Patent US4401698A successfully refreshed from Google Patents.
US4401698A
Expired / Lapsed
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Hydrophilic coatings for textile materials
Assignee: Wacker Chemical Corp
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Filing: 1981-12-18
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Granted: 1983-08-30
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Expires: 2001-12-18
Abstract
Abstract Silylated organic polymers which may be applied to textile materials to impart hydrophilic properties thereto are prepared by reacting polymeric organic acids with silylated aminofunctional polyethers. The resultant composition may then be crosslinked to impart durable hydrophilic properties to textile materials treated therewith.
Inventors
- 👤 Jeffrey A. Tripp
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 20:37
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; D06M15/647; C; C08; C08G; C08G65/00; C08G65/02; C08G65/32; C08G65/329; C08G65/336; C08G81/00; C08G81/02; C08G81/024; C08G81/025
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
333 words
A process for treating a textile material which comprises treating the textile material with a silylated organic polymer and thereafter drying the treated material at a temperature of from 25° to 200° C., said silylated organic polymer is obtained from the reaction of a silylated aminofunctional polyether and a polymeric organic acid having at least one acid group per molecule, at a temperature of from -10° to 200° C., in which the polymeric organic acid is obtained from the polymerization of an organic acid having aliphatic unsaturation, said silylated aminofunctional polyether has the formula ##STR19## where R is a radical selected from the group consisting of ##STR20## R 1 is selected from the class consisting of hydrogen, a monovalent hydrocarbon radical and a silicon containing radical selected from the group consisting of ##STR21## and when R is --N.sup.⊕ (R 1 ) 3 , A is an anionic silicon containing radical selected from the group consisting of ##STR22## and when R is ##STR23## then A is selected from the group consisting of hydrogen, a monovalent hydrocarbon radical, and a silicon containing radical selected from the group consisting of ##STR24## R 2 is a divalent radical, R 3 is a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, R 4 is a divalent hydrocarbon radical selected from the group consisting of (CH 2 ) y , CH═CH or a cyclic hydrocarbon radical selected from the group consisting of C 6 H 4 , C 6 H 8 , C 6 H 10 and C 10 H 6 , R 5 is selected from the group consisting of hydrogen and a monovalent hydrocarbon radical, with the proviso that at least one A or R 1 is a silicon containing radical, a is a number of from 0 to 4, e is 0, 1, 2 or 3, n is a number of from 2 to 4, x is a number of from 1 to 600 and y is a number of from 0 to 16.
Claim 2
Dependent Claim
333 words
A process for treating a textile material which comprises treating the textile material with a silylated organic polymer and thereafter drying the treated material at a temperature of from 25° to 200° C., said silylated organic polymer is obtained from the reaction of a silylated aminofunctional polyether and a polymeric organic acid having at least one acid group per molecule, at a temperature of from -10° to 200° C., in which the polymeric organic acid is obtained from the polymerization of an organic acid having aliphatic unsaturation, said silylated aminofunctional polyether has the formula ##STR19## where R is a radical selected from the group consisting of ##STR20## R 1 is selected from the class consisting of hydrogen, a monovalent hydrocarbon radical and a silicon containing radical selected from the group consisting of ##STR21## and when R is --N.sup.⊕ (R 1 ) 3 , A is an anionic silicon containing radical selected from the group consisting of ##STR22## and when R is ##STR23## then A is selected from the group consisting of hydrogen, a monovalent hydrocarbon radical, and a silicon containing radical selected from the group consisting of ##STR24## R 2 is a divalent radical, R 3 is a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, R 4 is a divalent hydrocarbon radical selected from the group consisting of (CH 2 ) y , CH═CH or a cyclic hydrocarbon radical selected from the group consisting of C 6 H 4 , C 6 H 8 , C 6 H 10 and C 10 H 6 , R 5 is selected from the group consisting of hydrogen and a monovalent hydrocarbon radical, with the proviso that at least one A or R 1 is a silicon containing radical, a is a number of from 0 to 4, e is 0, 1, 2 or 3, n is a number of from 2 to 4, x is a number of from 1 to 600 and y is a number of from 0 to 16.
Claim 3
Dependent Claim
21 words
The process of claim 1, wherein the silylated organic polymer is mixed with a diluent prior to coating the textile material.
Claim 4
Dependent Claim
21 words
The process of claim 1, wherein the silylated organic polymer is dissolved in a solvent prior to coating the textile material.
Claim 5
Dependent Claim
34 words
The process of claim 2, wherein the silylated organic polymer is present in an amount of from 0.25 to 99 percent by weight based on the weight of the silylated organic polymer and diluent.
Claim 6
Dependent Claim
34 words
The process of claim 3, wherein the silylated organic polymer is present in an amount of from 0.25 to 99 percent by weight based on the weight of the silylated organic polymer and solvent.
Claim 7
Dependent Claim
21 words
The process of claim 1, wherein the silylated organic polymer is dispersed in a nonsolvent prior to coating the textile material.
Claim 8
Dependent Claim
11 words
The process of claim 6 wherein the non solvent is water.
Claim 9
Dependent Claim
12 words
The process of claim 1, wherein the textile material is a polyester.
Claim 10
Dependent Claim
11 words
The process of claim 1, wherein the textile material is cotton.
Claim 11
Dependent Claim
13 words
The process of claim 1, wherein the textile material is a polyester/cotton blend.
Claim 12
Dependent Claim
11 words
The coated textile material obtained from the process of claim 1.
Claim 13
Dependent Claim
54 words
The process of claim 1, wherein the silylated aminofunctional polyether is obtained from the reaction of an aminofunctional silane and a dicarboxylic acid having up to 10 carbon atoms or anhydrides thereof to form a carboxylic acid functional silane and thereafter the carboxylic acid functional silane is reacted with an amine terminated oxyalkylene polymer.
Claim 14
Dependent Claim
30 words
The process of claim 1, wherein the silylated aminofunctional polyether is obtained from the reaction of a haloalkyltrialkoxysilane with an amine terminated polyether in the presence of an acid acceptor.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-08-29 | 1987-02-28 | 1987-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-08-29 | 1991-02-28 | 1991-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-08-29 | 1995-02-28 | 1995-08-30 | $7700.00 | Window Closed / Lapsed |