US4412016A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Propylene polymer composition
Assignee: Toyota Motor Corp
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Filing: 1982-03-19
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Granted: 1983-10-25
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Expires: 2002-03-19
Abstract
Abstract A shaped article having excellent rigidity, resistances to thermal deformation and to mechanical impact at a low temperature, a superior lacquer-bonding property and a satisfactory appearance is made from a propylene polymer composition comprising (A) 45 to 65% by weight of at least one crystalline ethylene-propylene block copolymer in which the content of the polymerized ethylene is in the range of from 5 to 10% by weight, in which the polypropylene component has a fraction thereof insoluble in boiling n-heptane, in an amount of 95% or more, in which a fraction thereof soluble in p-xylene at room temperature, has an intrinsic viscosity of from 3 to 4 determined in decahydronaphthalene at a temperature of 135 DEG C. and which has a melt flow index of from 5 to 70; (B) 25 to 40% by weight of at least one amorphous ethylene-propylene copolymer having an intrinsic viscosity of from 2.0 to 3.5 determined in decahydronaphthalene at a temperature of 135 DEG C., and a Mooney viscosity ML1+4 of from 40 to 100 determined at a temperature of 100 DEG C.; (C) 4 to 20% by weight of at least one high density polyethylene having a melt flow index of from 1 to 10; and (D) 3 to 20% by weight of talc in the form of fine particles having an average size of from 0.01 to 5 microns, the weight ratio of the amorphous ethylene-propylene copolymer (B) to the high density polyethylene (C) being in the range of from 10:1 to 5:3.
Inventors
- 👤 Osamu Fukui
- 👤 Yoshiro Umemoto
- 👤 Tsugumi Sanmiya
- 👤 Yutaka Sano
- 👤 Kazuyoshi Tanaka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 23:17
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08L; C08L53/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
232 words
A propylene polymer composition comprising (A) 45 to 65% by weight of at least one crystalline ethylene-propylene block copolymer in which the content of the polymerized ethylene is in the range of from 5 to 10% by weight, in which the polypropylene component has a fraction thereof insoluble in boiling n-heptane, in an amount of 95% or more based on the weight of said polypropylene component, in which a fraction thereof soluble in p-xylene at room temperature, has an intrinsic viscosity of from 3 to 4 determined in decahydronaphthalene at a temperature of 135° C. and which has a melt flow index of from 5 to 70; (B) 25 to 40% by weight of at least one amorphous ethylene-propylene copolymer having an intrinsic viscosity of from 2.0 to 3.5 determined in decahydronaphthalene at a temperature of 135° C., and a Mooney viscosity ML 1+4 of from 40 to 100 determined at a temperature of 100° C.; (C) 4 to 20% by weight of at least one high density polyethylene having a melt flow index of from 1 to 10; and (D) 3 to 20% by weight of talc in the form of fine particles having an average size of from 0.01 to 5 microns, in which composition, the ratio in weight of said amorphous ethylene-propylene copolymer (B) to said high density polyethylene (C) is in the range of from 10:1 to 5:3.
Claim 2
Dependent Claim
232 words
A propylene polymer composition comprising (A) 45 to 65% by weight of at least one crystalline ethylene-propylene block copolymer in which the content of the polymerized ethylene is in the range of from 5 to 10% by weight, in which the polypropylene component has a fraction thereof insoluble in boiling n-heptane, in an amount of 95% or more based on the weight of said polypropylene component, in which a fraction thereof soluble in p-xylene at room temperature, has an intrinsic viscosity of from 3 to 4 determined in decahydronaphthalene at a temperature of 135° C. and which has a melt flow index of from 5 to 70; (B) 25 to 40% by weight of at least one amorphous ethylene-propylene copolymer having an intrinsic viscosity of from 2.0 to 3.5 determined in decahydronaphthalene at a temperature of 135° C., and a Mooney viscosity ML 1+4 of from 40 to 100 determined at a temperature of 100° C.; (C) 4 to 20% by weight of at least one high density polyethylene having a melt flow index of from 1 to 10; and (D) 3 to 20% by weight of talc in the form of fine particles having an average size of from 0.01 to 5 microns, in which composition, the ratio in weight of said amorphous ethylene-propylene copolymer (B) to said high density polyethylene (C) is in the range of from 10:1 to 5:3.
Claim 3
Dependent Claim
23 words
The propylene polymer composition as claimed in claim 1, wherein said high density polyethylene has a density of 0.95 g/cm 3 or more.
Claim 4
Dependent Claim
22 words
The propylene polymer composition as claimed in claim 1, wherein said talc has an average size of from 0.5 to 3 microns.
Claim 5
Dependent Claim
39 words
The propylene polymer composition as claimed in claim 1, wherein the talc particles are coated with at least one member selected from organic titanate coupling agents, silane coupling agents, fatty acids, fatty acid metal salts and fatty acid esters.
Claim 6
Dependent Claim
38 words
The propylene polymer composition as claimed in claim 1, further comprising at least one additive consisting of at least one member selected from anti-oxidants, ultraviolet ray absorbing agents, flame retardants, pigments, lacquer-bonding enhancers, plasticizers, lubricants and anti-static agents.
Claim 7
Dependent Claim
44 words
The propylene polymer composition as claimed in claim 5 wherein said anti-oxidant comprises at least one member selected from the group consisting of 2,6-di-tert-butylphenol, 2,6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-4-n-butylphenol, 2,6-di-tert-butyl-α-dimethylamino-p-cresol, 6-(4-hydroxy-3,5-di-tert-butylanilino)-2,4-bis-octyl-thio-1,3,5-triazine, n-octadecyl-3-(4'-hydroxy-3,'5',-di-tert-butylphenyl) propionate, 2,6-di-tert-butyl-4-methylphenol (BHT), tris-(2-methyl-4-hydroxy-5-tert-butylphenyl) butane, tetrakis-[methylene 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl) propionate] methane, 1,3,5 -trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene, and dilaurylthiodipropionate.
Claim 8
Dependent Claim
38 words
The propylene polymer composition as claimed in claim 5 wherein said ultraviolet ray absorbing agent comprises at least one member selected from the group consisting of 2-hydroxy-4-n-octoxybenzophenone, 2-hydroxy-4-octadecyloxy-benzophenone, 4-dodecyloxy-2-hydroxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone, 2-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3'5'-di-tert-butylphenyl)-5-chloro-benzotriazole, nickel-bis-(orthoethyl-3,5-di-tert-butyl-4-hydroxybenzyl) phosphonate and bis (2,6-dimethyl-4-piperidyl) sebacate.
Claim 9
Dependent Claim
35 words
The propylene polymer composition as claimed in claim 5, wherein said flame retardant comprises at least one member selected from the group consisting of antimony trioxide, tricresyl phosphate, halogenated alkyltriazines, decarbromodiphenyl ether and chlorinated polyethylenes.
Claim 10
Dependent Claim
24 words
The propylene polymer composition as claimed in claim 5, wherein said pigment is selected from the group consisting of carbon black and titanium dioxide.
Claim 11
Dependent Claim
16 words
The propylene polymer composition as claimed in claim 5, wherein said lacquer-bonding enhancer comprises magnesium benzoate.
Claim 12
Dependent Claim
16 words
The propylene polymer composition as claimed in claim 5, wherein said plasticizer comprises a process oil.
Claim 13
Dependent Claim
18 words
The propylene polymer composition as claimed in claim 5, wherein said lubricant comprises a fatty acid metal salt.
Claim 14
Dependent Claim
17 words
The propylene polymer composition as claimed in claim 5, wherein said antistatic agent comprises a polyoxyethylene alkylether.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-24 | 1987-04-25 | 1987-10-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-24 | 1991-04-25 | 1991-10-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-24 | 1995-04-25 | 1995-10-25 | $7700.00 | Window Closed / Lapsed |