US4403397A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making avalanche photodiodes
Assignee: United States Department of the Navy
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Filing: 1981-07-13
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Granted: 1983-09-13
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Expires: 2001-07-13
Abstract
Abstract A quadrant avalanche photodiode with large surface areas is made using photolithographic planar technology. The use of proton bombardment creates semi-insulating material around the quadrants. Semi-insulating material prevents cross-talk between quadrants. The Schottky barrier quadrant detectors were fabricated using GaAs 1-x Sb x ternary alloys grown epitaxially on heavily doped GaAs substrates.
Inventors
- 👤 Nicholas Bottka
- 👤 Marian E. Hills
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:36
CPC Classifications
H; H10; H10P; H10P30/00; H10P30/20; H10P30/202; H10P30/206; H10F; H10F30/00; H10F30/20; H10F30/21; H10F30/22; H10F30/225; H10F30/227; H10F71/00; H10F71/127; H10F71/1272; H10F77/00; H10F77/95; H10F77/953; H10F77/959; H10P30/208; H10P30/22; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/544; Y10; Y10S; Y10S148/00; Y10S148/084
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
271 words
A method of making avalanche photodiode segmented detectors with at least one active layer from an epitaxially grown heterostructure sample of GaAs l-x Sb x epitaxially grown on an Sn doped GaAs substrate comprising the steps of: (a) applying a photoresist solution to coat both sides of the sample; (b) exposing at a preselected wavelength, the sample's active layer through a first mask to open a plurality of windows on said sample; (c) etching the sample; (d) plating a conductive material over said plurality of windows on said active layer; (e) applying a layer of photoresist on the epilayer side of the sample; (f) exposing said epilayer side applied layer through a second mask at a preselected wavelength, said second mask having different dimensions than said first mask; (g) bombarding said epilayer side of said sample with protons to produce semi-insulating volumes on said epilayer side where photoresist does not cover said epilayer side surface; (h) removing said unexposed layer of photoresist such that no photoresist remains on the sample; (i) applying a layer of photoresist to coat both sides of the sample; (j) exposing the epilayer side of photoresist through a third mask at a preselected wavelength; (k) etching said sample; (l) depositing electrode contacts on the conductive material on said epilayer side of said sample; (m) plasma-etching away said undeveloped photoresist with O 2 ; (n) depositing ohmic contacts on preselected portions of the substrate side of said sample; (o) cleaving the edges of said sample to reduce leakage current; (p) mounting said sample; and (q) making electrical contacts to said deposited ohmic contacts and said deposited electrode contacts.
Claim 2
Independent Claim
271 words
A method of making avalanche photodiode segmented detectors with at least one active layer from an epitaxially grown heterostructure sample of GaAs l-x Sb x epitaxially grown on an Sn doped GaAs substrate comprising the steps of: (a) applying a photoresist solution to coat both sides of the sample; (b) exposing at a preselected wavelength, the sample's active layer through a first mask to open a plurality of windows on said sample; (c) etching the sample; (d) plating a conductive material over said plurality of windows on said active layer; (e) applying a layer of photoresist on the epilayer side of the sample; (f) exposing said epilayer side applied layer through a second mask at a preselected wavelength, said second mask having different dimensions than said first mask; (g) bombarding said epilayer side of said sample with protons to produce semi-insulating volumes on said epilayer side where photoresist does not cover said epilayer side surface; (h) removing said unexposed layer of photoresist such that no photoresist remains on the sample; (i) applying a layer of photoresist to coat both sides of the sample; (j) exposing the epilayer side of photoresist through a third mask at a preselected wavelength; (k) etching said sample; (l) depositing electrode contacts on the conductive material on said epilayer side of said sample; (m) plasma-etching away said undeveloped photoresist with O 2 ; (n) depositing ohmic contacts on preselected portions of the substrate side of said sample; (o) cleaving the edges of said sample to reduce leakage current; (p) mounting said sample; and (q) making electrical contacts to said deposited ohmic contacts and said deposited electrode contacts.
Claim 3
Dependent Claim
31 words
A method of making avalanche photodiodes as described in claim 1 where said applying step (a) further comprises using positive photoresist which is dip-pulled at a rate of approximately 1.75 cm/min.
Claim 4
Dependent Claim
42 words
A method of making avalanche photodiodes as described in claim 1 where said applying step (e) further comprises dip-pulling the sample in positive photoresist at a rate of approximately 15.7 cm/min to get a layer of photoresist at least 4 μm thick.
Claim 5
Dependent Claim
38 words
A method of making avalanche photodiodes as described in claim 1 where said etching steps, (c) and (k), comprise using an etchant of 1:1, HCl:H 2 O which is applied for 1-2 minutes and then rinsed with water.
Claim 6
Dependent Claim
22 words
A method of making avalanche photodiodes as described in claim 1 where said deposited electrode contacts, step (l), comprises electroplating gold pads.
Claim 7
Dependent Claim
25 words
A method of making avalanche photodiodes as described in claim 1 where said deposited ohmic contacts, step (n), comprises sputtering Au-Ge(12%) for said ohmic contacts.
Claim 8
Independent Claim
257 words
A method of making avalanche photodiode segmented detectors comprising the steps of: (a) epitaxially growing several GaAs l-x Sb x layers on an Sn doped GaAs substrate, where x=the mole fraction of GaSb; (b) dip-pulling said substrate and layers in positive photoresist so as to coat both sides of the sample; (c) exposing said sample's outermost layer through a first mask, said exposure at a selected wavelength for a limited amount of time; (d) etching the sample in a solution of 1:1 HCl:H 2 O for one-to-two minutes; (e) plating palladium layers to form quadrants, said layer plated to a depth of 100-200 A; (f) dip-pulling a layer of photoresist on the sample to obtain a layer of photoresist approximately 4 μm thick; (g) exposing said layer of photoresist through a second mask at a selected wavelength for a limited amount of time, said second mask having different dimensions than said first mask; (h) bombarding the epitaxial layer side of said sample with protons to produce semi-insulating volumes around each quadrant; (i) dip-pulling a layer of photoresist on the sample; (j) etching said layer in 1:1 HCl:H 2 O solution for approximately one minute; (k) electroplating gold pad electrode contacts to each segment area where said developed photoresist has been removed; (l) plasma etching away said undeveloped photoresist with O 2 ; (m) sputtering Au-Ge, 12% Ge, 88% Au, ohmic contacts on selected areas of the substrate side of said sample; (n) cleaving the edges of said sample to reduce leakage current; and (o) mounting the sample.
Claim 9
Independent Claim
257 words
A method of making avalanche photodiode segmented detectors comprising the steps of: (a) epitaxially growing several GaAs l-x Sb x layers on an Sn doped GaAs substrate, where x=the mole fraction of GaSb; (b) dip-pulling said substrate and layers in positive photoresist so as to coat both sides of the sample; (c) exposing said sample's outermost layer through a first mask, said exposure at a selected wavelength for a limited amount of time; (d) etching the sample in a solution of 1:1 HCl:H 2 O for one-to-two minutes; (e) plating palladium layers to form quadrants, said layer plated to a depth of 100-200 A; (f) dip-pulling a layer of photoresist on the sample to obtain a layer of photoresist approximately 4 μm thick; (g) exposing said layer of photoresist through a second mask at a selected wavelength for a limited amount of time, said second mask having different dimensions than said first mask; (h) bombarding the epitaxial layer side of said sample with protons to produce semi-insulating volumes around each quadrant; (i) dip-pulling a layer of photoresist on the sample; (j) etching said layer in 1:1 HCl:H 2 O solution for approximately one minute; (k) electroplating gold pad electrode contacts to each segment area where said developed photoresist has been removed; (l) plasma etching away said undeveloped photoresist with O 2 ; (m) sputtering Au-Ge, 12% Ge, 88% Au, ohmic contacts on selected areas of the substrate side of said sample; (n) cleaving the edges of said sample to reduce leakage current; and (o) mounting the sample.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-09-12 | 1987-03-14 | 1987-09-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-09-12 | 1991-03-14 | 1991-09-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-09-12 | 1995-03-14 | 1995-09-13 | $7700.00 | Window Closed / Lapsed |