Patent US4409064A successfully refreshed from Google Patents.
US4409064A
Expired / Lapsed
US
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Process for concentrating sulfuric acid in an evaporator
Assignee: Air Products and Chemicals Inc
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Filing: 1981-11-09
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Granted: 1983-10-11
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Expires: 2001-11-09
Abstract
Abstract This invention relates to an improved process for reducing solute in a vapor stream and, particularly, to the adaption of this process in concentrating solutions in an evaporator wherein the solution is heated to volatilize solvent. The improvement for reducing solute in the vapor stream resides in (a) the utilization of a wire mesh mist eliminator pad having a wire diameter of from 0.001-0.05 inches, an interfacial area from 50-200 ft 2 /ft 3 , a void space of about 90-99 percent and a packing thickness of 4-16 inches and (b) spraying a liquid through the mist eliminator pad, the liquid being sprayed uniformly over the surface of the mist eliminator pad at a rate of 0.6-2.5 pounds liquid per pound of vapor to provide a wetting rate of 0.1-0.25 gallons per minute per square foot of mist eliminator surface area. The process has been particularly advantageous in the multistage concentration of corrosive products particularly in the concentration of a 60-70% sulfuric acid solution to about 93 percent.
Inventors
- 👤 Suresh M. Vora
- 👤 William J. Mazzafro
- 👤 Pierre L. T. Brian
- 👤 Michael S. K. Chen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 13:23
CPC Classifications
B; B01; B01D; B01D1/00; B01D1/16; C; C01; C01B; C01B17/00; C01B17/69; C01B17/88
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
199 words
A process for concentrating sulfuric acid which comprises: (a) introducing an aqueous feed sulfuric acid into an evaporator; (b) heating the feed sulfuric acid in said evaporator to a temperature sufficient to evaporate the water and form a vapor rich in water and leave a concentrated bottoms product rich in sulfuric acid; (c) passing the vapor rich in water through a knitted wire mist eliminator pad to remove droplets from the vapor stream; (d) scrubbing vaporized sulfuric acid from the vapor stream by spraying water or sulfuric acid through the mist eliminator pad at a rate of from 0.6-2.5 pounds liquid per pound of vapor passing through said mist eliminator pad, said liquid being sprayed substantially uniformly over said pad to provide a wetting rate of 0.10-0.35 gallons per minute per square foot of mist eliminator pad surface area, said mist eliminator pad having a wire diameter of 0.001-0.05 inches, and interfacial area of from 50-200 feet squared per cubic foot, a void space of from 90-99.7% and a thickness of 4-16 inches; (e) collecting the scrubbed vapor from the mist eliminator pad as an overhead fraction; and (f) collecting a concentrated sulfuric acid solution as a bottoms fraction.
Claim 2
Dependent Claim
199 words
A process for concentrating sulfuric acid which comprises: (a) introducing an aqueous feed sulfuric acid into an evaporator; (b) heating the feed sulfuric acid in said evaporator to a temperature sufficient to evaporate the water and form a vapor rich in water and leave a concentrated bottoms product rich in sulfuric acid; (c) passing the vapor rich in water through a knitted wire mist eliminator pad to remove droplets from the vapor stream; (d) scrubbing vaporized sulfuric acid from the vapor stream by spraying water or sulfuric acid through the mist eliminator pad at a rate of from 0.6-2.5 pounds liquid per pound of vapor passing through said mist eliminator pad, said liquid being sprayed substantially uniformly over said pad to provide a wetting rate of 0.10-0.35 gallons per minute per square foot of mist eliminator pad surface area, said mist eliminator pad having a wire diameter of 0.001-0.05 inches, and interfacial area of from 50-200 feet squared per cubic foot, a void space of from 90-99.7% and a thickness of 4-16 inches; (e) collecting the scrubbed vapor from the mist eliminator pad as an overhead fraction; and (f) collecting a concentrated sulfuric acid solution as a bottoms fraction.
Claim 3
Dependent Claim
21 words
The process of claim 1 wherein the mist eliminator pad has a thickness of from 6-12 inches and segmented layer construction.
Claim 4
Dependent Claim
25 words
The process of claim 2 wherein the liquid spray rate is from 0.9-1.2 lbs liquid per lb of vapor passed through the mist eliminator pad.
Claim 5
Dependent Claim
32 words
The process of claim 3 wherein said liquid is sprayed through a flow distributor utilizing a plurality of holes with one hole being positioned for every 7-20 square inches of pad surface.
Claim 6
Dependent Claim
18 words
The process of claim 3 wherein said feed solution to be concentrated contains from 80-91 percent sulfuric acid.
Claim 7
Dependent Claim
21 words
The process of claim 3 wherein said scrubbing is with sulfuric acid and the sulfuric acid contains from 60-75% sulfuric acid.
References Cited (Backward Citations)
US3334027A
Cited
US3634201A
Cited
US3661732A
Cited
US3970511A
Cited
US3944401A
Cited
US4138309A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-10 | 1987-04-11 | 1987-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-10 | 1991-04-11 | 1991-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-10 | 1995-04-11 | 1995-10-11 | $7700.00 | Window Closed / Lapsed |