/234; C10L1/238; C10L1/24; C10L1/2443; C10M; C10M133/00; C10M133/52; C10M133/58; C10M135/00; C10M135/32; H01B; H01B19/00; H01B19/02; H01B3/00; H01B3/18; H01B3/20; C10M2203/00; C10M2203/02; C10M2203/022; C10M2203/024; C10M2203/04; C10M2203/06; C10M2205/00; C10M2205/02; C10M2205/024; C10M2205/026; C10M2207/00; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/287; C10M2207/288; C10M2207/289; C10M2207/30; C10M2207/302; C10M2207/34; C10M2207/40; C10M2207/402; C10M2207/404; C10M2209/00; C10M2209/02; C10M2209/10; C10M2209/102; C10M2209/103; C10M2209/104; C10M2209/105; C10M2209/106; C10M2209/108; C10M2209/109; C10M2209/11; C10M2209/111; C10M2209/12; C10M2211/00; C10M2211/04; C10M2211/044; C10M2211/06; C10M2213/00; C10M2213/02; C10M2213/06; C10M2213/062; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/06; C10M2215/062; C10M2215/08; C10M2215/082; C10M2215/086; C10M2215/10; C10M2215/102; C10M2215/12; C10M2215/14; C10M2215/20; C10M2215/202; C10M2215/22; C10M2215/221; C10M2215/223; C10M2215/224; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/28; C10M2215/30; C10M2217/00; C10M2217/04; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/044; C10M2219/06; C10M2219/062; C10M2219/064; C10M2219/09; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/06; C10M2223/061; C10M2223/065; C10M2227/00; C10M2227/02; C10M2227/06; C10M2227/061; C10M2227/063; C10M2229/00; C10M2229/02; C10M2229/04; C10M2229/041; C10M2229/042; C10M2229/043; C10M2229/044; C10M2229/045; C10M2229/046; C10M2229/047; C10M2229/048; C10M2229/05; C10M2229/051; C10N; C10N2010/00; C10N2010/02; C10N2010/04; C10N2010/06; C10N2010/08; C10N2010/12; C10N2010/14; C10N2020/00; C10N2020/01; C10N2040/00; C10N2040/04; C10N2040/042; C10N2040/044; C10N2040/046; C10N2040/06; C10N2040/20; C10N2040/25; C10N2040/252; C10N2040/253; C10N2040/255; C10N2040/26; C10N2070/00; C10N2070/02
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
79 words
A fuel composition containing a major amount of a normally liquid fuel and a minor but detergent-producing amount of at least one N-substituted morpholine of the formula ##STR10## wherein R' is a divalent organic radical of at least one to about thirty carbon atoms, R 3 is a hydrogen atom or a monovalent hydrocarbyl, hydroxy-substituted hydrocarbyl or hydroxy hydrocarbyleneoxy-substituted hydrocarbyl radical of at least one carbon and R" is a hydrocarbyl radical of at least about thirty carbon atoms.
Claim 2
Dependent Claim
79 words
A fuel composition containing a major amount of a normally liquid fuel and a minor but detergent-producing amount of at least one N-substituted morpholine of the formula ##STR10## wherein R' is a divalent organic radical of at least one to about thirty carbon atoms, R 3 is a hydrogen atom or a monovalent hydrocarbyl, hydroxy-substituted hydrocarbyl or hydroxy hydrocarbyleneoxy-substituted hydrocarbyl radical of at least one carbon and R" is a hydrocarbyl radical of at least about thirty carbon atoms.
Claim 3
Dependent Claim
23 words
A fuel composition as claimed in claim 1 wherein R' contains about one to about six carbon atoms and R 3 is hydrogen.
Claim 4
Dependent Claim
28 words
A fuel composition as claimed in claim 1 wherein R' is a C 1 -C 3 aliphatic radical and R" is of at least about forty carbon atoms.
Claim 5
Dependent Claim
51 words
A fuel composition as claimed in claim 1 wherein R' is interrupted with one to about six Y groups, Y is an oxygen or sulfur atom or a sulfinyl, sulfonyl, or amino group, said amino group being of the formula >NR.sup.3, and R" is of at least about forty carbon atoms.
Claim 6
Dependent Claim
34 words
A fuel composition as claimed in claim 4 wherein the N-substituted morpholine is of the formula ##STR11## wherein each Y is an --0-- atom and R" is of at least about forty carbon atoms.
Claim 7
Dependent Claim
13 words
A fuel composition as claimed in claim 1 wherein R 3 is R".
Claim 8
Dependent Claim
17 words
A fuel composition as claimed in claim 1 wherein R" contains at least about forty carbon atoms.
Claim 9
Dependent Claim
43 words
A fuel composition as claimed in claim 1 wherein R" is derived from at least one member of the group of C 2 - 8 monoolefin polymers and halogenated C 2 - 8 monoolefin polymers and contains at least about forty carbon atoms.
Claim 10
Dependent Claim
16 words
A fuel composition as claimed in claim 8 wherein the monoolefin is a C 4 monoolefin.
Claim 11
Dependent Claim
25 words
A fuel composition as claimed in claim 1 wherein R 3 is a hydrogen atom and R" is of at least about forty carbon atoms.
Claim 12
Dependent Claim
18 words
A fuel composition as claimed in claim 10 wherein R' is --CH 2 CH 2 CH 2 --.
Claim 13
Dependent Claim
24 words
A fuel composition as claimed in claim 1 wherein the fuel is motor gasoline and R" is of at least about forty carbon atoms.
Claim 14
Dependent Claim
17 words
A fuel composition as cclaimed in claim 12 also containing a minor amount of an ashless dispersant.
Claim 15
Dependent Claim
19 words
A fuel composition as claimed in claim 1 wherein R 3 is R" and the fuel is motor gasoline.
Claim 16
Dependent Claim
25 words
A fuel composition as claimed in claim 1 wherein R 3 is a C 1 to C 19 hydrocarbyl group, the fuel is motor gasoline.
Claim 17
Dependent Claim
38 words
A fuel composition containing a major amount of motor gasoline and a minor carburetor detergency producing amount of N-substituted morpholine as claimed in claim 10 wherein the morpholine is prepared by reacting a chlorinated polyisobutylene with N-3-aminopropyl morpholine.
Claim 18
Dependent Claim
17 words
A composition as claimed in claim 16 wherein the N-substituted morpholine contains less than about 1.0% chlorine.
Claim 19
Dependent Claim
113 words
A fuel composition containing a major amount of a normally liquid fuel and a minor but detergent-producing amount of at least one N-substituted morpholine of the formula ##STR12## wherein R' is a divalent organic radical of at least one to about thirty carbon atoms and is interrupted with one to about six Y groups, Y is an oxygen or sulfur atom or a sulfinyl, sulfonyl or amino group, said amino group being of the formula >NR 3 , R 3 is a hydrogen atom or a monovalent hydrocarbyl, hydroxy-substituted hydrocarbyl or hydroxy hydrocarbyleneoxy-substituted hydrocarbyl radical of at least one carbon and R" is a hydrocarbyl radical of at least about thirty carbon atoms.
Claim 20
Dependent Claim
113 words
A fuel composition containing a major amount of a normally liquid fuel and a minor but detergent-producing amount of at least one N-substituted morpholine of the formula ##STR12## wherein R' is a divalent organic radical of at least one to about thirty carbon atoms and is interrupted with one to about six Y groups, Y is an oxygen or sulfur atom or a sulfinyl, sulfonyl or amino group, said amino group being of the formula >NR 3 , R 3 is a hydrogen atom or a monovalent hydrocarbyl, hydroxy-substituted hydrocarbyl or hydroxy hydrocarbyleneoxy-substituted hydrocarbyl radical of at least one carbon and R" is a hydrocarbyl radical of at least about thirty carbon atoms.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-31 | 1987-05-02 | 1987-11-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-31 | 1991-05-02 | 1991-11-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-31 | 1995-05-02 | 1995-11-01 | $7700.00 | Window Closed / Lapsed |