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US4411869A Expired / Lapsed US ⏱️ 0.0 years remaining

Multiple stage reactor system

Assignee: Honeywell UOP LLC
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Filing: 1983-02-28
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Granted: 1983-10-25
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Expires: 2003-02-28
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Abstract

Abstract The reactor system of this invention comprises two or more vertically spaced or stacked reaction chambers each of which contains two or more vertically positioned annular-form catalyst-retaining sections existing side-by-side, each of said catalyst-retaining sections being defined by an inner tubular-form catalyst-retaining screen coaxially disposed within a vertically positioned outer tubular-form catalyst-retaining screen. Catalyst particles are movable through the resulting annular-form catalyst sections in a dense phase via gravity flow. A reactant stream is processed serially through said reaction chambers, and contacted with catalyst within said annular-form catalyst-retaining sections in a manner to promote uniform flow of reactants across said sections. The disclosed reactor system is of particular advantage with respect to a relatively low pressure hydrocarbon conversion process.

Inventors

  • 👤 Joseph A. Kroushl
  • 👤 Arthur R. Greenwood

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 19:54
CPC Classifications
C; C07; C07C; C07C5/00; C07C5/32; C07C5/321; B; B01; B01J; B01J8/00; B01J8/08; B01J8/12; B01J8/125

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 369 words
A multiple stage reactor system which comprises, in combination: (a) a vertically elongated confined reactor vessel; (b) at least two vertically spaced reaction chambers within said vessel, each having upper and lower extremities; (c) a first port and a second port associated with each chamber, both located in one of said extremities; (d) each of said chambers containing a plurality of side-by-side annular-form vertically aligned catalyst-retaining sections positioned therein; (e) each of said catalyst-retaining sections being defined by an inner tubular-form catalyst-retaining screen coaxially disposed within an outer vertically positioned tubular-form catalyst-retaining screen, said inner catalyst-retaining screen further defining a fluid flow conduit within the inner space thereof; (f) each of said chambers containing a first flow manifold connecting said first port to one extremity of each of said fluid flow conduits; (g) each of said catalyst-retaining sections being further defined by two transverse partitions, one connected to the upper extremity of said fluid flow conduit and to the upper perimeter of said outer catalyst-retaining screen, and the other connected to the lower extremity of said fluid flow conduit and to the lower perimeter of said outer catalyst-retaining screen; (h) each of said chambers having a void space in open communication with said second port, and defined by the inner walls of said chamber and the outer surfaces of the plurality of catalyst-retaining sections contained therein, said void space serving as a second flow manifold connecting the outer surface of said plurality of catalyst-retaining sections to said second port; (i) catalyst inlet conduits extending through the upper extremity of the uppermost chamber and connected in open communication with the upper extremity of each of the catalyst-retaining sections contained therein; (j) inter-chamber catalyst conduits connecting the lower extremity of each catalyst-retaining section in each reaction chamber, except the catalyst-retaining sections in the lowermost chamber, in open communication with the upper extremity of a catalyst-retaining section in the next lower chamber; and, (k) catalyst withdrawal conduits connected in open communication with the lower extremity of each of the catalyst-retaining sections contained in the lowermost chamber and extending through the lower extremity thereof, whereby catalyst particles are gravitated through said vertically spaced reaction chambers via the plurality of catalyst-retaining sections contained therein.
Claim 2
Dependent Claim 369 words
A multiple stage reactor system which comprises, in combination: (a) a vertically elongated confined reactor vessel; (b) at least two vertically spaced reaction chambers within said vessel, each having upper and lower extremities; (c) a first port and a second port associated with each chamber, both located in one of said extremities; (d) each of said chambers containing a plurality of side-by-side annular-form vertically aligned catalyst-retaining sections positioned therein; (e) each of said catalyst-retaining sections being defined by an inner tubular-form catalyst-retaining screen coaxially disposed within an outer vertically positioned tubular-form catalyst-retaining screen, said inner catalyst-retaining screen further defining a fluid flow conduit within the inner space thereof; (f) each of said chambers containing a first flow manifold connecting said first port to one extremity of each of said fluid flow conduits; (g) each of said catalyst-retaining sections being further defined by two transverse partitions, one connected to the upper extremity of said fluid flow conduit and to the upper perimeter of said outer catalyst-retaining screen, and the other connected to the lower extremity of said fluid flow conduit and to the lower perimeter of said outer catalyst-retaining screen; (h) each of said chambers having a void space in open communication with said second port, and defined by the inner walls of said chamber and the outer surfaces of the plurality of catalyst-retaining sections contained therein, said void space serving as a second flow manifold connecting the outer surface of said plurality of catalyst-retaining sections to said second port; (i) catalyst inlet conduits extending through the upper extremity of the uppermost chamber and connected in open communication with the upper extremity of each of the catalyst-retaining sections contained therein; (j) inter-chamber catalyst conduits connecting the lower extremity of each catalyst-retaining section in each reaction chamber, except the catalyst-retaining sections in the lowermost chamber, in open communication with the upper extremity of a catalyst-retaining section in the next lower chamber; and, (k) catalyst withdrawal conduits connected in open communication with the lower extremity of each of the catalyst-retaining sections contained in the lowermost chamber and extending through the lower extremity thereof, whereby catalyst particles are gravitated through said vertically spaced reaction chambers via the plurality of catalyst-retaining sections contained therein.
Claim 3
Dependent Claim 27 words
The reactor system of claim 1 further characterized in that each of said reaction chambers contains from four to seven of said side-by-side annular form catalyst-retaining sections.
Claim 4
Dependent Claim 25 words
The reactor system of caim 2 further characterized in that each of said reaction chambers contains six of said side-by-side catalyst-retaining sections circumferentially spaced therein.
Claim 5
Dependent Claim 25 words
The reactor system of caim 2 further characterized in that each of said reaction chambers contains six of said side-by-side catalyst-retaining sections circumferentially spaced therein.
Claim 6
Dependent Claim 38 words
The reactor system of claim 1 further characterized in that said first flow manifold in each chamber connects the first port of the chamber with a lower extremity of each of said fluid flow conduits within the chamber.
Claim 7
Dependent Claim 25 words
The reactor system of claim 4 further characterized in that said first and second ports of each chamber are located at the lower extremity thereof.
Claim 8
Dependent Claim 38 words
The reactor system of claim 1 further characterized in that said first flow manifold in each chamber connects the first part of the chamber with an upper extremity of each of said fluid flow conduits within the chamber.
Claim 9
Dependent Claim 25 words
The reactor system of claim 5 further characterized in that said first and second ports of each chamber are located at the upper extremity thereof.
Claim 10
Dependent Claim 34 words
The reactor system of claim 1 further characterized in that said first port of each chamber is a reactant inlet port and said second port of each chamber is a reaction effluent outlet port.
Claim 11
Dependent Claim 34 words
The reactor system of claim 1 further characterized in that said first port of each chamber is a reaction effluent outlet port and said second port of each chamber is a reactant inlet port.
Claim 12
Dependent Claim 391 words
A process for the conversion of a hydrocarbon charge stock characterized in that the hydrocarbon charge stock is passed in vapor phase to a multiple stage reactor system comprising, in combination: (a) a vertically elongated confined reactor vessel; (b) at least two vertically spaced reaction chambers within said vessel, each having upper and lower extremities; (c) a first port and a second port associated with each chamber, both located in one of said extremities; (d) each of said chambers containing a plurality of side-by-side annular-form vertically aligned catalyst-retaining sections positioned therein; (e) each of said catalyst-retaining sections being defined by an inner tubular-form catalyst-retaining screen coaxially disposed within an outer vertically positioned tubular-form catalyst-retaining screen, said inner catalyst-retaining screen further defining a fluid flow conduit within the inner space thereof; (f) each of said chambers containing a first flow manifold connecting said first port to one extremity of each of said fluid flow conduits; (g) each of said catalyst-retaining sections being further defined by two transverse partitions, one connected to the upper extremity of said fluid flow conduit and to the upper perimeter of said outer catalyst-retaining screen, and the other connected to the lower extremity of said fluid flow conduit and to the lower perimeter of said outer catalyst-retaining screen; (h) each of said chambers having a void space in open communication with said second port, and defined by the inner walls of said chamber and the outer surface of the plurality of catalyst-retaining sections contained therein, said void space serving as a second flow manifold connecting the outer surface of said plurality of catalyst-retaining sections to said second port; (i) catalyst inlet conduits extending through the upper extremity of the uppermost chamber and connected in open communication with the upper extremity of each of the catalyst-retaining sections contained therein; (j) inter-chamber catalyst conduits connecting the lower extremity of each catalyst-retaining section in each reaction chamber, except the catalyst-retaining sections in the lowermost chamber, in open communication with the upper extremity of a catalyst-retaining section in the next lower chamber; and, (k) catalyst withdrawal conduits connected in open communication with the lower extremity of each of the catalyst-retaining sections contained in the lowermost chamber and extending through the lower extremity thereof, whereby catalyst particles are gravitated through said vertically spaced reaction chambers via the plurality of catalyst-retaining sections contained therein.
Claim 13
Dependent Claim 391 words
A process for the conversion of a hydrocarbon charge stock characterized in that the hydrocarbon charge stock is passed in vapor phase to a multiple stage reactor system comprising, in combination: (a) a vertically elongated confined reactor vessel; (b) at least two vertically spaced reaction chambers within said vessel, each having upper and lower extremities; (c) a first port and a second port associated with each chamber, both located in one of said extremities; (d) each of said chambers containing a plurality of side-by-side annular-form vertically aligned catalyst-retaining sections positioned therein; (e) each of said catalyst-retaining sections being defined by an inner tubular-form catalyst-retaining screen coaxially disposed within an outer vertically positioned tubular-form catalyst-retaining screen, said inner catalyst-retaining screen further defining a fluid flow conduit within the inner space thereof; (f) each of said chambers containing a first flow manifold connecting said first port to one extremity of each of said fluid flow conduits; (g) each of said catalyst-retaining sections being further defined by two transverse partitions, one connected to the upper extremity of said fluid flow conduit and to the upper perimeter of said outer catalyst-retaining screen, and the other connected to the lower extremity of said fluid flow conduit and to the lower perimeter of said outer catalyst-retaining screen; (h) each of said chambers having a void space in open communication with said second port, and defined by the inner walls of said chamber and the outer surface of the plurality of catalyst-retaining sections contained therein, said void space serving as a second flow manifold connecting the outer surface of said plurality of catalyst-retaining sections to said second port; (i) catalyst inlet conduits extending through the upper extremity of the uppermost chamber and connected in open communication with the upper extremity of each of the catalyst-retaining sections contained therein; (j) inter-chamber catalyst conduits connecting the lower extremity of each catalyst-retaining section in each reaction chamber, except the catalyst-retaining sections in the lowermost chamber, in open communication with the upper extremity of a catalyst-retaining section in the next lower chamber; and, (k) catalyst withdrawal conduits connected in open communication with the lower extremity of each of the catalyst-retaining sections contained in the lowermost chamber and extending through the lower extremity thereof, whereby catalyst particles are gravitated through said vertically spaced reaction chambers via the plurality of catalyst-retaining sections contained therein.
Claim 14
Dependent Claim 33 words
The process of claim 10 further characterized in that said hydrocarbon feedstock is subjected to catalytic dehydrogenation in the reactor system in the presence of a dehydrogenation catalyst emplaced within the catalyst-retaining sections.
Claim 15
Dependent Claim 20 words
The process of claim 11 further characterized in that said hydrocarbon charge stock comprises C 2 + normally gaseous hydrocarbons.
Claim 16
Dependent Claim 17 words
The process of claim 12 further characterized in that the hydrocarbon charge stock comprises propane or butane.
Claim 17
Dependent Claim 34 words
The process of claim 10 further characterized in that said first flow manifold in each chamber connects the first port with a lower extremity of each of said fluid flow conduits within the chamber.
Claim 18
Dependent Claim 27 words
The process of claim 10 further characterized in that each of said reaction chambers contains from four to seven of said side-by-side annular-form vertically aligned catalyst-retaining sections.
Claim 19
Dependent Claim 27 words
The process of claim 15 further characterized in that each of said reaction chambers contains six of said side-by-side annular-form vertically aligned catalyst-retaining sections circumferentially spaced therein.
Claim 20
Dependent Claim 24 words
The process of claim 10 further characterized in that said first and second ports are located at the lower extremity of said reaction chamber.
Claim 21
Dependent Claim 35 words
The process of claim 10 further characterized in that said first port of each chamber is a hydrocarbon charge stock inlet port and said second port of each chamber is a reaction effluent outlet port.
Claim 22
Dependent Claim 29 words
The process of claim 10 further characterized in that said second port is a hydrocarbon charge stock inlet port and said first port is a reaction effluent outlet port.
Claim 23
Dependent Claim 24 words
The process of claim 10 further characterized in that said first and second ports of each chamber are located at the upper extremity thereof.

References Cited (Backward Citations)

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US2683654A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-24 1987-04-25 1987-10-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-24 1991-04-25 1991-10-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-24 1995-04-25 1995-10-25 $7700.00 Window Closed / Lapsed

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