Patent US4409344A successfully refreshed from Google Patents.
US4409344A
Expired / Lapsed
US
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Low shrink unsaturated polyester resinous composition
Assignee: Cargill Inc
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Filing: 1981-06-23
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Granted: 1983-10-11
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Expires: 2001-06-23
Abstract
Abstract A low shrink unsaturated polyester based upon propylene glycol terephthalate reacted with a dibasic acid or anhydrides thereof and glycols and mixing the polyester with a filler, fibrous reinforcing agent and catalyst.
Inventors
- 👤 Thomas J. Moulson
- 👤 John E. Greenzweig
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 19:51
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/06; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/676; C08K; C08K3/00; C08K3/01; C08K3/013; C08K7/00; C08K7/02
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
177 words
A molding compound containing fibrous reinforcement comprising: (a) a low shrink polyester which is a product of a mixture of (i) from about 25 to about 35 parts by weight of a member selected from the group consisting of maleic acid, fumaric acid, their anhydrides and mixtures thereof; from about 5 to about 25 parts by weight of a member selected from the group consisting of isophthalic acid, phthalic acid, their anhydrides, and mixtures thereof; from about 10 to about 40 parts by weight propylene glycol; from about 10 to about 30 parts by weight dipropylene glycol; from about 5 to about 30 parts by weight propylene glycol terephthalate; (ii) heating said mixture of about 420° F. until a neat resin is formed with an acid number of from about 5 to about 50; and (iii) diluting the neat resin with from about 25 to about 100 parts by weight of a member selected from the group consisting of styrene, vinyl toluene and mixtures thereof; (b) mixing said resin with a filler, fibrous reinforcing agent and catalyst-initiator.
Claim 2
Dependent Claim
177 words
A molding compound containing fibrous reinforcement comprising: (a) a low shrink polyester which is a product of a mixture of (i) from about 25 to about 35 parts by weight of a member selected from the group consisting of maleic acid, fumaric acid, their anhydrides and mixtures thereof; from about 5 to about 25 parts by weight of a member selected from the group consisting of isophthalic acid, phthalic acid, their anhydrides, and mixtures thereof; from about 10 to about 40 parts by weight propylene glycol; from about 10 to about 30 parts by weight dipropylene glycol; from about 5 to about 30 parts by weight propylene glycol terephthalate; (ii) heating said mixture of about 420° F. until a neat resin is formed with an acid number of from about 5 to about 50; and (iii) diluting the neat resin with from about 25 to about 100 parts by weight of a member selected from the group consisting of styrene, vinyl toluene and mixtures thereof; (b) mixing said resin with a filler, fibrous reinforcing agent and catalyst-initiator.
Claim 3
Dependent Claim
27 words
A molding compound in accordance with claim 1 wherein said fibrous reinforcing agent comprises from about 10 to about 75 percent by weight of said molding compound.
Claim 4
Dependent Claim
27 words
A molding compound in accordance with claims 1 or 2 wherein said filler comprises from about 20 to about 70 percent by weight of said molding compound.
Claim 5
Dependent Claim
32 words
A molding compound in accordance with claims 1 or 2 wherein said filler is selected from the group consisting of limestone, alumina trihydrate, talc, silica, wollastonite, alumina, barytes, gypsum, and kaolin clay.
Claim 6
Dependent Claim
35 words
A molding compound in accordance with claim 1 or 2 wherein said fibrous reinforcing agent is selected from the group consisting of glass fibers, boron fibers, graphite fibers, poly (vinyl alcohol) fibers, and polyimide fibers.
Claim 7
Dependent Claim
25 words
A molding compound in accordance with claim 1 wherein said catalyst initiator is selected from the group consisting of peroxides, azo compounds and mixtures thereof.
Claim 8
Dependent Claim
28 words
A molding compound in accordance with claim 1 wherein said catalyst initiator is selected from the group consisting of teritiary butyl perbenzoate, benzoyl peroxide, and azo bis isobutyronitrile.
Claim 9
Dependent Claim
12 words
An article molded from a molding compound in accordance with claim 1.
Claim 10
Dependent Claim
18 words
A molding compound in accordance with claim 1 or 2 wherein said fibrous reinforcing agent is textile fibers.
Claim 11
Dependent Claim
15 words
A molding compound in accordance with claim 9 wherein said textile fibers are polyester fibers.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-10 | 1987-04-11 | 1987-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-10 | 1991-04-11 | 1991-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-10 | 1995-04-11 | 1995-10-11 | $7700.00 | Window Closed / Lapsed |