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US4409344A Expired / Lapsed US ⏱️ 0.0 years remaining

Low shrink unsaturated polyester resinous composition

Assignee: Cargill Inc
•
Filing: 1981-06-23
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Granted: 1983-10-11
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Expires: 2001-06-23
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Abstract

Abstract A low shrink unsaturated polyester based upon propylene glycol terephthalate reacted with a dibasic acid or anhydrides thereof and glycols and mixing the polyester with a filler, fibrous reinforcing agent and catalyst.

Inventors

  • 👤 Thomas J. Moulson
  • 👤 John E. Greenzweig

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 19:51
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/06; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/676; C08K; C08K3/00; C08K3/01; C08K3/013; C08K7/00; C08K7/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 177 words
A molding compound containing fibrous reinforcement comprising: (a) a low shrink polyester which is a product of a mixture of (i) from about 25 to about 35 parts by weight of a member selected from the group consisting of maleic acid, fumaric acid, their anhydrides and mixtures thereof; from about 5 to about 25 parts by weight of a member selected from the group consisting of isophthalic acid, phthalic acid, their anhydrides, and mixtures thereof; from about 10 to about 40 parts by weight propylene glycol; from about 10 to about 30 parts by weight dipropylene glycol; from about 5 to about 30 parts by weight propylene glycol terephthalate; (ii) heating said mixture of about 420° F. until a neat resin is formed with an acid number of from about 5 to about 50; and (iii) diluting the neat resin with from about 25 to about 100 parts by weight of a member selected from the group consisting of styrene, vinyl toluene and mixtures thereof; (b) mixing said resin with a filler, fibrous reinforcing agent and catalyst-initiator.
Claim 2
Dependent Claim 177 words
A molding compound containing fibrous reinforcement comprising: (a) a low shrink polyester which is a product of a mixture of (i) from about 25 to about 35 parts by weight of a member selected from the group consisting of maleic acid, fumaric acid, their anhydrides and mixtures thereof; from about 5 to about 25 parts by weight of a member selected from the group consisting of isophthalic acid, phthalic acid, their anhydrides, and mixtures thereof; from about 10 to about 40 parts by weight propylene glycol; from about 10 to about 30 parts by weight dipropylene glycol; from about 5 to about 30 parts by weight propylene glycol terephthalate; (ii) heating said mixture of about 420° F. until a neat resin is formed with an acid number of from about 5 to about 50; and (iii) diluting the neat resin with from about 25 to about 100 parts by weight of a member selected from the group consisting of styrene, vinyl toluene and mixtures thereof; (b) mixing said resin with a filler, fibrous reinforcing agent and catalyst-initiator.
Claim 3
Dependent Claim 27 words
A molding compound in accordance with claim 1 wherein said fibrous reinforcing agent comprises from about 10 to about 75 percent by weight of said molding compound.
Claim 4
Dependent Claim 27 words
A molding compound in accordance with claims 1 or 2 wherein said filler comprises from about 20 to about 70 percent by weight of said molding compound.
Claim 5
Dependent Claim 32 words
A molding compound in accordance with claims 1 or 2 wherein said filler is selected from the group consisting of limestone, alumina trihydrate, talc, silica, wollastonite, alumina, barytes, gypsum, and kaolin clay.
Claim 6
Dependent Claim 35 words
A molding compound in accordance with claim 1 or 2 wherein said fibrous reinforcing agent is selected from the group consisting of glass fibers, boron fibers, graphite fibers, poly (vinyl alcohol) fibers, and polyimide fibers.
Claim 7
Dependent Claim 25 words
A molding compound in accordance with claim 1 wherein said catalyst initiator is selected from the group consisting of peroxides, azo compounds and mixtures thereof.
Claim 8
Dependent Claim 28 words
A molding compound in accordance with claim 1 wherein said catalyst initiator is selected from the group consisting of teritiary butyl perbenzoate, benzoyl peroxide, and azo bis isobutyronitrile.
Claim 9
Dependent Claim 12 words
An article molded from a molding compound in accordance with claim 1.
Claim 10
Dependent Claim 18 words
A molding compound in accordance with claim 1 or 2 wherein said fibrous reinforcing agent is textile fibers.
Claim 11
Dependent Claim 15 words
A molding compound in accordance with claim 9 wherein said textile fibers are polyester fibers.

References Cited (Backward Citations)

US3701748A Cited
US3772241A Cited
US3657387A Cited
US3926902A Cited
US3909483A Cited
US3922247A Cited
US3989655A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-10 1987-04-11 1987-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-10 1991-04-11 1991-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-10 1995-04-11 1995-10-11 $7700.00 Window Closed / Lapsed

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