Reclamation process for water-borne uranium

Claim 2

A process for treating an aqueous solution including ammonium nitrate, fluorides and uranium compounds and recovering uranium therefrom, consisting essentially of the combination and sequence of steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 to thereby precipitate out the fluorides, and removing therefrom any insolubles including precipitates induced by said pH adjustment; (b) acidifying the basic solution with its contents of remaining solubles to a pH of lower than about 6 to thereby convert the uranium to a soluble uranyl compound; (c) contacting the acidified solution and its contents comprising the soluble uranyl compound with an ion exchange material having at least one amidoxime group therein, and thereby removing and retaining thereon ions comprising uranium from the acidified solution; and, (d) recovering uranium from the ion exchange material by contacting said material with an acid.

Claim 3

The process of claim 1, wherein the pH of the aqueous solution with its contents is adjusted to a basic condition of higher than about 8 by the addition thereto of at least one alkali selected from the group consisting of a hydroxide, carbonate or bicarbonate of an alkaline earth metal, alkali metal and ammonia, and mixtures thereof.

Claim 4

The process of claim 2, wherein the alkali is calcium hydroxide.

Claim 5

The process of claim 2, wherein the alkali is ammonium hydroxide.

Claim 6

The process of claim 2, wherein the alkali is sodium hydroxide.

Claim 7

The process of claim 2, wherein the alkali is magnesium hydroxide.

Claim 8

The process of claim 2, wherein the alkali is at least one carbonate or bicarbonate selected from the group consisting of calcium, magnesium, sodium and ammonia, and mixtures thereof.

Claim 9

The process of claim 1, wherein the basic solution with its contents is acidified to a pH of less than about 6 with a mineral acid.

Claim 10

The process of claim 6, wherein the mineral acid is nitric acid.

Claim 11

The process of claim 1, wherein ions comprising uranium retained on the ion exchange material are removed therefrom by contact with a mineral acid.

Claim 12

The process of claim 10, wherein the mineral acid is nitric acid.

Claim 13

The process of claim 1, wherein any hydrogen peroxide present in the solution being treated is decomposed prior to contacting the solution and its contents with the ion exchange material.

Claim 14

A process for treating an aqueous solution including ammonium nitrate, fluorides and uranium compounds, and recovering uranium therefrom, consisting essentially of the combination and sequence of steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 by the addition thereto of an alkali to thereby precipitate out the fluorides, and removing therefrom any insolubles including precipitates formed by said pH adjustment; (b) acidifying the basic solution with its contents of remaining solubles to a pH of at least about 5 with mineral acid to thereby convert the uranium to a soluble uranyl salt; (c) eliminating any hydrogen peroxide contained in the solution; (d) contacting the acidifed solution and its contents comprising the soluble uranyl salt with a chelating ion exchange material having at least one amidoxime group therein, and thereby removing from the acidified solution and retaining on said ion exchange material ions comprising uranium; and (e) recovering uranium from the ion exchange material by contacting said material with mineral acid.

Claim 15

A process for treating an aqueous solution including ammonium nitrate, fluorides and uranium compounds, and recovering uranium therefrom, consisting essentially of the combination and sequence of steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 by the addition thereto of an alkali to thereby precipitate out the fluorides, and removing therefrom any insolubles including precipitates formed by said pH adjustment; (b) acidifying the basic solution with its contents of remaining solubles to a pH of at least about 5 with mineral acid to thereby convert the uranium to a soluble uranyl salt; (c) eliminating any hydrogen peroxide contained in the solution; (d) contacting the acidifed solution and its contents comprising the soluble uranyl salt with a chelating ion exchange material having at least one amidoxime group therein, and thereby removing from the acidified solution and retaining on said ion exchange material ions comprising uranium; and (e) recovering uranium from the ion exchange material by contacting said material with mineral acid.

Claim 16

The process of claim 13, wherein the pH of the aqueous solution with its contents is adjusted to a basic condition of higher than about 8 by the addition thereto of at least one alkali selected from the group of hydroxides, carbonates and bicarbonates of calcium, magnesium, sodium and ammonium, and mixtures thereof.

Claim 17

The process of claim 13, wherein the alkali is calcium hydroxide.

Claim 18

The process of claim 13, wherein the alkali is magnesium hydroxide.

Claim 19

The process of claim 13, wherein the basic water with its contents is acidified to a pH of at least about 5 with nitric acid.

Claim 20

The process of claim 13, wherein ions comprising uranium retained on the ion exchange material are removed therefrom by contact with nitric acid.

Claim 21

The process of claim 13, wherein any hydrogen peroxide present in the solution being treated is eliminated therefrom prior to contacting the solution and its contents with the ion exchange material.

Claim 22

The process of claim 19, wherein the hydrogen peroxide is eliminated by decomposition.

Claim 23

The process of claim 20, wherein the decomposition of hydrogen peroxide is facilitated by absorbing the stabilizer therefor on activated carbon.

Claim 24

The process of claim 20, wherein the decomposition of hydrogen peroxide is facilitated by subjecting the peroxide to a metal catalyst selected from the group consisting of iron and copper, and high temperatures.

Claim 25

The process of claim 13, wherein the chelating ion exchange material comprises a crosslinked macroporous acrylic polymer having amidoxime groups of the formula ##STR2##

Claim 26

A process for treating an aqueous solution including ammonium nitrate, fluorides and uranium compounds, and recovering uranium therefrom, consisting essentially of the steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 by the addition thereto of at least one alkali selected from the group consisting of hydroxides, carbonates and bicarbonates of calcium, magnesium, sodium and ammonia, and mixtures thereof, to thereby precipitate out fluoride as an insoluble, and removing from the water any insolubles including precipitates formed by said pH adjustment; (b) acidifying the basic solution with its contents of uranium solubles to a pH of at least about 5 with nitric acid to thereby convert the uranium to uranyl nitrate; (c) contacting the acidified solution and its contents including the uranyl nitrate with a chelating ion exchange material having at least one amidoxime group thereon, and thereby removing the acidified solution and retaining on said ion exchange material uranyl ions form the uranyl nitrate; and (d) recovering uranyl ions from the ion exchange material by contacting said material with nitric acid.

Claim 27

A process for treating an aqueous solution including ammonium nitrate, fluorides and uranium compounds, and recovering uranium therefrom, consisting essentially of the steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 by the addition thereto of at least one alkali selected from the group consisting of hydroxides, carbonates and bicarbonates of calcium, magnesium, sodium and ammonia, and mixtures thereof, to thereby precipitate out fluoride as an insoluble, and removing from the water any insolubles including precipitates formed by said pH adjustment; (b) acidifying the basic solution with its contents of uranium solubles to a pH of at least about 5 with nitric acid to thereby convert the uranium to uranyl nitrate; (c) contacting the acidified solution and its contents including the uranyl nitrate with a chelating ion exchange material having at least one amidoxime group thereon, and thereby removing the acidified solution and retaining on said ion exchange material uranyl ions form the uranyl nitrate; and (d) recovering uranyl ions from the ion exchange material by contacting said material with nitric acid.

Claim 28

The process of claim 24, wherein any hydrogen peroxide present in the solution being treated is eliminated therefrom prior to contacting the acidfied solution and its contents with the ion exchange material.

Claim 29

A process for treating an aqueous solution including ammonium nitrate, fluoride compounds and uranium compounds, and recovering uranium therefrom, consisting essentially of the steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 by the addition thereto of calcium hydroxide to thereby precipitate out fluorides as insoluble calcium fluoride and any iron as an insoluble hydroxide, and removing from the solution insolubles including the precipitated calcium fluoride and any hydroxide of iron; (b) acidifying the basic solution with its contents of remaining solubles to a pH of about 5 to about 4 with nitric acid to thereby convert the uranium to uranyl nitrate; (c) contacting the acidified solution and its contents including the uranyl nitrate with a chelating ion exchange material having at least one amidoxime group thereon and charged with ammonia cations, and thereby removing from the acidified soluton and retaining on said ion exchange material the uranyl ions from the uranyl nitrate; and (d) recovering uranyl ions from the ion exchange material by contacting said material with nitric acid.

Claim 30

A process for treating an aqueous solution including ammonium nitrate, fluoride compounds and uranium compounds, and recovering uranium therefrom, consisting essentially of the steps of: (a) adjusting the pH of the aqueous solution with its contents to a basic condition of higher than about 8 by the addition thereto of calcium hydroxide to thereby precipitate out fluorides as insoluble calcium fluoride and any iron as an insoluble hydroxide, and removing from the solution insolubles including the precipitated calcium fluoride and any hydroxide of iron; (b) acidifying the basic solution with its contents of remaining solubles to a pH of about 5 to about 4 with nitric acid to thereby convert the uranium to uranyl nitrate; (c) contacting the acidified solution and its contents including the uranyl nitrate with a chelating ion exchange material having at least one amidoxime group thereon and charged with ammonia cations, and thereby removing from the acidified soluton and retaining on said ion exchange material the uranyl ions from the uranyl nitrate; and (d) recovering uranyl ions from the ion exchange material by contacting said material with nitric acid.

Claim 31

The process of claim 26, wherein any hydrogen peroxide present in the solution being treated is eliminated therefrom prior to contacting the acidified solution and its contents with the ion exchange material.

Claim 32

The process of claim 26, wherein the chelating ion exchange material comprises a crosslinked macroporous acrylic polymer having amidoxime groups of the formula ##STR3##