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US4407877A Expired / Lapsed US ⏱️ 0.0 years remaining

High-strength laminate

Assignee: Individual
•
Filing: 1982-05-27
•
Granted: 1983-10-04
•
Expires: 2002-05-27
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Abstract

Abstract A high-strength laminate comprising generally weakly adhered biaxially oriented films, each formed of a blend which exhibits a distinct fibrous morphology with the fibres forming a distinct unidirectional grain when measured in a micro-scale but with the fibre-portions strongly deflected from this direction as seen on a micro-scale, the films being arranged in the laminate such that the undirectional grain in at least two of the films criss-cross each other. This laminate is produced by melt attenuating the blend(s) while extruding the latter into film-like layers, cross-laminating at least two layers before or after solidification while they are still in molecularly unoriented state--except for the weak orientation produced by the melt-attenuation--and finally strongly biaxially orienting the laminate by stretching in several steps, whereby the stretching is generally uniaxial during each step.

Inventors

  • 👤 Ole-Bendt Rasmussen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:46
CPC Classifications
B; B32; B32B; B32B37/00; B29; B29C; B29C48/00; B29C48/03; B29C48/09; B29C48/10; B29C48/16; B29C48/18; B29C48/19; B29C48/20; B29C48/21; B29C48/22; B32B27/00; B29C48/07; B29C48/08; Y; Y10; Y10S; Y10S428/00; Y10S428/905; Y10T; Y10T428/00; Y10T428/24; Y10T428/24058; Y10T428/24132

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 148 words
A high-strength generally continuous flexible laminate comprised of at least two generally continuous films each being biaxially oriented and generally weakly adhered to an adjacent such film in face-to-face relation, each such film being formed by extrusion with coincidental melt attenuation of a blend of at least two polymers which are sufficiently incompatible as to exhibit upon said extrusion an internal microscopic fibrillar morphology in which elongated fibrils are arranged in a generalized grain-like pattern having one predominant grain direction and imparting a corresponding direction of splittability to such film, such generalized grain pattern including fibrils having microscopically visible recurrent deflections from said predominant grain direction at intervals therealong which form a substantially zig-zagging specific grain configuration incorporated within said generalized grain pattern, the films being arranged in the laminate in such manner that the respective directions of splittability for at least two such films intersect each other.
Claim 2
Dependent Claim 148 words
A high-strength generally continuous flexible laminate comprised of at least two generally continuous films each being biaxially oriented and generally weakly adhered to an adjacent such film in face-to-face relation, each such film being formed by extrusion with coincidental melt attenuation of a blend of at least two polymers which are sufficiently incompatible as to exhibit upon said extrusion an internal microscopic fibrillar morphology in which elongated fibrils are arranged in a generalized grain-like pattern having one predominant grain direction and imparting a corresponding direction of splittability to such film, such generalized grain pattern including fibrils having microscopically visible recurrent deflections from said predominant grain direction at intervals therealong which form a substantially zig-zagging specific grain configuration incorporated within said generalized grain pattern, the films being arranged in the laminate in such manner that the respective directions of splittability for at least two such films intersect each other.
Claim 3
Dependent Claim 15 words
A laminate according to claim 1 comprising at least three of said biaxially oriented films.
Claim 4
Dependent Claim 33 words
A laminate according to claim 1 in which the adherence between at least two films is strong in spots or lines and at least weak in the remaining portions of the adjacent surfaces.
Claim 5
Dependent Claim 31 words
A laminate according to claim 3 comprising at least three such films in which the lines or spots of strong adherence are staggered in the two sides of the intermediate film.
Claim 6
Dependent Claim 33 words
A laminate according to claim 1 comprising two such films each having its generalized grain pattern extending obliquely to the extrusion direction and in criss-crossing relationship to the grain of the other layer.
Claim 7
Dependent Claim 27 words
A laminate according to claim 5 also comprising a third film between the said two layers with its generalized grain pattern extending parallel to said extrusion direction.
Claim 8
Dependent Claim 23 words
A laminate according to claim 1 in which at least one such film has its generalized grain pattern extending in a lateral direction.
Claim 9
Dependent Claim 25 words
A laminate according to claim 1 in which each such film has varying orientation and thickness according to a pattern of generally parallel narrow striations.
Claim 10
Dependent Claim 112 words
A laminate according to claim 8 in which said striations form two sets (A) and (B) interspersed with one another, each striation comprising portions of each of the oriented films, the striations (A) being relatively thick, and are biaxially cold stretched in a pronouncedly unbalanced manner, with the main axis of cold stretching generally substantially parallel to the direction of the striations, and with the tear propagation direction forming a small angle to the direction of orientation, while the striations (B) being relatively thin, and are biaxially cold stretched generally in a balanced manner or in unbalanced manner with their main axis of cold stretching criss-crossing with the direction of the striations.
Claim 11
Dependent Claim 21 words
A laminate according to claim 1 in which at least one of said films is a blend mainly containing crystalline polyolefins.
Claim 12
Dependent Claim 25 words
A laminate according to claim 10 in which at least one of said films is substantially a blend of polypropylene and high- and/or low-density polyethylene.
Claim 13
Dependent Claim 20 words
A laminate according to claim 10 in which said blend contains static polypropylene or ethylene-propylene rubber as an alloying agent.
Claim 14
Dependent Claim 20 words
A laminate according to claim 1 where each said polymer blend contains not more than 85% of any given polymer.
Claim 15
Dependent Claim 18 words
A laminate according to claim 10 where the polyolefin mainly is a polypropylene copolymer with 2-5% of ethylene.
Claim 16
Dependent Claim 16 words
A laminate according to claim 10 in which said blend is of polypropylene and an elastomer.
Claim 17
Dependent Claim 27 words
A laminate according to claim 15 in which said elastomer is atactic polypropylene, an ethylene-propylene-rubber, an ethylene-vinylacetate copolymer, a polyisobutylene, or a "thermoplastic rubber" based on butadiene/styrene.
Claim 18
Dependent Claim 40 words
A laminate according to claim 1 where each said polymer blend is of a polyester and of a polyamide, a polyester and a polyurethane, a polyester and a polycarbonate, a polyamide and a polycarbonate, or a blend of vinylidene copolymers.
Claim 19
Dependent Claim 18 words
A laminate according to claim 1 wherein the biaxial orientation of each of said films is generally balanced.

References Cited (Backward Citations)

US3701701A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-03 1987-04-04 1987-10-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-03 1991-04-04 1991-10-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-03 1995-04-04 1995-10-04 $7700.00 Window Closed / Lapsed

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